MSDS: CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
Synonyms:
4119AN & F CHAMPION庐 UNIVERSAL ANTIFREEZE & COOLANT
Company Identification
Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735
PHONE: 800-821-5693 WEBSITE: www.championbrands.com
CAS Registry Number Not Applicable
Synonyms None
Generic/Chemical Name Mixture
Product Type Antifreeze
Preparation Date October 23, 2007
Transportation Emergency Response
CHEMTREC: (800) 424-9300
Product Information
Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
Ethylene Glycol 107-21-1 80.0 - 95.0 % weight
Diethylene glycol 111-46-6 0.0 鈥? 5.0% weight
Water 1-5 7732-18-5 1.0 鈥? 5.0% weight
2-Ethyl Hexanoic Acid, Sodium Salt 1-5 19766-89-3 1.0 鈥? 5.0% weight
Neodacanoic Acid, Sodium Salt 1-5 31524-27-3 1.0 鈥? 5.0% weight
- HARMFUL OR FATAL IF SWALLOWED
- CAUSES EYE IRRITATION
- CONTAINS MATERIAL THAT MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS BASED ON ANIMAL DATA
- POSSIBLE BIRTH DEFECT HAZARD - CONTAINS MATERIAL THAT MAY CAUSE BIRTH DEFECTS BASED ON ANIMAL DATA
- MAY CAUSE DAMAGE TO: KIDNEY
3. HAZARD IDENTIFICATION
NFPA: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0
HMIS: HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0
IMMEDIATE HEALTH EFFECTS
INHALATION: May cause irritation of the nose and throat with headache, particularly from mists. High vapor
concentrations caused, for example, by heating the material in an enclosed and poorly ventilated workplace, may
produce nausea, vomiting, headache, dizziness and irregular eye movements.
SKIN CONTACT: No evidence of adverse effects from available information.
EYE CONTACT: Liquid, vapors or mist may cause discomfort in the eye with persistent conjunctivitis, seen as slight
excess redness or conjunctiva. Serious corneal injury is not anticipated.
INGESTION: May cause abdominal discomfort or pain, nausea, vomiting, dizziness, drowsiness, malaise, blurring of
vision, irritability, back pain, decrease in urine output, kidney failure, and central nervous system effects, including
irregular eye movements, convulsions and coma. Cardiac failure and pulmonary edema may develop. Severe kidney
damage which may be fatal may follow the swallowing of ethylene glycol. A few reports have been published
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MSDS: CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
describing the development of weakness of the facial muscles, diminishing hearing, and difficulty with swallowing,
during the late stages of severe poisoning.
CHRONIC EFFECTS: Prolonged or repeated inhalation exposure may produce signs of central nervous system
involvement, particularly dizziness and jerking eye movements. Prolonged or repeated skin contact may cause skin
sensitization and an associated dermatitis in some individuals. Ethylene glycol has been found to cause birth defects
in laboratory animals. The significance of this finding to humans has not been determined.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: The available toxicological information and a knowledge
of the physical and chemical properties of the material suggest that overexposure in unlikely to aggravate existing
medical conditions.
4. FIRST AID MEASURES
Eyes: Immediately flush eyes with large amounts of water for 15 minutes, lifting lower and upper lids. Get medical
attention as soon as possible. Contact lenses should never be worn when working with this chemical.
Skin: Flush area of skin contact immediately with large amounts of water for at least 15 minutes while removing
contaminated clothing. If irritation persists after flushing, get medical attention promptly. Wash clothing before re-use.
Inhalation: If inhaled, immediately remove victim to fresh air and call emergency medical care. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Ingestion: Obtain medical attention immediately. If patient is fully conscious, give two glasses of water. Do not induce
vomiting. If medical advice is delayed, and if the person has swallowed a moderate volume of material (a few ounces),
then give three to four ounces of hard liquor, such as whisky. For children, give proportionally less liquor, according to
weight.
