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MSDS Material Safety Data Sheet
CAS

68476-86-8
107-21-1
1336-21-6

File Name: championbrands_com---4086.asp
                                                                                                                    M S D S : C H A M P I O N 庐 MSDS 4 0 8 6 K
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHAMPION庐 MSDS 4086K
Synonyms:
4086K CHAMPION庐 AIR LOK EMERGENCY TIRE INFLATER

Company Identification
Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735
PHONE: 800-821-5693 WEBSITE: www.championbrands.com

CAS Registry Number Not Applicable
Synonyms None
Generic/Chemical Name NA
Product Type AEROSOL TIRE CARE PRODUCT CONTAINING AN AQUEOUS
SOLUTION OF ETHYLENE GLYCOL
Preparation Date March 20, 2007
Transportation Emergency Response
CHEMTREC: (800) 424-9300
Product Information
Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com
2. COMPOSITION/INFORMATION ON INGREDIENTS

COMPONENTS CAS NUMBER AMOUNT
PROPANE-ISOBUTANE-n-BUTANE 68476-86-8 18% - 22% weight
ETHYLENE GLYCOL 107-21-1 1% - 5% weight
AMMONIUM HYDROXIDE 1336-21-6 < 1 % weight

3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Prolonged contact with skin may cause moderate irritation. Harmful if swallowed or if eye
contact occurs.

POTENTIAL HEALTH EFFECTS
CARCINOGENICITY: Product not considered a carcinogen by OSHA, NTP, or IARC.
MEDICAL CONDITIONS: Pre-existing eye or skin conditions may be aggravated by over-exposure to this product.
TARGET ORGANS: Liver, kidneys.
PRIMARY ENTRY ROUTES: Ingestion, inhalation.

ACUTE HEALTH EFFECTS
EYE: Will cause irritation upon contact.
SKIN: Prolonged contact with skin can cause irritation. Repeated skin contact may cause persistent irritation and
dermatitis.
INHALATION: Respiratory irritation and dizziness.
INGESTION: Large dose can be fatal.

CHRONIC HEALTH EFFECTS: None known.




REV DATE: 3/20/2007 PAGE 1 OF 4
MSDS: CHAMPION庐 MSDS 4086K
4. FIRST AID MEASURES

EYE CONTACT: Immediately flush eyes with plenty of water for 15 minutes. Seek medical attention.

SKIN CONTACT: Wash area with soap and water. Seek medical attention if irritation persists.

INHALATION: Remove to fresh air. If not breathing, give artificial respiration. Seek medical attention. Inhalation hazard
unlikely due to low volatility of product.

INGESTION: INDUCE vomiting. Only give CONSCIOUS victim two glasses of water and seek medical attention. NEVER
give UNCONSCIOUS victim anything by mouth.

5. FIRE FIGHTING MEASURES

FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Not classified by OSHA as flammable or combustible.

NFPA RATINGS: Health: 1 Flammability: 0 Reactivity: 0
FLAMMABLE PROPERTIES:
FLASH POINT: NG
EXTINGUISHING MEDIA: Carbon Dioxide (CO2), Dry Chemical, Foam.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
FIRE FIGHTING INSTRUCTIONS: Containers can build up pressure if exposed to fire. Containers should be cooled with
water spray.
FIRE FIGHTING EQUIPMENT: Self contained breathing apparatus with full face piece operated in positive pressure
mode.

6. ACCIDENTAL RELEASE INFORMATION
SPILL/LEAK PROCEDURES: Notify safety personnel, evacuate all unnecessary personnel and provide adequate
ventilation. If feasible and without risk, clean-up personnel should stop leak. All clean-up personnel should wear proper
personal protective equipment.
SMALL SPILL: Clean with inert absorbant and place in recovery drums for disposal.
LARGE SPILL: Dike to prevent further migration of material. DO NOT release into waterways or sewers. Follow
applicable federal and state regulations (20CFR1910.120).
NOTE: Product in aerosol container, spill hazard unlikely.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802
as appropriate or required.

