Product Name: Bumper 250 EC Fungicide
Page: 1 of 5
This revision issued: June, 2005
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Propiconazole is an azole derived fungicide.
Bumper 250 EC Fungicide
Trade Name:
Product Use: Agricultural fungicide for use as described on the product label.
Creation Date: June, 2005
Revision Date: June, 2005
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Not classified as hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: Not Hazardous - No criteria found.
Safety Phrases: Not Hazardous - No criteria found.
SUSDP Classification: S6
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Clear, amber coloured liquid.
Odour: Characteristic odour.
Major Health Hazards: no significant risk factors have been found for this product.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. In addition product is unlikely to cause any discomfort or irritation.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product may be irritating to eyes, but is
unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. However, this product may be
irritating to mucous membranes but is unlikely to cause anything more than transient discomfort.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Propiconazole 60207-90-1 25 not set not set
Ethoxylated castor oil 61791-12-6 10-20 not set not set
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Bumper 250 EC Fungicide
Page: 2 of 5
This revision issued: June, 2005
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Gently blot away excess liquid. Wash gently and thoroughly with water (use non-abrasive soap if
necessary) for 5 minutes or until chemical is removed.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing
water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more
than a few minutes.
Ingestion: If product is swallowed or gets in mouth, wash mouth with water and give some water to drink. If
symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as flammable. There is a slight risk of an explosion from
this product if commercial quantities are involved in a fire. Violent steam generation or eruption may occur upon
application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate
in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back
considerable distances.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: >64掳C
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: Flammable
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. As a
minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include rubber, PVC. Eye/face
protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours
or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is
necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned
below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Bumper 250 EC Fungicide
Page: 3 of 5
This revision issued: June, 2005
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store in the closed original container in a dry, cool, well-ventilated area out of direct
sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in
Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check
packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
The ADI for Propiconazole is set at 0.04mg/kg/day. The corresponding NOEL is set at 4mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2004.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Clear, amber coloured liquid.
Odour: Characteristic odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No specific data. Expected to be low at 100掳C.
Vapour Pressure: No data. Expected to be low at 20掳C
Vapour Density: No data.
Specific Gravity: Approx 1.0 at 20掳C
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Hydrogen
chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness,
nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma
and death.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Bumper 250 EC Fungicide
Page: 4 of 5
This revision issued: June, 2005
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Toxicity: For Propiconazole:
LD50 Oral (Rat) 1517mg/kg LD50 Oral (Mouse) 1419mg/kg
LD50 Dermal (Rat) >4000mg/kg LD50 Dermal (Rabbit) >6000mg/kg
LC50 Inhal (Rat, 4hr) >5800mg/m3
Section 12 - Ecological Information
This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
For Propiconazole:
Birds: LD50 Japanese quail: 2223mg/kg LD50 Bobwhite quail: >2825mg/kg
LD50 mallard ducks: >2510mg/kg
Fish: LC50 carp: 6.8mg/L LC50 rainbow trout: 5.3mg/L
LC50 golden orfe: 5.1mg/L
Algae: EC50 0.02-13.6mg/L
Bees: not toxic to bees
Daphnia: EC50 4.8mg/L
After oral administration to the rat, Propiconazole is rapidly absorbed and also rapidly and almost completely
eliminated with urine and faeces. Residues in tissues were generally low and there was no evidence for accumulation
or retention of Propiconazole or its metabolites. The major sites of enzymatic attack are the propyl side-chain and the
cleavage of the dioxolane ring, together with some attack at the 2,4-dichlorophenyl and 1,2,4-triazole rings. In the
mouse, the major metabolic pathway is via cleavage of the dioxolane ring.
Plants: Degradation proceeds through hydroxylation of the n-propyl side-chain and deketalisation of the dioloxane
ring. After cleavage of triazole, triazole-alanine is formed as the main metabolite. Metabolites are conjugated mostly
as glucosides.
The main degradation pathways are hydroxylation of the propyl side-chain and the dioxolane ring, and finally
formation of the 1,2,4-triazole. Koc (ads) 950ml/g, immobile in soil.
Section 13 - Disposal Considerations
Disposal: Instructions concerning the disposal of this product and its containers are given on the product label.
These should be carefully followed.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
The following ingredients: Propiconazole, are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Bumper 250 EC Fungicide
Page: 5 of 5
This revision issued: June, 2005
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, June, 2005.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
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