Notes to Physician: : The principal toxic effects of ethylene glycol, when swallowed, are kidney damage and
metabolic acidosis. The combination of metabolic acidosis, an osmol gap and oxalate crystals in the urine is evidence
of ethylene glycol poisoning. Pulmonary edema with hypoxemia has been described in a number of patients following
poisoning with ethylene glycol. Respiratory support with mechanical ventilation may be required. There may be cranial
nerve involvement in the late stages of toxicity from swallowed ethylene glycol. In particular, effects have been
reported involving the seventh, eighth, and ninth cranial nerves, presenting with bilateral facial paralysis, diminished
hearing and dysphagia. Ethanol is antidotal and its early administration may block the formation of nephrotoxic
metabolites of ethylene glycol in the liver. The objective is to rapidly achieve and maintain a blood ethanol level of
approximately 100 mg/dl by giving a loading dose of ethanol followed by a maintenance dose. Intravenous
administration of ethanol is the preferred route. Ethanol blood levels should be checked frequently. Hemodialysis may
be required. 4-Methyl pyrazole (Fomepizole庐), a potent inhibitor of alcohol dehydrogenase, has been used
therapeutically to decrease the metabolic consequences of ethylene glycol poisoning. Fomepizole庐 is easier to use
clinically than ethanol, does not cause CNS depression or hypoglycemia and requires less monitoring than ethanol.
Additional therapeutic modalities which may decrease the adverse consequences of ethylene glycol metabolism are
the administration of both thiamine and pyridoxine. As there are complicated and serious overdoses, we recommend
you consult with the toxicologists at your poison control center.
5. FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.
FLAMMABLE PROPERTIES:
Flashpoint: 119掳C (247掳F)
FLASH POINT: Greater than 254潞F (123潞C) TOC >230潞F (>110潞C) Setaflash
AUTOIGNITION TEMPERATURE: Not determined
NFPA CLASSIFICATION: IIIB
FLAMMABILITY LIMITS: LEL: Not determined UEL: Not determined
EXTINGUISHING MEDIA: For large fires, use alcohol type or all-purpose foams. For small fires, use water spray,
carbon dioxide or dry chemical.
SPECIAL FIRE FIGHTING PROCEDURES: Do not spray pool fires directly. Firefighters should wear positive
pressure self- contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or
stored.
UNUSUAL FIRE HAZARDS: A solid stream of water or foam directed into hot, burning liquid can cause frothing.
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MSDS: CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
HAZARDOUS COMBUSTION PRODUCTS: Burning may produce carbon monoxide and carbon dioxide.
6. ACCIDENTAL RELEASE INFORMATION
Wear appropriate protective clothing and equipment (See Section 8). Collect with absorbent material and place in
appropriate, labeled container for disposal or, if permitted flush spill area with water.
7. HANDLING AND STORAGE
DANGER: Harmful or Fatal if Swallowed. Do not drink antifreeze or solution. Avoid eye and prolonged or repeated
skin contact. Avoid breathing vapors or mists. Wash exposed skin thoroughly with soap and water after use. Do not
store in opened or unlabeled containers. Keep container away from open flames and excessive heat. Do not reuse
empty containers unless properly cleaned. Empty containers retain product residue and may be dangerous. Do not
cut, weld, drill, etc. containers, even empty.
Sudden release of hot organic chemical vapors or mists from process equipment operating at elevated temperature
and pressure, or sudden ingress of air into vacuum equipment, may result in ignitions without any obvious ignition
sources. Use of this product in elevated temperature applications should be thoroughly evaluated to assure safe
operating conditions.
8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should read and understand all instructions
and limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances.
ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory Protection: Respiratory protection is required if airborne concentration exceeds TLV. At any detectable
concentration any self-contained breathing apparatus with a full face piece and operated in a pressure-demand or
other positive pressure mode or any supplied-air respirator with a full face piece and operated in a pressure-demand
or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in
pressure-demand or other positive pressure mode.
Escape: Any air-purifying full face piece respirator (gas mask) with a chin-style or front- or back-mounted organic
vapor canister or any appropriate escape-type self-contained breathing apparatus.
Skin Protection: Protective gloves recommended when prolonged skin contact cannot be avoided. Polyethylene;
Neoprene; Nitrile; Polyvinyl alcohol; Natural Rubber, Butyl Rubber. Safety shower should be available.
Eye Protection: Safety goggles and face shield. Emergency eyewash should be available. Contact lenses should not
be worn when working with this chemical.
Engineering Controls: Use general or local exhaust ventilation to meet TLV requirements.
