MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
Synonyms:
4117 CHAMPION庐 105 FLASH SOLVENT (MINERAL SPIRITS) 4244 CHAMPION庐 SG PENETRATING OIL
4122 CHAMPION庐 5 MINUTE MOTOR FLUSH 4306 CHAMPION庐 SUPER VALVE SHIELD
Company Identification
Champion Brands, L.L.C., 1001 Golden Drive, Clinton, MO 64735
PHONE: 800-821-5693 WEBSITE: www.championbrands.com
CAS Registry Number Not Applicable
Synonyms None
Generic/Chemical Name Mixture
Product Type Petroleum Based Color Dye
Preparation Date February 22, 2008
Transportation Emergency Response
CHEMTREC: (800) 424-9300
Product Information
Product Information and MSDS Requests: (800) 821-5693 and www.championbrands.com
2. COMPOSITION/INFORMATION ON INGREDIENTS
COMPONENTS CAS NUMBER AMOUNT
Aliphatic Hydrocarbons (Stoddard Type) 8052413 < 15.0% weight
1,3,5-Trimethylbenzene 108678 < 1.0% weight
1,2,4-Trimethylbenzene 95636 < 1.0% weight
Xylene 1330207 > 3.0% weight
Ethylbenzene 100414 4.3 鈥? 10.2% weight
Dipropylene glycol monomethyl ether 34590948 0.0 鈥? 4.3% weight
Base Oil, Distillates, Hydrotreated, Petroleum Hydrocarbon Mixture > 3.0% weight
The BASE OIL may be a mixture of any of the following: CAS 64741884, CAS 64741895, CAS 64741964, CAS 64741975, CAS
64742014, CAS 64742525, CAS 64742536, CAS 64742547, CAS 64742558, CAS 64742570, CAS 64742627
The COLORANT ADDITIVES are a mixture of any of the following: CAS 74499368, CAS 2475447, CAS 29887089, CAS 75476947,
CAS 91696263, CAS 91696321, CAS 91696309
3. HAZARD IDENTIFICATION
PRIMARY ROUTES OF EXPOSURE
INHALATION
EYE CONTACT
SKIN CONTACT
DERMAL ABSORPTION
IMMEDIATE EFFECTS
Eye Contact: Contact with the eyes causes severe irritation. Symptoms may include pain, tearing, reddening, swelling
and impaired vision.
Skin Contact: Contact with the skin causes irritation. Skin contact may cause drying or defatting of the skin. Symptoms
may include pain, itching, discoloration, swelling, and blistering.
Ingestion: May be harmful if swallowed. Symptoms may include pain, nausea, vomiting, and diarrhea.
Inhalation: The vapor or fumes from this material may cause respiratory irritation. Symptoms of respiratory irritation may
include coughing and difficulty breathing. Central nervous system effects may include headache, dizziness, nausea,
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MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
vomiting, weakness, loss of coordination, blurred vision, drowsiness, confusion, or disorientation. At extreme exposures,
central nervous system effects may include respiratory depression, tremors or convulsions, loss of consciousness, coma
or death.
DELAYED OR OTHER HEALTH EFFECTS:
Prolonged or repeated overexposure to xylene can cause the following: reversible liver and kidney impairment.
Prolonged or repeated overexposure to ethylbenzene can cause the following: kidney, liver, lung, pituitary, thyroid and
testicular effects. Ethylbenzene has been listed by the International Agency for Research on Cancer (IARC).
Prolonged or repeated overexposure to dipropylene glycol monomethyl ether can cause the following: kidney and liver
effects.
4. FIRST AID MEASURES
Eye: Flush eyes with water immediately while holding the eyelids open. Remove contact lenses, if worn, after initial
flushing, and continue flushing for at least 15 minutes. Get immediate medical attention.
Skin: Wash skin with water immediately and remove contaminated clothing and shoes. Get immediate medical attention.
To remove the material from skin, apply a waterless hand cleaner, mineral oil, or petroleum jelly. Then wash with soap
and water. Discard contaminated clothing and shoes or thoroughly clean before reuse.
Ingestion: If swallowed, give 2 glasses of water to drink, get immediate medical attention. Do not induce vomiting. Never
give anything by mouth to an unconscious person.
Inhalation: Move the exposed person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get immediate medical attention.
