MSDS: CHAMPION庐 MSDS 1100 SERIES LUBRICANTS
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHAMPION庐 MSDS 1100 SERIES LUBRICANTS
Synonyms:
3000 DURATECH庐 TRACTOR HYDRAULIC FLUID 4011 CHAMPION庐 HY TRAN
4000 CHAMPION庐 4000 PREMIUM TRACTOR HYD. FLUID 4101A CHAMPION庐 AC HYDRAULIC 821
4010A CHAMPION庐 JDT 303 TRACTOR FLUID 4111U CHAMPION庐 FORD TRACTOR HYDRAULIC
Company Identification
Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735
PHONE: 800-821-5693 WEBSITE: www.championbrands.com
CAS Registry Number Not Applicable
Synonyms None
Generic/Chemical Name Mixture
Product Type Petroleum Based Lubricating Oil
Preparation Date March 20, 2007
Transportation Emergency Response
CHEMTREC: (800) 424-9300
Product Information
Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
Base Oil, Distillates, Hydrotreated, Petroleum Hydrocarbon Mixture 85.0 鈥? 99.5% weight
Additives, Non-hazardous in refined oil Mixture 0.5 鈥? 15.0 %weight
The BASE OIL may be a mixture of any of the following: CAS 64741884, CAS 64741895, CAS 64741964, CAS 64741975, CAS
64742014, CAS 64742525, CAS 64742536, CAS 64742547, CAS 64742558, CAS 64742570, CAS 64742627
The ADDITIVES are a mixture of confidential ingredients permitted by 29 CFR 1910.1200 and various State Right to Know Laws. In
the event of medical emergency, specific chemical information will be disclosed to a treating physician or nurse.
3. HAZARD IDENTIFICATION
IMMEDIATE HEALTH EFFECTS
Eye: Not expected to cause prolonged or significant eye irritation.
Skin: Contact with the skin is not expected to cause prolonged or significant irritation. Not expected to be harmful to
internal organs if absorbed through the skin.
Ingestion: Not expected to be harmful if swallowed.
Inhalation: Not expected to be harmful if inhaled. Contains a petroleum-based mineral oil. May cause respiratory
irritation or other pulmonary effects following prolonged or repeated inhalation of oil mist at airborne levels above the
recommended mineral oil mist exposure limit. Symptoms of respiratory irritation may include coughing and difficulty
breathing.
4. FIRST AID MEASURES
Eye: No specific first aid measures are required. As a precaution, remove contact lenses, if worn, and flush eyes with
water.
Skin: No specific first aid measures are required. As a precaution, remove clothing and shoes if contaminated. To
remove the material from skin, use soap and water. Discard contaminated clothing and shoes or thoroughly clean
before reuse.
Ingestion: No specific first aid measures are required. Do not induce vomiting. As a precaution, get medical advice.
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MSDS: CHAMPION庐 MSDS 1100 SERIES LUBRICANTS
Inhalation: No specific first aid measures are required. If exposed to excessive levels of material in the air, move the
exposed person to fresh air. Get medical attention if coughing or respiratory discomfort occurs.
5. FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.
NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0
FLAMMABLE PROPERTIES:
Flashpoint: >200 掳C (392 掳F)
Autoignition: NDA
Flammability (Explosive) Limits (% by volume in air): Lower: NA Upper: NA
EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions: This material will burn although it is not easily ignited. For fires involving this material, do
not enter any enclosed or confined fire space without proper protective equipment, including self-contained breathing
apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids,
and gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this
material undergoes combustion. Combustion may form oxides of: Sulfur, Phosphorus, and Nitrogen.
6. ACCIDENTAL RELEASE INFORMATION
Protective Measures: Eliminate all sources of ignition in vicinity of spilled material.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further
contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in
Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent
materials or pumping. Where feasible and appropriate, remove contaminated soil. Place contaminated materials in
disposable containers and dispose of in a manner consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-
8802 as appropriate or required.
