Product Name: Farmoz Fairgro Liquid Fungicidal Seed Dressing
Page: 1 of 6
This revision issued: August, 2008
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Thiram is a dimethyldithiocarbamate derivative; Thiabendazole is a benzimidazole
derivative.
Farmoz Fairgro Liquid Fungicidal Seed Dressing
Trade Name:
Product Use: Agricultural fungicide for use as described on the product label.
Creation Date: June, 2005
Revision Date: August, 2008
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Note: This product range is classed as a MARINE POLLUTANT only and so the Dangerous Goods classification
which follows is for MARINE transport only. Not classed as a Dangerous Good for Storage or Road and Rail
transport.
Risk Phrases: R40, R43, R40/20/22, R36/37, R51. Possible risk of irreversible effects. May cause sensitisation by
skin contact. Harmful: possible risk of irreversible effects through inhalation, and if swallowed. Irritating to eyes and
respiratory system. Toxic to aquatic organisms.
Safety Phrases: S2, S20, S23, S26, S28, S38, S46, S24/25, S36/37/39. Keep out of reach of children. When using,
do not eat or drink. Do not breathe vapours or mists. In case of contact with eyes, rinse immediately with plenty of
water and contact a doctor or Poisons Information Centre. After contact with skin, wash immediately with plenty of
soap and water. In case of insufficient ventilation, wear suitable respiratory equipment. If swallowed, contact a doctor
or Poisons Information Centre immediately and show this container or label. Avoid contact with skin and eyes. Wear
suitable protective clothing, gloves and eye/face protection.
SUSDP Classification: S6
ADG Classification: Class 9 (ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., contains
Thiabendazole and Thiram)
UN Number: 3082
Emergency Overview
Physical Description & colour: Opaque green liquid.
Odour: Mild odour.
Major Health Hazards: Thiram is irritating to the eyes, skin, and respiratory tract. It is a skin sensitizer. Symptoms
of acute inhalation exposure to Thiram include itching, scratchy throat, hoarseness, sneezing, coughing, inflammation
of the nose or throat, bronchitis, dizziness, headache, fatigue, nausea, diarrhoea, and other gastrointestinal
complaints. Persons with chronic respiratory or skin disease are at increased risk from exposure to Thiram. Ingestion
of Thiram and alcohol together may cause stomach pains, nausea, vomiting, headache, slight fever, and possible
dermatitis. May cause irreversible effects, harmful by inhalation and if swallowed, irritating to eyes and respiratory
system, possible skin sensitiser.
Potential Health Effects
See section 11 for Chronic exposure studies.
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data shows that this
product is harmful, but symptoms are not available. In addition product is an inhalation irritant. Symptoms may include
headache, irritation of nose and throat and increased secretion of mucous in the nose and throat. Other symptoms
may also become evident, but they should disappear after exposure has ceased.
Skin Contact:
Short term exposure: Classified as a potential sensitiser by skin contact. Exposure to a skin sensitiser, once
sensitisation has occurred, may manifest itself as skin rash or inflammation, and in some individuals this reaction can
be severe. However product is unlikely to cause any discomfort in normal use.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Fairgro Liquid Fungicidal Seed Dressing
Page: 2 of 6
This revision issued: August, 2008
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product is an eye irritant. Symptoms
may include stinging and reddening of eyes and watering which may become copious. Other symptoms may also
become evident. If exposure is brief, symptoms should disappear once exposure has ceased. However, lengthy
exposure or delayed treatment may cause permanent damage.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is harmful, but symptoms are not available. This product is unlikely to cause any irritation problems in the short or long
term.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: Thiram is Class 3 - unclassifiable as to carcinogenicity to humans.
See the IARC website for further details. A web address has not been provided as addresses frequently change.
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Thiram 137-26-8 36 1 not set
Thiabendazole 148-79-8 20 not set not set
Other non hazardous ingredients secret <10 not set not set
Water 7732-18-5 to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at
once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if
administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about
unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.
Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5
minutes or until chemical is removed.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is
involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Does not burn.
Upper Flammability Limit: Does not burn.
Lower Flammability Limit: Does not burn.
Autoignition temperature: Not applicable - does not burn.
Flammability Class: Does not burn.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Fairgro Liquid Fungicidal Seed Dressing
Page: 3 of 6
This revision issued: August, 2008
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store packages of this product in a cool place. Protect this product from light. Store in the
closed original container in a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not
come into contact with substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or
separate on standing and may require stirring before use. Check packaging - there may be further storage
instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Thiram 1 not set
The ADI for Thiram is set at 0.004mg/kg/day. The corresponding NOEL is set at 0.4mg/kg/day.
