Product Name: Farmoz Clincher Plus Herbicide
Page: 1 of 5
This revision issued: September, 2006
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Metolachlor is a chloroacetanilide derivative.
Farmoz Clincher Plus Herbicide
Trade Name:
Product Use: Agricultural herbicide for use as described on the product label.
Creation Date: September, 2006
Revision Date: September, 2006
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Xi, Irritating. Hazardous according to the criteria of ASCC.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code. However, this is a C1
Combustible Liquid and for storage meets the definition of Dangerous Goods.
Risk Phrases: R36. Irritating to eyes.
Safety Phrases: S2, S13, S25, S26, S28, S46, S61, S20/21, S36/37/39. Keep out of reach of children. Keep away
from food, drink and animal feeding stuffs. Avoid contact with eyes. In case of contact with eyes, rinse immediately
with plenty of water and contact a doctor or Poisons Information Centre. After contact with skin, wash immediately
with plenty of soap and water. If swallowed, contact a doctor or Poisons Information Centre immediately and show
this container or label. Avoid release to the environment. Refer to special instructions/Safety Data Sheets. When
using, do not eat, drink or smoke. Wear suitable protective clothing, gloves and eye/face protection.
SUSDP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Brown liquid.
Odour: Faint odour.
Major Health Hazards: Signs of human intoxication from Metolachlor exposure include abdominal cramps,
anaemia, shortness of breath, dark urine, convulsions, diarrhoea, jaundice, weakness, nausea, sweating, and
dizziness. This product is also an eye irritant.
Potential Health Effects
Inhalation:
Short term exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product is an eye irritant. Symptoms may include stinging and reddening of eyes and
watering which may become copious. Other symptoms may also become evident. If exposure is brief, symptoms
should disappear once exposure has ceased. However, lengthy exposure or delayed treatment may cause permanent
damage.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is an oral
irritant. Symptoms may include burning sensation and reddening of skin in mouth and throat. Other symptoms
(detailed above) may also become evident, but should slowly disappear once exposure has ceased.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Clincher Plus Herbicide
Page: 2 of 5
This revision issued: September, 2006
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
ASCC: No significant ingredient is classified as carcinogenic by ASCC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Metolachlor 51218-45-2 86 not set not set
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The ASCC TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day
for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no
longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures
at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about
30 minutes, seek medical advice.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 5 minutes or until
chemical is removed.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 20 minutes or until
the product is removed, while holding the eyelid(s) open. Take care not to rinse contaminated water into the
unaffected eye or onto the face. Obtain medical attention immediately. Take special care if exposed person is wearing
contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is no risk of an
explosion from this product under normal circumstances if it is involved in a fire. Violent steam generation or eruption
may occur upon application of direct water stream on hot liquids.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: >93掳C
Upper Flammability Limit: No data.
Lower Flammability Limit: No data.
Autoignition temperature: No data.
Flammability Class: C1
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC, Viton. Eye/face protective equipment should comprise as a minimum, protective
goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend
that you use a respirator. It should be fitted with a type G cartridge, suitable for agricultural chemicals. Otherwise, not
normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Clincher Plus Herbicide
Page: 3 of 5
This revision issued: September, 2006
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Note that this product is combustible and therefore, for Storage, meets the definition of Dangerous Goods
in some states. If you store large quantities (tonnes) of such products, we suggest that you consult your state's
Dangerous Goods authority in order to clarify your obligations regarding their storage.
Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct
sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in
Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check
packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
ASCC Exposure limits
Exposure limits have not been established by ASCC for any of the significant ingredients in this product.
The ADI for Metolachlor is set at 0.08mg/kg/day. The corresponding NOEL is set at 7.5mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2005.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Protective glasses or goggles should be worn when this product is being used. Failure to protect
your eyes may cause them harm. Emergency eye wash facilities are also recommended in an area close to where
this product is being used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC, Viton.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Eyebaths or eyewash stations and safety deluge showers should be provided near to where this product is being
used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Brown liquid.
Odour: Faint odour.
Boiling Point: Not available.
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No data.
Vapour Pressure: 3.7mpa at 25掳C
Vapour Density: No data.
