MSDS: CHAMPION庐 MSDS 1810 SERIES ALCOHOL (DILUTED) PRODUCTS
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHAMPION庐 MSDS 1810 SERIES ALCOHOL (DILUTED) PRODUCTS
Synonyms:
4105 CHAMPION庐 JACK FROST PREMIX 4086 CHAMPION庐 AIR LOK TIRE SEALANT
Company Identification
Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735
PHONE: 800-821-5693 WEBSITE: www.championbrands.com
CAS Registry Number Not Applicable
Synonyms None
Generic/Chemical Name Mixture
Product Type Petroleum Based Lubricating Oil
Preparation Date October 11, 2007
Transportation Emergency Response
CHEMTREC: (800) 424-9300
Product Information
Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
Methyl Alcohol 67561 < 35.0% weight
Isopropanol 67630 < 35.0% weight
Additives, Non-hazardous Mixture > 65.0% weight
3. HAZARD IDENTIFICATION
IMMEDIATE HEALTH EFFECTS
Eye: Contact with the eyes causes severe irritation. Symptoms may include pain, tearing, reddening, swelling and
impaired vision.
Skin: Toxic; may be harmful in contact with skin. Contact with the skin causes irritation. Skin contact may cause drying
or defatting of the skin. Symptoms may include redness, burning, cracking, itching, and drying.
Ingestion: May be harmful if swallowed. Because of its low viscosity, this material can directly enter the lungs, if
swallowed, or if subsequently vomited. Once in the lungs it is very difficult to remove and can cause severe injury or
death. May be irritating to mouth, throat, and stomach. Symptoms may include pain, nausea, vomiting, and diarrhea.
Inhalation: Toxic; may be harmful or fatal if inhaled. The vapor or fumes from this material may cause respiratory
irritation. Symptoms of respiratory irritation may include coughing and difficulty breathing. Breathing this material at
concentrations above the recommended exposure limits may cause central nervous system effects. Central nervous
system effects may include headache, dizziness, nausea, vomiting, weakness, loss of coordination, blurred vision,
drowsiness, confusion, or disorientation. At extreme exposures, central nervous system effects may include respiratory
depression, tremors or convulsions, loss of consciousness, coma or death.
Target Organs: Contains material that causes damage to the following organs if swallowed or inhaled at concentrations
above the recommended exposure limit: red blood cells (hemolysis) Symptoms of hemolysis: nausea, vomiting,
diarrhea, abdominal pain, dark urine and stool. Contains material that may cause damage to the following organ(s) if
swallowed based on animal data: Eyes (cataracts) Contains material that may cause damage to the following organ(s)
following repeated ingestion based on animal data: Liver Thyroid.
Cancer Information: Based on information currently available this material cannot be classified with regard to
carcinogenicity.
See Section 11 for additional information. Risk depends on duration and level of exposure.
REV DA TE: 10/11/2007 PAGE 1 OF 5
MSDS: CHAMPION庐 MSDS 1810 SERIES ALCOHOL (DILUTED) PRODUCTS
4. FIRST AID MEASURES
Eye: Flush eyes with water immediately while holding the eyelids open. Remove contact lenses, if worn, after initial
flushing, and continue flushing for at least 15 minutes. Get immediate medical attention.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get immediate medical
attention. To remove the material from skin, apply a waterless hand cleaner, mineral oil, or petroleum jelly. Then wash
with soap and water. Discard contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: If swallowed, get immediate medical attention. Do not induce vomiting. Never give anything by mouth to an
unconscious person.
Inhalation: During an emergency, wear an approved, positive pressure air-supplying respirator. Move the exposed
person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical
attention.
Note to Physicians: This material is an aspiration hazard. Potential danger from aspiration must be weighing against
possible oral toxicity when deciding whether to induce vomiting.
5. FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Classified by OSHA as combustible.
NFPA RATINGS: Health: 2 Flammability: 2 Reactivity: 0
FLAMMABLE PROPERTIES:
Flashpoint: >37掳C (> 100掳F) by Tag Closed Cup, ASTM D 56
Autoignition: No Data Available
Flammability (Explosive) Limits (% by volume in air): Lower: Not Determined Upper: Not Determined
EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without
proper protective equipment, including self-contained breathing apparatus.
6. ACCIDENTAL RELEASE INFORMATION
Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this material is
released into the work area, evacuate the area immediately. Monitor area with combustible gas indicator.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further
contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in
Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent
materials or pumping. All equipment used when handling the product must be grounded. A vapor suppressing foam may
be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Where feasible and appropriate,
remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner
consistent with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802
as appropriate or required.
7. HANDLING AND STORAGE
Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive
force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment,
and electrical motors and switches. Fire hazard is greater as liquid temperature rises above 85F. Do not get in eyes, on
skin, or on clothing. Do not taste or swallow. Wash thoroughly after handling. Do not breathe vapor or fumes. Keep out
of the reach of children.
General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems
and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To
minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all
operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable
atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering,
REV DA TE: 10/11/2007 PAGE 2 OF 5
MSDS: CHAMPION庐 MSDS 1810 SERIES ALCOHOL (DILUTED) PRODUCTS
mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer
to OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association
(NFPA 77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended
Practice 2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'.
General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE AND
STORE ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may
rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static
electricity, or other sources of ignition. They may explode and cause injury or death. Empty containers should be
completely drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly.
8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should read and understand all instructions and
limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances.
ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eye/Face Protection: Wear protective equipment to prevent eye contact. Selection of protective equipment may
include safety glasses, chemical goggles, face shields, or a combination depending on the work operations conducted.
Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may include gloves,
apron, boots, and complete facial protection depending on operations conducted. Suggested materials for protective
gloves include: Silver Shield, Viton.
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure
limits for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator that
provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:
Component Agency TWA STEL Ceiling Notation
Methanol ACGIH 200 mg/m3 250 mg/m3 -- A3
Methanol OSHA PEL/VPEL 200 mg/m3 250 mg/m3 -- --
Isopropanol ACGIH 400 mg/m3 500 mg/m3 -- --
Isopropanol OSHA PEL/VPEL 400 mg/m3 500 mg/m3 -- Skin
9. PHYSICAL AND CHEMICAL PROPERTIES
Attention: the data below are typical values and do not constitute a specification.
Vapor Pressure: Not determined
Vapor Density, Air = 1: Not determined
Specific Gravity: Not determined
Solubility: Soluble in water
Percent Volatile: Not determined
Odor: Mild alcohol odor
Appearance: Clear blue to opaque pink
Boiling Point: >80掳C (>176掳F).
REV DA TE: 10/11/2007 PAGE 3 OF 5
MSDS: CHAMPION庐 MSDS 1810 SERIES ALCOHOL (DILUTED) PRODUCTS
10. STABILITY AND REACTIVITY
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling
conditions of temperature and pressure.
Incompatibility With Other Materials: A void contact with acetaldehyde, acids, chlorine, ethylene oxide, isocyanates,
strong oxidizing agents, calcium hypochlorite, zinc. Do not use with aluminum equipment > 120掳F.
Hazardous Decomposition Products: May for carbon dioxide and carbon monoxide
Hazardous Polymerization: Hazardous polymerization will not occur.
11. TOXILOGICAL INFORMATION
IMMEDIATE HEALTH EFFECTS
Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components.
Skin Sensitization:
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or product
components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product
components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or
product components.
ADDITIONAL TOXICOLOGY INFORMATION: No Data.
12. ECOLOGICAL INFORMATION
ECOTOXICITY
The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be kept out
of sewage and drainage systems and all bodies of water.
ENVIRONMENTAL FATE
This material is not expected to be readily biodegradable.
13. DISPOSAL INFORMATION
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria
of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations.
Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct
determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous
waste disposal facility.
14. TRANSPORTATION INFORMATION
The description shown may not apply to all shipping situations such as Consumer Commodity packaging. Consult
49CFR, or appropriate Dangerous Goods Regulations, for additional description requirements (e.g., technical name)
and mode-specific or quantity-specific shipping requirements.
U.S. Department of Transportation Non-Bulk NONE 鈥? Excepted from Hazmat Regulations
(IATA) International Air Dangerous Good Regulations
Proper Shipping Name: Flammable Liquid, n.o.s. (Methanol)
ID #: UN 1993
Class: 3
Hazard Label: Flammable Liquid
PG: III, Ltd. Qty. Packaging Instruction: Y309 (Max qty. per package 10L)
Special Provision: A3
(IMDG) International Maritime Dangerous Goods
Not IMDG regulated according to IMDG Code 鈥? Page 3003 Part 1.1.1
REV DA TE: 10/11/2007 PAGE 4 OF 5
MSDS: CHAMPION庐 MSDS 1810 SERIES ALCOHOL (DILUTED) PRODUCTS
15. REGULATORY INFORMATION
EPCRA 311/312 CATEGORIES: 1. Immediate (Acute) Health Effects: YES
2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactiv Hazard:
ity NO
SARA 302 - 40 CFR 355 APPENDIX A and 313 - 40 CFR 372.65 COMPONENTS:
None.
EPA ACCIDENTAL RELEASE PREVENTION 40 CFR 68:
None.
OSHA PROCESS SAFETY MANAGEMENT 29 CFR 1910:
None.
CHEMICAL INVENTORIES:
AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances (AICS).
CANADA: All the components of this material are on the Canadian Domestic Substances List (DSL).
EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment Directive
92/32/EEC.
JAPAN: All the components of this product are on the Existing & New Chemical Substances (ENCS) inventory in Japan,
or have an exemption from listing.
KOREA: This material contains components that require notification before sale or importation into Korea.
PHILIPPINES: All the components of this product are listed on the Philippine Inventory of Chemicals and Chemical
Substances (PICCS).
UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical
Inventory.
NEW JERSEY RTK CLASSIFICATION: Refer to components listed in Section 2.
PENNSYLVANIA RTK CLASSIFICATION: Refer to components listed in Section 2.
CALIFORNIA PROPOSITION 65: None.
16. DISCLAIMER
NFPA RATINGS: Health: 2 Flammability: 2 Reactivity: 0
HMIS RATINGS: Health: 2 Flammability: 2 Reactivity: 0
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-
Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the
National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).
REVISION STATEMENT: Revision updates many sections and the MSDS should be read in its entirety.
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
CAS - Chemical Abstract Service Number
ACGIH - American Conference of Government Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods Code
API - American Petroleum Institute MSDS - Material Safety Data Sheet
NFPA - National Fire Protection Association (USA)
CHA - Champion LLC
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
IARC - International Agency for Research on Cancer OSHA - Occupational Safety and Health Administration
Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard
(Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.
The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of Champion
Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the particular purpose,
regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no legal responsibility for
use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and
since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the
results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the
material for his particular purpose.
REV DA TE: 10/11/2007 PAGE 5 OF 5
|