MSDS: CHAMPION庐 MSDS 4123I
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHAMPION庐 MSDS 4123I
Synonyms:
4123I CHAMPION庐 HEAVY DUTY ENGINE DEGREASER
Company Identification
Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735
PHONE: 800-821-5693 WEBSITE: www.championbrands.com
CAS Registry Number Not Applicable
Synonyms None
Generic/Chemical Name NA
Product Type AEROSOL ENGINE CLEANER AND DEGREASER CONTAINING KEROSENE
Preparation Date March 20, 2007
Transportation Emergency Response
CHEMTREC: (800) 424-9300
Product Information
Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
KEROSENE 8008-20-6 8% - 12% weight
2-BUTOXYETHANOL 111-76-2 2% - 6% weight
POLY(OXY-1,2-ETHANEDIYL), ALPHA-(4-NONYLPHENYL)-OMEGA-HYDROXY 127087-87-0 2% - 6% weight
LUBRICATING OILS HYDROTREATED SPENT 59-63% 64742-58-1 59% - 63% wt.
PROPANE-ISOBUTANE-n-BUTANE 68476-86-8 19% - 23% wt.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Harmful if inhaled, swallowed, or absorbed through skin.
POTENTIAL HEALTH EFFECTS
CARCINOGENICITY: Product not considered a carcinogen by OSHA, NTP, or IARC.
MEDICAL CONDITIONS: Pre-existing eye or skin conditions may be aggravated by over-exposure to this product.
TARGET ORGANS: Central nervous system, liver, lungs, kidneys.
PRIMARY ENTRY ROUTES: Skin absorption and inhalation.
ACUTE HEALTH EFFECTS
EYE: Will cause irritation upon contact.
SKIN: Prolonged contact with skin can cause irritation. Repeated skin contact may cause persistent irritation and
dermatitis.
INHALATION: Respiratory irritation and dizziness.
INGESTION: Product may cause discomfort, nausea, vomiting, and diarrhea.
CHRONIC HEALTH EFFECTS: Overexposure to the ingredients in this product may cause liver abnormalities, and
kidney damage.
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MSDS: CHAMPION庐 MSDS 4123I
4. FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Seek medical attention.
SKIN CONTACT: Wash area with soap and water. Seek medical attention if irritation persists.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. Seek medical attention. Inhalation hazard
unlikely due to low volatility of product.
INGESTION: DO NOT induce vomiting. Only give CONSCIOUS victim two glasses of water and seek medical attention.
NEVER give UNCONSCIOUS victim anything by mouth.
5. FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.
NFPA RATINGS: Health: 1 Flammability: 2 Reactivity: 0
FLAMMABLE PROPERTIES:
FLASH POINT: BT 120 - 200 F TCC
EXTINGUISHING MEDIA: Carbon Dioxide (CO2), Dry Chemical, Foam.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors are heavier than air and can collect in low areas.
FIRE FIGHTING INSTRUCTIONS: Containers can build up pressure if exposed to fire. Containers should be cooled with
water spray.
FIRE FIGHTING EQUIPMENT: Self contained breathing apparatus with full face piece operated in positive pressure
mode.
6. ACCIDENTAL RELEASE INFORMATION
SPILL/LEAK PROCEDURES: Notify safety personnel, evacuate all unnecessary personnel and provide adequate
ventilation. If feasible and without risk, clean-up personnel should stop leak. All clean-up personnel should wear proper
personal protective equipment.
SMALL SPILL: Clean with inert absorbant and place in recovery drums for disposal.
LARGE SPILL: Dike to prevent further migration of material. DO NOT release into waterways or sewers. Follow
applicable federal and state regulations (20CFR1910.120).
NOTE: Product in aerosol container, spill hazard unlikely.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802
as appropriate or required.
7. HANDLING AND STORAGE
STORAGE REQUIREMENTS: Store in clean, dry locations away from excessive heat. Store in areas designated for the
storage of (Level III) aerosols according to NFPA 30B (Manufacturing and Storage of Aerosol Products).
HANDLING PRECAUTIONS: Wash throughly after handling. Do not get into eyes, on skin, or on clothing. Do not smoke
while using this product. Do not use near excessive heat, sparks, or open flame.
8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
ENGINEERING CONTROLS: Eye wash station and safety shower.
VENTILATION: Strong general ventilation or local exhaust.
PERSONNEL PROTECTIVE EQUIPMENT
EYE: Chemical splash goggles with indirect or no ventilation.
SKIN: Chemical resistant gloves such as nitrile.
RESPIRATORY: Organic vapor air puifying respirator if vapors are a nuisance or if the concentrations are above PEL or
TLV.
COMMENTS: Never eat, drink, or smoke in work areas.
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MSDS: CHAMPION庐 MSDS 4123I
9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT: BT 220 - 440 F
SPECIFIC GRAVITY: BT 0.820 - 0.825
VAPOR PRESSURE: BT 0.4 - 5.0 mmHG
VAPOR DENSITY: BT 4.5 - 6.2 AIR=1
SOLUBILITY IN WATER: Not soluble in water.
ODOR/APPEARANCE/CHARACTERISTICS: Colorless liquid, petroleum distillate odor.
VOC: 35%
10. STABILITY AND REACTIVITY
STABILITY: Material is stable
POLYMERIZATION: Hazardous polymerization cannot occur.
CHEMICAL INCOMPATIBILITIES: Strong oxidizing agents.
CONDITION TO AVOID: Excessive heat and open flame.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, and carbon dioxide.
11. TOXICOLOGY INFORMATION
---------LD50----------------
Kerosene: 28 g/kg (oral)
12. ECOLOGICAL INFORMATION
ECOTOXICITY: No data
ENVIRONMENTAL FATE: No data
13. DISPOSAL INFORMATION
Dispose of in accordance with all applicable state, federal, and local regulations.
14. TRANSPORTATION INFORMATION
DOT DOMESTIC:
*Consumer Commodity ORM-D
EXPORT:
*Aerosols Dispensers, Class 2.1, UN1950, IMCO 9.0, Page 9022.
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
OSHA: Considered hazardous material as defined by 29CFR1910.1200
EPA SARA TITLE III:
-Section 311-312 (40CFR370): If stored in excess of the threshold quantities, this product should be reported as a(n):
*IMMEDIATE (acute) HEALTH HAZARD
*DELAYED (chronic) HEALTH HAZARD
*FIRE HAZARD
*SUDDEN RELEASE HAZARD
-Section 313 (40CFR372): This product contains ingredients which are subject to the reporting requirements of SARA 313:
*2-Butoxyethanol
STATE REGULATIONS
CALIFORNIA PROPOSITION 65: This product does not contain ingredients which are on the current Proposition 65 list.
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MSDS: CHAMPION庐 MSDS 4123I
16. DISCLAIMER
NFPA RATINGS: Health: 1 Flammability: 2 Reactivity: 0
HMIS RATINGS: Health: 1 Flammability: 2 Reactivity: 0
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-
Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the
National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).
NOTES:
*NG="NOT GIVEN" *BT="BETWEEN" *<="LESS THAN" *>="GREATER THAN"
USER'S RESPONSIBILITY: This MSDS provides environmental, health and safety information. This product is to be
used in applications consistent with our product literature and container label. Individuals handling this product should be
informed to the recommended safety precautions and have access to this MSDS. Please contact your local sales
representative or our Environmental, Health and Safety Department for further information.
Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard
(Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.
The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of Champion
Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the particular purpose,
regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no legal responsibility for
use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and
since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the
results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the
material for his particular purpose.
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