Note to Physicians: Ingestion of this product or subsequent vomiting may result in aspiration of light hydrocarbon liquid,
which may cause pneumonitis.
5. FIRE FIGHTING MEASURES
FIRE CLASSIFICATION:
OSHA Classification (29 CFR 1910.1200): Flammable Liquid Class 1B
NFPA RATINGS: Health: 2 Flammability: 2 Reactivity: 0
FLAMMABLE PROPERTIES:
Flashpoint: > 38 掳C (>100 掳F) Pensky-Martens Closed Cup
Autoignition: Xylene 466 - 530 掳C (874 - 986 掳F)
Flammability (Explosive) Limits (% by volume in air): LEL = 1.0% UEL = 14% DPGME
EXTINGUISHING MEDIA: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
PROTECTION OF FIRE FIGHTERS:
Fire Fighting Instructions: For fires involving this material, do not enter any enclosed or confined fire space without
proper protective equipment, including self-contained breathing apparatus.
Combustion Products: Highly dependent on combustion conditions. A complex mixture of airborne solids, liquids, and
gases including carbon monoxide, carbon dioxide, and unidentified organic compounds will be evolved when this
material undergoes combustion. Combustion may form oxides of: Nitrogen.
6. ACCIDENTAL RELEASE INFORMATION
Protective Measures: Eliminate all sources of ignition in the vicinity of the spill or released vapor. If this material is
released into the work area, evacuate the area immediately. Monitor area with combustible gas indicator.
Spill Management: Stop the source of the release if you can do it without risk. Contain release to prevent further
contamination of soil, surface water or groundwater. Clean up spill as soon as possible, observing precautions in
Exposure Controls/Personal Protection. Use appropriate techniques such as applying non-combustible absorbent
materials or pumping. All equipment used when handling the product must be grounded. A vapor suppressing foam may
be used to reduce vapors. Use clean non-sparking tools to collect absorbed material. Where feasible and appropriate,
remove contaminated soil. Place contaminated materials in disposable containers and dispose of in a manner consistent
with applicable regulations.
Reporting: Report spills to local authorities and/or the U.S. Coast Guard's National Response Center at (800) 424-8802
as appropriate or required.
7. HANDLING AND STORAGE
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MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
Precautionary Measures: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive
force. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and
electrical motors and switches. Fire hazard is greater as liquid temperature rises above 85F. Do not get in eyes, on skin,
or on clothing. Do not taste or swallow. Wash thoroughly after handling. Do not breathe vapor or fumes. Keep out of the
reach of children.
General Handling Information: Avoid contaminating soil or releasing this material into sewage and drainage systems
and bodies of water.
Static Hazard: Electrostatic charge may accumulate and create a hazardous condition when handling this material. To
minimize this hazard, bonding and grounding may be necessary but may not, by themselves, be sufficient. Review all
operations which have the potential of generating and accumulating an electrostatic charge and/or a flammable
atmosphere (including tank and container filling, splash filling, tank cleaning, sampling, gauging, switch loading, filtering,
mixing, agitation, and vacuum truck operations) and use appropriate mitigating procedures. For more information, refer to
OSHA Standard 29 CFR 1910.106, 'Flammable and Combustible Liquids', National Fire Protection Association (NFPA
77, 'Recommended Practice on Static Electricity', and/or the American Petroleum Institute (API) Recommended Practice
2003, 'Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents'.
General Storage Information: DO NOT USE OR STORE near heat, sparks, flames, or hot surfaces . USE AND STORE
ONLY IN WELL VENTILATED AREA. Keep container closed when not in use.
Container Warnings: Container is not designed to contain pressure. Do not use pressure to empty container or it may
rupture with explosive force. Empty containers retain product residue (solid, liquid, and/or vapor) and can be dangerous.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose such containers to heat, flame, sparks, static electricity,
or other sources of ignition. They may explode and cause injury or death. Empty containers should be completely
drained, properly closed, and promptly returned to a drum reconditioner or disposed of properly.
8. EXPOSURE CONTROL/PERSONAL PROTECTIVE EQUIPMENT
GENERAL CONSIDERATIONS:
Consider the potential hazards of this material (see Section 3), applicable exposure limits, job activities, and other
substances in the work place when designing engineering controls and selecting personal protective equipment. If
engineering controls or work practices are not adequate to prevent exposure to harmful levels of this material, the
personal protective equipment listed below is recommended. The user should read and understand all instructions and
limitations supplied with the equipment since protection is usually provided for a limited time or under certain
circumstances.