Specific Gravity: 1.11-1.13 at 20掳C
Water Solubility: 480ppm at 20掳C
pH: 5-9
Volatility: No data.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Clincher Plus Herbicide
Page: 4 of 5
This revision issued: September, 2006
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-
ventilated area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas in reducing
atmospheres. Hydrogen chloride gas, other compounds of chlorine. Water. Carbon monoxide poisoning produces
headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and
unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Toxicity: An information profile for Metolachlor is available at http://extoxnet.orst.edu/pips/ghindex.html
Acute toxicity: Metolachlor is harmful by ingestion. The reported oral LD50 in rats for technical grade Metolachlor is
from 1200mg/kg to 2780mg/kg. It is practically nontoxic by skin exposure, with a reported dermal LD50 of greater than
2000mg/kg. Technical Metolachlor is a skin sensitizer in guinea pigs, and causes slight irritation and mild eye irritation
in rabbits. The 4-hour rat inhalation LC50 of greater than 4.3mg/L indicates slight toxicity via this route. Human
exposure most commonly occurs through skin or eye contact. Signs of human intoxication from Metolachlor exposure
include abdominal cramps, anaemia, shortness of breath, dark urine, convulsions, diarrhoea, jaundice, weakness,
nausea, sweating, and dizziness.
Chronic toxicity: While Metolachlor is not readily absorbed by the skin, repeated dermal exposures may create skin
sensitization, especially among those who work with Metolachlor. In rats fed Metolachlor for 90 days, no effects were
noted at about 90mg/kg/day. In a 2-year study of mice, a similar no-effect level was found, but doses of about
300mg/kg/day caused decreased body weight gain.
Reproductive effects: In two long-term rat reproduction studies, mating, gestation, lactation, and fertility were not
affected at doses of 50mg/kg/day. However, pup weights and parental food consumption decreased at this low dose.
The evidence suggests that Metolachlor is not likely to have an effect on reproduction in humans under normal
circumstances.
Teratogenic effects: Metolachlor caused no birth defects in rats at maternal doses of 300mg/kg/day administered
during critical periods of gestation (organogenesis), although some delayed or abnormal development in offspring was
seen at this dose. These data indicate that teratogenic and developmental effects in humans are unlikely at expected
levels of exposure.
Mutagenic effects: Metolachlor tested negative in two bacterial assays. Also, no mutagenicity effects were noted in a
standard mouse test. From this evidence it is unlikely that the compound is mutagenic.
Carcinogenic effects: Male and female mice exposed to doses up to 100mg/kg/day for 18 to 20 months did not
develop cancer, nor did male rats at doses of up to 150mg/kg/day over a 2-year period. From these data, it seems
unlikely that Metolachlor is carcinogenic in humans.
Organ toxicity: Exposure to Metolachlor can damage the liver and cause irritation of the skin, eyes, and mucous
membranes. It has also caused skin sensitization in guinea pigs.
Fate in humans and animals: Studies show that orally administered Metolachlor is quickly broken down into
metabolites and is almost totally eliminated in the urine and faeces of goats, rats, and poultry. Metolachlor itself was
not detected in the urine, faeces, or body tissues.
Section 12 - Ecological Information
This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
Breakdown in soil and groundwater: Metolachlor is moderately persistent in the soil environment. Half-lives of 15 to
70 days in different soils have been observed. Soils with significant soil water content may show more rapid
breakdown.
Breakdown in water: Metolachlor is highly persistent in water over a wide range of water acidity. Its half-life at 20 C
is more than 200 days in highly acid waters, and is 97 days in highly basic waters. Metolachlor is also relatively stable
in water under natural sunlight.
Breakdown in vegetation: Metolachlor, applied before plants emerge, is absorbed through shoots just above the
seed, and may be absorbed from the soil into and through the roots. This chemical acts by inhibiting the production of
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Clincher Plus Herbicide
Page: 5 of 5
This revision issued: September, 2006
essential plant components like chlorophylls, enzymes, and other proteins. Metolachlor is a growth inhibitor affecting
root and shoot growth after seeds have germinated.
Section 13 - Disposal Considerations
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. Special
help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding
disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural
chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty
drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredient: Metolachlor, is mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
ASCC Office of the Australian Safety and Compensation Council
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the ASCC document 鈥淣ational Code of Practice for the Preparation
of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, September, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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