7. HANDLING AND STORAGE
Precautionary Measures: DO NOT USE IN HIGH PRESSURE SYSTEMS in the vicinity of flames, sparks and hot
surfaces. Use only in well ventilated areas. Keep container closed. Keep out of the reach of children.
General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage
systems and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material.
To minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review
all operations which have the potential of generating an accumulation of electrostatic charge and/or a flammable
atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading,
filtering, mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more
information, refer to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire
Protection Association (NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum
Institute (API) Recommended Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray
Currents'.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it
may rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks,
static electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should
be completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly
8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other
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MSDS: CHAMPION庐 MSDS 1100 SERIES LUBRICANTS
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should read and understand all instructions
and limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances.
Special note: Do not use in breathing air apparatus or medical equipment.
ENGINEERING CONTROLS:
Use in a well-ventilated area.
PERSONAL PROTECTIVE EQUIPMENT
Eye/Face Protection: No special eye protection is normally required. Where splashing is possible, wear safety
glasses with side shields as a good safety practice.
Skin Protection: No special protective clothing is normally required. Where splashing is possible, select protective
clothing depending on operations conducted, physical requirements and other substances in the workplace.
Suggested materials for protective gloves include: 4H (PE/EVAL), Nitrile Rubber, Silver Shield, Viton.
Respiratory Protection: No respiratory protection is normally required.
If user operations generate an oil mist, determine if airborne concentrations are below the occupational exposure limit
for mineral oil mist. If not, wear an approved respirator that provides adequate protection from the measured
concentrations of this material. For air-purifying respirators use a particulate cartridge.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:
Component Agency TWA STEL Ceiling Notation
Distillates, Hydrotreated, Petroleum Hydrocarbon ACGIH 5 mg/m3 10 mg/m3
Distillates, Hydrotreated, Petroleum Hydrocarbon OSHA_PEL 5 mg/m3
9. PHYSICAL AND CHEMICAL PROPERTIES
Attention: the data below are typical values and do not constitute a specification.
Appearance and Odor: Colorless to Brown oily liquid.
pH: NA
Vapor Pressure: <0.01 mmHg @ 100 掳F
Vapor Density (Air = 1): >1
Boiling Point: >315.6掳C (600掳F)
Solubility: Soluble in hydrocarbons; insoluble in water
Freezing Point: NA
Melting Point: NA
Specific Gravity: 0.82 - 0.88 @ 15.6 掳C / 15.6 掳C
Viscosity: 42.0 cSt 鈥? 68.0 cSt @ 40掳C (104掳F) (Min)
10. STABILITY AND REACTIVITY
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling
conditions of temperature and pressure.
Incompatibility With Other Materials: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides,
etc.
Hazardous Decomposition Products: Hydrogen Sulfide (Temperatures >149 掳F (65 掳C))
Hazardous Polymerization: Hazardous polymerization will not occur.
11. TOXILOGICAL INFORMATION
IMMEDIATE HEALTH EFFECTS
Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components.
Skin Sensitization: No product toxicology data available.
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or
product components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product
components.
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MSDS: CHAMPION庐 MSDS 1100 SERIES LUBRICANTS
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or
product components.
ADDITIONAL TOXICOLOGY INFORMATION:
This product contains petroleum base oils which may be refined by various processes including severe solvent
extraction, severe hydrocracking, or severe hydrotreating. None of the oils requires a cancer warning under the OSHA
Hazard Communication Standard (29 CFR 1910.1200). These oils have not been listed in the National Toxicology
Program (NTP) Annual Report nor have they been classified by the International Agency for Research on Cancer
(IARC) as; carcinogenic to humans (Group 1), probably carcinogenic to humans (Group 2A), or possibly carcinogenic
to humans (Group 2B). These oils have not been classified by the American Conference of Governmental Industrial
Hygienists (ACGIH) as: confirmed human carcinogen (A1), suspected human carcinogen (A2), or confirmed animal
carcinogen with unknown relevance to humans (A3).