The ADI for Thiabendazole is set at 0.3mg/kg/day. The corresponding NOEL is set at 3mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2004.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: If you believe you may have a sensitisation to this product or any of its declared ingredients, you
should prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that all skin
areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Safety deluge showers should, if practical, be provided near to where this product is being used.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Fairgro Liquid Fungicidal Seed Dressing
Page: 4 of 6
This revision issued: August, 2008
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Opaque green liquid.
Odour: Mild odour.
Boiling Point: Approximately 100掳C at 100kPa.
Freezing/Melting Point: Approximately 0掳C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20掳C (water vapour pressure).
Vapour Density: No data.
Specific Gravity: 1.15-1.16 at 20掳C
Water Solubility: Completely soluble/dispersible in water.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Not applicable - does not burn.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. Protect this product from
light. Store in the closed original container in a dry, cool, well-ventilated area out of direct sunlight.
Incompatibilities: No particular Incompatibilities.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds,
and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur
dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water. Carbon monoxide
poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment,
and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Toxicity: Acute toxicity: Thiram is harmful by ingestion and inhalation and by dermal absorption. Acute exposure
in humans may cause headaches, dizziness, fatigue, nausea, diarrhoea, and other gastrointestinal complaints. In rats
and mice, large doses of Thiram produced muscle incoordination, hyperactivity followed by inactivity, loss of muscular
tone, laboured breathing, and convulsions. Most animals died within 2 to 7 days. Thiram is irritating to the eyes, skin,
and respiratory tract. It is a skin sensitizer. Symptoms of acute inhalation exposure to Thiram include itching, scratchy
throat, hoarseness, sneezing, coughing, inflammation of the nose or throat, bronchitis, dizziness, headache, fatigue,
nausea, diarrhoea, and other gastrointestinal complaints. Persons with chronic respiratory or skin disease are at
increased risk from exposure to Thiram. Ingestion of Thiram and alcohol together may cause stomach pains, nausea,
vomiting, headache, slight fever, and possible dermatitis. Workers exposed to Thiram during application or mixing
operations within 24 hours of moderate alcohol consumption have been hospitalized with symptoms. The 4-hour
inhalation LC50 for Thiram is greater than 500 mg/L in rats. Reported oral LD50 values for Thiram are 620 to over 1900
mg/kg in rats; 1500 to 2000 mg/kg in mice; and 210 mg/kg in rabbits. The dermal LD50 is greater than 1000 mg/kg in
rabbits and in rats.
Chronic toxicity: Symptoms of chronic exposure to Thiram in humans include drowsiness, confusion, loss of sex
drive, incoordination, slurred speech, and weakness, in addition to those due to acute exposure. Repeated or
prolonged exposure to Thiram can also cause allergic reactions such as dermatitis, watery eyes, sensitivity to light,
and conjunctivitis. Except for the occurrence of allergic reactions, harmful chronic effects from Thiram have been
observed in test animals only at very high doses. In one study, a dietary dose of 125 mg/kg/day Thiram was fatal to all
rats within 17 weeks. Oral doses of about 49 mg/kg/day to rats for 2 years produced weakness, muscle
incoordination, and paralysis of the hind legs. Rats fed 52 to 67 mg/kg/day for 80 weeks exhibited hair loss, and
paralysis and atrophy of the hind legs. Symptoms of muscle incoordination and paralysis from Thiram poisoning have
been shown to be associated with degeneration of nerves in the lower lumbar and pelvic regions. Day-old white
leghorn chicks fed 30 and 60 ppm for 6 weeks exhibited bone malformations. At doses of about 10% of the LD50 for
15 days, Thiram reduced blood platelet and white blood cell counts, suppressed blood formation, and slowed blood
coagulation in rabbits.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Fairgro Liquid Fungicidal Seed Dressing
Page: 5 of 6
This revision issued: August, 2008
Reproductive effects: Very high oral doses of approximately 1200 mg/kg/day Thiram to mice on days 6 to 17 of
pregnancy caused resorption of embryos and retarded foetal development. In another study, doses of 132 mg/kg/day
for 13 weeks produced infertility in male mice, while doses of 96 mg/kg/day for 14 days delayed the oestrous cycle in
females. The feeding of 50 mg/kg/day Thiram from day 16 of pregnancy to 21 days after birth caused reduced growth
and survival of the pups. Pups that were transferred to untreated dams at birth remained healthy, while pups
transferred from untreated to treated dams showed toxic effects. These data suggest that reproductive effects occur
at high doses not likely to be experienced by humans.
Teratogenic effects: Cleft palate, wavy ribs, and curved long leg bones were observed in the offspring of mice that
ingested very high Thiram doses of 1200 mg/kg/day on days 6 to 17 of pregnancy. Maternal doses of 125 mg/kg/day
Thiram were teratogenic in hamsters, causing incomplete formation of the skull and spine, fused ribs, abnormalities of
the legs, heart, great vessels, and kidneys. Developmental toxicity was observed in a three-generation study of rats
fed 5.0 mg/kg/day. These data suggest that high doses are required to cause teratatogenic effects.