ENGINEERING CONTROLS:
Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below the
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eye/Face Protection: Wear protective equipment to prevent eye contact. Selection of protective equipment may include
safety glasses, chemical goggles, face shields, or a combination depending on the work operations conducted.
Skin Protection: Wear protective clothing to prevent skin contact. Selection of protective clothing may include gloves,
apron, boots, and complete facial protection depending on operations conducted. Suggested materials for protective
gloves include: Silver Shield, Viton.
Respiratory Protection: Determine if airborne concentrations are below the recommended occupational exposure limits
for jurisdiction of use. If airborne concentrations are above the acceptable limits, wear an approved respirator that
provides adequate protection from this material, such as: Air-Purifying Respirator for Organic Vapors.
Use a positive pressure air-supplying respirator in circumstances where air-purifying respirators may not provide
adequate protection.
Occupational Exposure Limits:
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MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
Component Agency TWA STEL Ceiling Notation
Ethylbenzene ACGIH 100 mg/m3 545 mg/m3 -- A3
Ethylbenzene OSHA PEL/VPEL 100 mg/m3 435 mg/m3 -- --
Aliphatic Hydrocarbons (Stoddard Tyupe) ACGIH 100 mg/m3 -- -- --
Aliphatic Hydrocarbons (Stoddard Tyupe) OSHA PEL/VPEL 500/100 mg/m3 -- -- Skin
Xylene ACGIH TLV 100 mg/m3 655 mg/m3 -- Skin A3
Xylene OSHA PEL/VPEL 100 mg/m3 655 mg/m3 -- --
Xylene NIOSH REL 435 mg/m3 868 mg/m3 --
Dipropylene glycol monomethyl ether ACGIH TLV 100 mg/m3 150 mg/m3 -- --
Dipropylene glycol monomethyl ether OSHA PEL/VPEL 100 mg/m3 150 mg/m3 -- --
9. PHYSICAL AND CHEMICAL PROPERTIES
Attention: the data below are typical values and do not constitute a specification.
Color: Dark Blue, Red, or Green
Physical State: Liquid
Odor: Hydrocarbon odor
pH: Not Applicable
Vapor Pressure: 5 to 6.6 mm Hg @ 20 掳C Xylene
Vapor Density (Air = 1): 3.6 Xylene
%Volatility: <56% approx.
Boiling Point: 137 to 144 掳C
Solubility: Insoluble
Freezing Point: No Data Available
Specific Gravity: 0. 96 @ 15.6掳C (60掳F)
Viscosity: >3.8 cSt @ 20掳C (68掳F)
10. STABILITY AND REACTIVITY
Chemical Stability: This material is considered stable under normal ambient and anticipated storage and handling
conditions of temperature and pressure.
Incompatibility With Other Materials: May react with strong acids, strong alkalis and strong oxidizing agents.
Hazardous Decomposition Products: None known.
Hazardous Polymerization: Hazardous polymerization will not occur.
11. TOXILOGICAL INFORMATION
IMMEDIATE HEALTH EFFECTS
Eye Irritation: The eye irritation hazard is based on evaluation of data for similar materials or product components.
Skin Irritation: The skin irritation hazard is based on evaluation of data for similar materials or product components.
Skin Sensitization:
Acute Dermal Toxicity: The acute dermal toxicity hazard is based on evaluation of data for similar materials or product
components.
Acute Oral Toxicity: The acute oral toxicity hazard is based on evaluation of data for similar materials or product
components.
Acute Inhalation Toxicity: The acute inhalation toxicity hazard is based on evaluation of data for similar materials or
product components.