During use in engines, contamination of oil with low levels of cancer-causing combustion products occurs. Used motor
oils have been shown to cause skin cancer in mice following repeated application and continuous exposure. Brief or
intermittent skin contact with used motor oil is not expected to have serious effects in humans if the oil is thoroughly
removed by washing with soap and water.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be kept
out of sewage and drainage systems and all bodies of water.
ENVIRONMENTAL FATE
This material is not expected to be readily biodegradable.
13. DISPOSAL INFORMATION
Oil collection services are available for used oil recycling or disposal. Place contaminated materials in containers and
dispose of in a manner consistent with applicable regulations. Contact your sales representative or local
environmental or health authorities for approved disposal or recycling methods. (See B.C. Reg. GY/92 Waste
Management Act; R.R.O. 1990, Reg. 347 General-Waste Management; C.C.SM.c. W40 The Waste Reduction and
Prevention Act; N.S. Reg. 51/95 and N.S. Reg. 179/96 for examples of Provincial legislation.)
14. TRANSPORTATION INFORMATION
The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods
Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.
DOT Shipping Name: NOT REGULATED AS A HAZARDOUS MATERIAL FOR TRANSPORTATION UNDER 49
CFR
DOT Hazard Class: NOT APPLICABLE
DOT Identification Number: NOT APPLICABLE
DOT Packing Group: NOT APPLICABLE
Additional Information: NOT HAZARDOUS BY U.S. DOT. ADR/RID HAZARD CLASS NOT APPLICABLE.
IMO/IMDG Shipping Name: NOT REGULATED AS DANGEROUS GOODS FOR TRANSPORTATION UNDER THE
IMDG CODE
IMO/IMDG Hazard Class: NOT APPLICABLE
IMO/IMDG Identification Number: NOT APPLICABLE
IMO/IMDG Packing Group: NOT APPLICABLE
15. REGULATORY INFORMATION
EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: NO
2. Delayed (Chronic) Health Effects: NO
3. Fire Hazard: NO
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO
REGULATORY LISTS SEARCHED:
4_I1=IARC Group 1 15=SARA Section 313
4_I2A=IARC Group 2A 16=CA Proposition 65
4_I2B=IARC Group 2B 17=MA RTK
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MSDS: CHAMPION庐 MSDS 1100 SERIES LUBRICANTS
05=NTP Carcinogen 18=NJ RTK
06=OSHA Carcinogen 19=DOT Marine Pollutant
09=TSCA 12(b) 20=PA RTK
CHEMICAL INVENTORIES:
AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances
(AICS).
CANADA: All the components of this material are on the Canadian Domestic Substances List (DSL).
EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment
Directive 92/32/EEC.
JAPAN: All the components of this product are on the Existing & New Chemical Substances (ENCS) inventory in
Japan, or have an exemption from listing.
KOREA: All the components of this product are on the Existing Chemicals List (ECL) in Korea.
UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical
Inventory.
UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical
Inventory.
NEW JERSEY RTK CLASSIFICATION:
Under the New Jersey Right-to-Know Act L. 1983 Chapter 315 N.J.S.A. 34:5A-1 et. seq., the product is to be
identified as follows: PETROLEUM OIL (Lubricating oil)
WHMIS CLASSIFICATION:
This product is not considered a controlled product according to the criteria of the Canadian Controlled Products
Regulations.
16. DISCLAIMER
NFPA RATINGS: Health: 0 Flammability: 1 Reactivity: 0
HMIS RATINGS: Health: 0 Flammability: 1 Reactivity: 0
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-
Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the
National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).
REVISION STATEMENT: Revision updates many sections and the MSDS should be read in its entirety.
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CHA - Champion LLC CAS - Chemical Abstract Service Number
NDA - No Data Available NA - Not Applicable
<= - Less Than or Equal To >= - Greater Than or Equal To
Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS
Standard (Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.
The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of
Champion Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the
particular purpose, regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no
legal responsibility for use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we
may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume
any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination
of the suitability of the material for his particular purpose.
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