7. HANDLING AND STORAGE
STORAGE REQUIREMENTS: Store in clean, dry locations away from excessive heat.

HANDLING PRECAUTIONS: Wash throughly after handling. Do not get into eyes, on skin, or on clothing.

8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
ENGINEERING CONTROLS: Eye wash station and safety shower.
VENTILATION: General ventilation. Material non-volatile.
PERSONNEL PROTECTIVE EQUIPMENT
EYE: Chemical splash goggles with indirect or no ventilation.
SKIN: None required under normal use.
RESPIRATORY: None required under normal use.
COMMENTS: Never eat, drink, or smoke in work areas.




REV DATE: 3/20/2007 PAGE 2 OF 4
MSDS: CHAMPION庐 MSDS 4086K
9. PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT: > 212 F

SPECIFIC GRAVITY: 1.025

pH: 10.25

ODOR/APPEARANCE/CHARACTERISTICS: White milky liquid, ammonia odor.

10. STABILITY AND REACTIVITY
STABILITY: Material is stable
POLYMERIZATION: Hazardous polymerization cannot occur.
CHEMICAL INCOMPATIBILITIES: Strong oxidizing agents.
CONDITION TO AVOID: Excessive heat and open flame.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, and carbon dioxide.

11. TOXICOLOGY INFORMATION
-------------LD50--------------------
Ammonium Hydroxide: 350 mg/kg (oral)
Ethylene Glycol: 8.54 mg/kg (oral)o data.

12. ECOLOGICAL INFORMATION

ECOTOXICITY: No data

ENVIRONMENTAL FATE: No data

13. DISPOSAL INFORMATION
Dispose of in accordance with all applicable state, federal, and local regulations.

14. TRANSPORTATION INFORMATION
DOT DOMESTIC:
*Not regulated
EXPORT:
*Aerosols Dispensers, Class 2.1, UN1950, IMCO 9.0, Page 9022.

15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
OSHA: Considered hazardous material as defined by 29CFR1910.1200
EPA SARA TITLE III:
-Section 311-312 (40CFR370): If stored in excess of the threshold quantities, this product should be reported as a(n):
*IMMEDIATE (acute) HEALTH HAZARD
*DELAYED (chronic) HEALTH HAZARD
*SUDDEN RELEASE HAZARD
-Section 313 (40CFR372): This product contains ingredients which are subject to the reporting requirements of SARA 313:
*Ethylene Glycol
STATE REGULATIONS
CALIFORNIA PROPOSITION 65: This product does not contain ingredients which are on the current Proposition 65 list.
NEW JERSEY RIGHT-TO-KNOW: This product contains the following ingredients which are non-hazardous, but are
among the top five ingredients in this product:
------CAS#-------
7732-18-5: Water
24937-78-7: Polymer



REV DATE: 3/20/2007 PAGE 3 OF 4
MSDS: CHAMPION庐 MSDS 4086K
16. DISCLAIMER
NFPA RATINGS: Health: 1 Flammability: 0 Reactivity: 0
HMIS RATINGS: Health: 1 Flammability: 0 Reactivity: 0
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-
Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the
National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).

NOTES:
*NG="NOT GIVEN" *BT="BETWEEN" *<="LESS THAN" *>="GREATER THAN"

USER'S RESPONSIBILITY: This MSDS provides environmental, health and safety information. This product is to be
used in applications consistent with our product literature and container label. Individuals handling this product should be
informed to the recommended safety precautions and have access to this MSDS. Please contact your local sales
representative or our Environmental, Health and Safety Department for further information.

Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard
(Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.

The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of Champion
Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the particular purpose,
regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no legal responsibility for
use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and
since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the
results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the
material for his particular purpose.




REV DATE: 3/20/2007 PAGE 4 OF 4

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