ADDITIONAL TOXICOLOGY INFORMATION:
Component ACUTE ORAL LD50 ACUTE DERMAL LD50 ACUTE INHALATION LC50
Ethylbenzene NO DATA AVAILABLE NO DATA AVAILABLE 17,360 MG/M3 (RAT)(4H)
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MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
Xylene 4.3 G/KG (RAT) >3.95 ML/KG (RABBIT) 6,700 PPM (RAT)(4H)
1,3,5-Trimethylbenzene NO DATA AVAILABLE NO DATA AVAILABLE 24 MG/M3 (RAT)(4H)
1,2,4-Trimethylbenzene 6.0 G/KG (RAT) NO DATA AVAILABLE 24 MG/M3 (RAT)(4H)
Cancer: Ethylbenzene has indicated that lifetime inhalation exposure of rats and mice resulted in increases in certain
types of cancer at 750 ppm, including kidney tumors in rats and lung cancer tumors in mice. Incidences of testicular
adenoma were increased along with increased incidences of thyroid effects in rats at 750 ppm; pituitary effects were
observed in female mice at 250 ppm. These effects were not observed in animals exposed to ethylbenzene at 75 ppm.
Mutagen: No Data
12. ECOLOGICAL INFORMATION
ECOTOXICITY
The toxicity of this material to aquatic organisms has not been evaluated. Consequently, this material should be kept out
of sewage and drainage systems and all bodies of water.
ENVIRONMENTAL FATE
This material is not expected to be readily biodegradable.
13. DISPOSAL INFORMATION
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of
a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement
of certain physical properties and analysis for regulated components may be necessary to make a correct determination.
If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal
facility.
14. TRANSPORTATION INFORMATION
The description shown may not apply to all shipping situations. Consult 49CFR, or appropriate Dangerous Goods
Regulations, for additional description requirements (e.g., technical name) and mode-specific or quantity-specific
shipping requirements.
DEPARTMENT OF TRANSPORTATION
PACKAGED CLASSIFICATION: ORM -D
DOT Shipping Name: CONSUMER COMMODITY
BULK CLASSIFICATION:
IMDG: UN1268, PETROLEUM DISTILLATES, N.O.S. 3, III
IATA_P: UN1268, Petroleum distillates, n.o.s. 3, III
IATA_C: UN1268, Petroleum distillates, n.o.s. 3, III
CFR_ROAD: UN1268, Petroleum distillates, n.o.s. (Aliphatic Petroleum Distillates,) 3, III
CFR_RAIL: UN1268, Petroleum distillates, n.o.s. (Aliphatic Petroleum Distillates,) 3, III
CFRJNWTR: UN1268, Petroleum distillates, n.o.s. (Aliphatic Petroleum Distillates,) 3, III
IMDGJNWTR: UN1268, PETROLEUM DISTILLATES, N.O.S. 3, III
IMDG_ROAD: UN1268, PETROLEUM DISTILLATES, N.O.S. 3, III
IMDG_RAIL: UN1268, PETROLEUM DISTILLATES, N.O.S. 3, III
15. REGULATORY INFORMATION
SARA TITLE 3: Section 311/312 CATEGORIES:
1. Immediate (Acute) Health Effects: YES
2. Delayed (Chronic) Health Effects: YES
3. Fire Hazard: YES
4. Sudden Release of Pressure Hazard: NO
5. Reactivity Hazard: NO
SARA TITLE 3: Section 313 INFORMATION:
This product contains a chemical which is listed in Section 313 at or above de minimis concentrations. The following
listed chemicals are present (Quantity present and CAS are found in section 2.)
Ethylbenzene
Xylene
CERCLA INFORMATION:
This material is regulated under the Comprehensive Environmental Response, Compensation, and Liability Act
(CERCLA) and the Superfund Amendments and Reauthorization Act (SARA) Title III Section 304. This material is, or
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MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
contains, chemicals listed in 40 CFR Table 302.4 or no designated RCRA ISC substances. The reportable Quantity(s)
(RQ) are listed below. Releases in excess of its reportable quantity must be reported to the National Response Center
(800 424-8802) and to the appropriate state and local emergency response organizations.
Ethylbenzene 1000 LBS
Xylene 100 LBS
RCRA WASTE DISPOSAL CLASS: D001, Ignitable
CHEMICAL INVENTORIES:
AUSTRALIA: All the components of this material are listed on the Australian Inventory of Chemical Substances (AICS).
CANADA: All the components of this material are on the Canadian Domestic Substances List (DSL).
EUROPEAN UNION: All the components of this material are in compliance with the EU Seventh Amendment Directive
92/32/EEC.
JAPAN: All the components of this product are on the Existing & New Chemical Substances (ENCS) inventory in Japan,
or have an exemption from listing.
KOREA: This material contains components that require notification before sale or importation into Korea.
PHILIPPINES: All the components of this product are listed on the Philippine Inventory of Chemicals and Chemical
Substances (PICCS).