Occupational Exposure Limits:
Component Exposure Limits Skin Form
Ethylene glycol 100 mg/m3 CEILING ACGIH Aerosol
Ethylene glycol 125 mg/m3 CEILING OSHA -vacated
50 ppm CEILING OSHA 鈥? vacated
100 mg/m3 CEILING UCC Aerosol and Vapor
Diethylene glycol 50 ppm TWA8 AIHA WEEL Aerosol and Vapor
Diethylene glycol 10 mg/m3 TWA8 AIHA WEEL Aerosol
2-Ethyl Hexanoic Acid None Established (PEL/TLV)
Neodacanoic Acid, Sodium Salt None Established (PEL/TLV)
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MSDS: CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
9. PHYSICAL AND CHEMICAL PROPERTIES
Attention: the data below are typical values and do not constitute a specification.
APPEARANCE AND ODOR: Green or yellow liquid with a characteristic odor.
pH: 8.7-9.2
SPECIFIC GRAVITY: 1.07-1.14
10. STABILITY AND REACTIVITY
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling
conditions of temperature and pressure. Keep away from flame
Incompatibility With Other Materials: Strong acid or oxidizing agents
Hazardous Decomposition Products: Incomplete combustion may produce CO & CO2 gas
Hazardous Polymerization: Hazardous polymerization will not occur.
11. TOXILOGICAL INFORMATION
CARCINOGEN: None of the components of these products is listed as a carcinogen or suspected carcinogen by
IARC, NTP or OSHA.
Acute Toxicity Values:
Ethylene Glycol: LD50 Oral Rat: 4700 mg/kg; LD50 Skin Rabbit: 9530 mg/kg
Diethylene Glycol: LD50 Oral Rat: 12,565 mg/kg; LD50 Skin Rabbit: 11,890 mg/kg
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH:
Ethylene glycol has been shown to produce dose-related teratogenic effects in rats and mice when given by gavage
or in drinking water at high concentrations or doses. Also, in a preliminary study to assess the effects of exposure of
pregnant rats and mice to aerosols at concentrations 150, 1,000 and 2,500 mg/m3 for 6 hours a day throughout the
period of organogenesis, teratogenic effects were produced at the highest concentrations, but only in mice. The
conditions of these latter experiments did not allow a conclusion as to whether the developmental toxicity was
mediated by inhalation of aerosol, percutaneous absorption of ethylene glycol from contaminated skin, or swallowing
of ethylene glycol as a result of grooming the wetted coat. In a further study, comparing effects from high aerosol
concentration by whole-body or nose-only exposure, it was shown that nose-only exposure resulted in maternal
toxicity (1,000 and 2,500 mg/m3) and developmental toxicity in with minimal evidence of teratogenicity (2,500 mg/m3).
The no-effects concentration (based on maternal toxicity) was 500 mg/m3. In a further study in mice, no teratogenic
effects could be produced when ethylene glycol was applied to the skin of pregnant mice over the period of
organogenesis. The above observations suggest that ethylene glycol is to be regarded as an animal teratogen; there
is currently no available information to suggest that ethylene glycol caused birth defects in humans. Cutaneous
application of ethylene glycol is ineffective in producing developmental toxicity; exposure to high aerosol concentration
is only minimally effective in producing developmental toxicity; the major route for producing developmental toxicity is
perorally. Two chronic feeding studies, using rats and mice, have not produced any evidence that ethylene glycol
causes dose-related increases in tumor incidence or a different pattern of tumors compared with untreated controls.
The absence of carcinogenic potential for ethylene glycol has been supported by numerous invitro genotoxicity
studies showing that it does not produce mutagenic or clastogenic effects. This product contains less than 0.3%
tolytriazole which has demonstrated mutagenic activity in a bacterial test system. A correlation has been established
between mutagenic activity and carcinogenic activity for many chemicals. Tolytriazole has not been identified as a
carcinogen or probable carcinogen by NTP, IARC or OSHA.
12. ECOLOGICAL INFORMATION
Ethylene Glycol: LC50 Goldfish: 5,000 mg/L/24 hr. at 20 C static conditions.