Mutagenic effects: Thiram has been found to be mutagenic in some test organisms but not in others. Thus, the
evidence is inconclusive.
Carcinogenic effects: When administered to mice at the highest dose possible, Thiram was not carcinogenic.
Dietary levels as high as 125 mg/kg/day for 2 years did not cause tumours in rats. These data indicate that Thiram is
not carcinogenic.
Organ toxicity: Studies have shown evidence of damage to the liver by Thiram in the form of decreased liver enzyme
activity and increased liver weight. Thiram may also cause damage to the nervous system, blood, and kidneys.
Fate in humans and animals: In the body, carbon disulfide is formed from the breakdown of Thiram and does
contribute to the toxicity of Thiram to the liver. Thiram is not a member of the ethylene(bis)dithiocarbamate (EBDC)
chemical family, and thus it should not generate ethylene thiourea (ETU).
Section 12 - Ecological Information
Effects on birds: Thiram is practically nontoxic to birds. The reported dietary LC50 of Thiram in Japanese quail is
greater that 5000 ppm. Reported dietary LC50 values in pheasants and mallard ducks are 2800 ppm and 673 ppm,
respectively. The LD50 for the compound in red-winged blackbirds is greater than 100 mg/kg.
Effects on aquatic organisms: Thiram is highly toxic to fish. The LC50 for the compound is 0.23 mg/L in bluegill
sunfish, 0.13 mg/L in trout, and 4 mg/L in carp. Thiram is not expected to bioconcentrate in aquatic organisms.
Effects on other organisms: Thiram is nontoxic to bees.
Environmental Fate:
Breakdown in soil and groundwater: Thiram is of low to moderate persistence. It is nearly immobile in clay soils or
in soils high in organic matter. Because it is only slightly soluble in water (30 mg/L) and has a strong tendency to
adsorb to soil particles, Thiram is not expected to contaminate groundwater. The soil half-life for Thiram is reported as
15 days. Thiram degrades more rapidly in acidic soils and in soils high in organic matter. In a humus sandy soil, at pH
3.5, Thiram decomposed after 4 to 5 weeks, while at pH 7.0, Thiram decomposed after 14 to 15 weeks. Thiram
persisted for over 2 months in sandy soils, but disappeared within 1 week from a compost soil. The major metabolites
of Thiram in the soil are copper dimethyldithiocarbamate, dithiocarbamate, dimethylamine, and carbon disulfide. In
soil, Thiram will be degraded by microbial action or by hydrolysis under acidic conditions. Thiram will not volatilize
from wet or dry soil surfaces.
Breakdown in water: In water, Thiram is rapidly broken down by hydrolysis and photodegradation, especially under
acidic conditions. Thiram may adsorb to suspended particles or to sediment.
Breakdown in vegetation: No data are currently available.
Section 13 - Disposal Considerations
Disposal: Instructions concerning the disposal of this product and its containers are given on the product label.
These should be carefully followed.
Section 14 - Transport Information
Note: This product range is classed as a MARINE POLLUTANT only and so the Dangerous Goods classification
which follows is for MARINE transport only. Not classed as a Dangerous Good for Storage or Road and Rail
transport.
ADG Code: 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S, contains Thiabendazole and
Thiram.
Hazchem Code: 2X
Special Provisions: SP179, SP274
Dangerous Goods Class: Class 9, Miscellaneous Dangerous Goods.
Packaging Group: III
Packaging Method: 3.8.9
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Fairgro Liquid Fungicidal Seed Dressing
Page: 6 of 6
This revision issued: August, 2008
Class 9 Miscellaneous Dangerous Goods shall not be loaded in the same vehicle or packed in the same freight
container with Classes 1 (Explosives), 5.1 (Oxidising Agents where the Miscellaneous Dangerous Goods are Fire
Risk Substances), 5.2 (Organic Peroxides where the Miscellaneous Dangerous Goods are Fire Risk Substances).
They may however be loaded in the same vehicle or packed in the same freight container with Classes 2.1
(Flammable Gases), 2.2 (Non-Flammable, Non-Toxic Gases), 2.3 (Toxic Gases), 3 (Flammable liquids), 4.1
(Flammable Solids), 4.2 (Spontaneously Combustible Substances), 4.3 (Dangerous When Wet Substances), 5.1
(Oxidising Agents except where the Miscellaneous Dangerous Goods are Fire Risk Substances), 5.2 (Organic
Peroxides except where the Miscellaneous Dangerous Goods are Fire Risk Substances), 6 (Toxic Substances), 7
(Radioactive Substances), 8 (Corrosive Substances), Foodstuffs and foodstuff empties.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
The following ingredients: Thiram, Thiabendazole, are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, August, 2008.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
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