UNITED STATES: All of the components of this material are on the Toxic Substances Control Act (TSCA) Chemical
Inventory.
STATE REGULATORY INFORM ATION:
THE FOLLOWING CHEMICALS ARE SPECIFICALLY LISTED BY INDIVIDUAL STATES; OTHER PRODUCT
SPECIFIC HEALTH AND SAFETY DATA IN OTHER SECTIONS OF THE MSDS MAY ALSO BE APPLICABLE FOR
STATE REQUIREMENTS. FOR DETAILS ON YOUR REGULATORY REQUIREMENTS YOU SHOULD CONTACT
THE APPROPRIATE AGENCY IN YOUR STATE.
STATE LISTED COMPONENT CAS NO PERCENT STATE CODE
1,2,4-TRIMETHYL BENZENE 95-63-6 <1 MA, NJ, PA, CA, MN
1,3,5-TRIMETHYL BENZENE 108-67-8 <1 MA, NJ
XYLENE 95-47-6 <3 CA, FL, MA, NJ, PA, RI, IL
CA = CALIFORNIA HAZ. SUBST. LIST LA = LOUISIANA HAZ. SUBST. LIST
CA65C, CA65R, CA65C/R = CALIFORNIA SAFE DRINKING MA = MASSACHUSETTS SUBST. LIST
WATER AND TOXICS ENFORCEMENT ACT OF 1986 OR ME = MAINE HAZ. SUBST. LIST
PROPOSITION 65 LIST MN = MINNESOTA HAZ. SUBST. LIST
CT = CONNECTICUT TOXIC. SUBST. LIST NJ = NEW JERSEY HAZ. SUBST. LIST
FL = FLORIDA SUBST. LIST PA = PENNSYLVANIA HAZ. SUBST. LIST
IL = ILLINOIS TOXIC SUBST. LIST RI = RHODEISLAND HAZ. SUBST. LIST.
WHMIS CLASSIFICATION:
Class B, Division 3: Flammable Liquids
Class D, Division 1, Subdivision B: Toxic Material -Acute Lethality
Class D, Division 2, Subdivision A: Very Toxic Material -Carcinogenicity
Class D, Division 2, Subdivision B: Toxic Material -Chronic Toxic Effects Skin or Eye Irritation.
16. DISCLAIMER
NFPA RATINGS: Health: 1 Flammability: 2 Reactivity: 0
HMIS RATINGS: Health: 0 Flammability: 2 Reactiv 0
ity:
(0-Least, 1-Slight, 2-Moderate, 3-High, 4-Extreme, PPE:- Personal Protection Equipment Index recommendation, *-
Chronic Effect Indicator). These values are obtained using the guidelines or published evaluations prepared by the
National Fire Protection Association (NFPA) or the National Paint and Coating Association (for HMIS ratings).
REVISION STATEMENT: Revision updates many sections and the MSDS should be read in its entirety.
ABBREVIATIONS THAT MAY HAVE BEEN USED IN THIS DOCUMENT:
TLV - Threshold Limit Value TWA - Time Weighted Average
STEL - Short-term Exposure Limit PEL - Permissible Exposure Limit
OSHA - Occupational Safety and Health Administration CAS - Chemical Abstract Service Number
ACGIH - American Conference of Government Industrial Hygienists IMO/IMDG - International Maritime Dangerous Goods Code
API - American Petroleum Institute MSDS - Material Safety Data Sheet
IARC - International Agency for Research on Cancer NFPA - National Fire Protection Association (USA)
DOT - Department of Transportation (USA) NTP - National Toxicology Program (USA)
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MSDS: CHAMPION庐 MSDS 1600 SERIES SOLVENT PRODUCTS
Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and the ANSI MSDS Standard
(Z400.1) by Champion LLC, 1001 Golden Drive, Clinton, Missouri 64735.
The information presented herein has been compiled from sources considered to be dependable and is accurate to the best knowledge of Champion
Brands, L.L.C. Champion Brands, L.L.C., makes no warranty whatsoever expressed or implied of merchantability or fitness for the particular purpose,
regarding the accuracy of such data or the results to be obtained from the use thereof. Champion Brands, L.L.C., assumes no legal responsibility for
use or reliance upon this data. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and
since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the
results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the
material for his particular purpose.
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