Toxicity threshold (cell multiplication inhibition test):
Bacterial (Pseudomonas putida): 10,000 mg/l
Protozoa (Entosiphon sulcatum and Uronema parduczi; Chatton-Lwoff): >10,000 mg/l
Algae (Microcystis aeruginosa): 2,000 mg/l
Green algae (Scenedesmus quandricauda): >10,000 mg/l
13. DISPOSAL INFORMATION
DO NOT discharge to sewer. Wear appropriate personal protection. Take up with sand, vermiculite, or similar inert
material. Dispose in accordance with federal, state and local regulations.
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MSDS: CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
14. TRANSPORTATION INFORMATION
The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods
Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.
U.S. DEPARTMENT OF TRANSPORTATION: Non-Bulk is not regulated by the US D.O.T. (in quantities under 5,000
lbs in any one inner package)
IATA: Non-Bulk is not regulated by IATA
IMDG: Non-Bulk is not regulated by IMDG (in quantities under 5,000 lbs in any one inner package)
15. REGULATORY INFORMATION
THIS PRODUCT CONTAINS COMPONENT(S) CITED ON THE FOLLOWING REGULATIONS.
Chemical Name Cas Number
Ethylene Glycol 107-21-1
United States 鈥? TSCA Inventory: Listed
Water Standards: No data available
Atmospheric Standards: Clean Air Act (1990) - List of Hazardous Air Contaminants: listed
CERCLA: Reportable Quantity (RQ): 5,000 pounds (532 gallons)
OSHA Hazard Communication Standard: This product is a 鈥渉azardous chemical鈥? as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
SARA Title III: Section 311/312 - Categories: Acute hazard; chronic hazard
Section 312 - Inventory Reporting: Ethylene glycol is subject to Tier I and/or Tier II annual inventory reporting.
Section 313 - Emission Reporting: Ethylene glycol is subject to Form R reporting requirements.
Section 302 - Extremely Hazardous Substances: Ethylene glycol is not listed.
CHEMICAL INVENTORIES:
State Right-To-Know:
Director's List of Hazardous Substances: listed
Florida - Hazardous Substances List: listed
Massachusetts - Right-to-Know List: listed
Minnesota - Haz. Subs. List: listed (particulate and vapor)
New Jersey - Right-to-Know List (Total): Present greater than 1.0%
Pennsylvania Right-to-Know List: environmental hazard
California - Exposure Limits - Ceilings: vapor-50 ppm ceiling; 125 mg/m3 ceiling
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986): The normal
consumer use of this product does not result in exposure to chemicals known to the state of California to
cause Cancer and/or reproductive harm above the significant risk level for carcinogens or the maximum
allowable dose levels for reproductive toxins. Warnings are not required for consumer packaging. However,
industrial or other occupational use of this product at higher frequency and using larger quantities of this
product may result in exposures exceeding these levels and are labeled accordingly.
California SCAQMD Rule 443.1 (South Coast Air Quality Management District Rule 443.1, Labeling of
Materials Containing Organic Solvents): VOC: Vapor pressure 0.06 mmHg at 20掳C, 1113.38 g/l
Canadian Regulations: This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all the information required.
WHMIS Information: D2A - material has potential toxic effects. Refer elsewhere in the MSDS for specific warnings and safe
handling information. Refer to the employer's workplace education program.
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS): All of the
ingredients are listed on the EINECS inventory.
AUSTRALIA: All of the ingredients of this product are listed on the Australian Inventory of Chemical Substances.
JAPAN: All of the ingredients of this product are listed on the Japanese Existing and New Chemical Substances (METI) List.
KOREA: All of the ingredients of this product are listed on the Korean Existing Chemical List (KECL).
PHILIPPINES: All of the ingredients of this product are listed on the Philippine Inventory of Chemical and Chemical
Substance (PICCS)
CHINA: All of the ingredients of this product are listed on the Inventory of Existing Chemical Substance in China (IECSC).
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MSDS: CHAMPION庐 MSDS 2030 SERIES ANTIFREEZE
16. DISCLAIMER
REVISION STATEMENT: Revision updates many sections and the MSDS should be read in its entirety.
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CHA - Champion LLC CAS - Chemical Abstract Service Number
NDA - No Data Available NA - Not Applicable
<= - Less Than or Equal To >= - Greater Than or Equal To
Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS
Standard (Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.
The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of
Champion Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the
particular purpose, regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no
legal responsibility for use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we
may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume
any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination
of the suitability of the material for his particular purpose.
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