Product Name: Farmoz Escalate Ultra Cotton Defoliant
Page: 1 of 5
This revision issued: June, 2005
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Both active ingredients are urea derivatives.
Farmoz Escalate Ultra Cotton Defoliant
Trade Name:
Product Use: For the defoliation of Cotton prior to harvest.
Creation Date: June, 2005
Revision Date: June, 2005
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R40, R48/22, R50/53. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage
to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long term adverse effects
in the aquatic environment.
Safety Phrases: S13, S20, S23, S37, S46, S60, S61. Keep away from food, drink and animal feeding stuffs. When
using, do not eat or drink. Do not breathe spray mist. Wear suitable gloves. If swallowed, contact a doctor or Poisons
Information Centre immediately and show this container or label. This material and its container must be disposed of
as hazardous waste. Avoid release to the environment. Refer to special instructions/Safety Data Sheets.
SUSDP Classification: None allocated.
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Pale grey to brown suspension.
Odour: Unpleasant odour.
Major Health Hazards: may cause serious damage to health by prolonged exposure, may cause irreversible
effects, harmful if swallowed.
Potential Health Effects
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data indicates that this
product is not harmful. In addition product is unlikely to cause any discomfort or irritation.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product is believed to be mildly irritating, but is unlikely to cause anything more than mild
transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product is believed to be mildly
irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is harmful, but symptoms are not available. This product is unlikely to cause any irritation problems in the short or long
term.
Long Term exposure: No data for health effects associated with long term ingestion.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Escalate Ultra Cotton Defoliant
Page: 2 of 5
This revision issued: June, 2005
Carcinogen Status:
NOHSC: Diuron is classified by NOHSC as a Class 3 Carcinogen, possibly carcinogenic to humans.
See the NOHSC website for further details. A web address has not been provided as addresses frequently change.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: Diuron is Class 3 - unclassifiable as to carcinogenicity to humans.
See the IARC website for further details. A web address has not been provided as addresses frequently change.
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Thidiazuron 51707-55-2 12 not set not set
Diuron 330-54-1 6 10 not set
Other non hazardous ingredients secret to 100 not set not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
Skin Contact: Wash gently and thoroughly with water (use non-abrasive soap if necessary) for 10 minutes or until
chemical is removed. If irritation persists, repeat flushing and obtain medical advice.
Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until
the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as a C2 combustible product. There is no risk of an
explosion from this product under normal circumstances if it is involved in a fire.
This product is likely to decompose only after heating to dryness, followed by further strong heating.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Will not burn until water component is driven off.
Upper Flammability Limit: No data
Lower Flammability Limit: No data
Autoignition temperature: No data
Flammability Class: C2
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Escalate Ultra Cotton Defoliant
Page: 3 of 5
This revision issued: June, 2005
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Note that this product is combustible and therefore, for Storage, meets the definition of Dangerous Goods
in some states. If you store large quantities (tonnes) of such products, we suggest that you consult your state's
Dangerous Goods authority in order to clarify your obligations regarding their storage.
Store packages of this product in a cool place. Protect this product from light. Store in the closed original container in
a dry, cool, well-ventilated area out of direct sunlight. Make sure that the product does not come into contact with
substances listed under "Incompatibilities" in Section 10. Some liquid preparations settle or separate on standing and
may require stirring before use. Check packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Diuron 10 not set
The ADI for Thidiazuron is set at 0.02mg/kg/day. The corresponding NOEL is set at 2.5mg/kg/day.
The ADI for Diuron is set at 0.006mg/kg/day. The corresponding NOEL is set at 0.625mg/kg/day. ADI means
Acceptable Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec
2004.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that
the work environment remains clean and that vapours and mists are minimised.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: rubber,
PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Pale grey to brown suspension.
Odour: Unpleasant odour.
Boiling Point: Approximately 100掳C at 100kPa.
Freezing/Melting Point: Approximately 0掳C.
Volatiles: Water component.
Vapour Pressure: 2.37 kPa at 20掳C (water vapour pressure).
Vapour Density: No data.
Specific Gravity: Approx 1.0 at 20掳C
Water Solubility: Forms a suspension in water.
pH: No data.
Volatility: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: No data
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Escalate Ultra Cotton Defoliant
Page: 4 of 5
This revision issued: June, 2005
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: This product should be kept in a cool place, preferably below 30掳C. DO NOT store the
product at low temperatures (less than 5掳C). Protect this product from light.
Incompatibilities: strong oxidising agents.
Fire Decomposition: This product is likely to decompose only after heating to dryness, followed by further strong
heating. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and its compounds,
and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Oxides of sulfur (sulfur
dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Hydrogen chloride gas, other
compounds of chlorine. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness,
confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Chronic toxicity: Male rats given extremely high doses of Diuron over a 2-week period showed changes in their
spleen and bone marrow. Other chronic effects attributed to moderate to high doses of the pesticide over time
included changes in blood chemistry, increased mortality, growth retardation, abnormal blood pigment, and anaemia.
When fed small amounts of Diuron in food for 2 years, animal species showed no adverse effects.
Reproductive effects: Daily low doses of Diuron fed to female rats through three successive generations caused
significantly decreased body weight of offspring in the second and third litters. The fertility rate remained unaffected. It
is unlikely that Diuron will cause reproductive effects in humans at expected levels of exposure.
Teratogenic effects: Diuron is teratogenic at high doses. Administered to pregnant rats on days 6 through 15 of
gestation, it produced no birth defects in the offspring at doses of up to 125 mg/kg/day. However, doses of 250
mg/kg/day caused wavy ribs, extra ribs, and delayed bone formation. There were also weight decreases in offspring
at 500 mg/kg/day. There was no increase in the severity of the rib deformation at this higher dose. Pregnant mice
given very high doses of Diuron (nearly 2000 mg/kg/day) exhibited reproductive and embryotoxic effects.
Developmental effects were found in their offspring.
Mutagenic effects: Diuron does not appear to be mutagenic. The majority of tests have shown that Diuron does not
produce mutations in animal cells or in bacterial cells.
Carcinogenic effects: Limited evidence indicates that low level exposures to Diuron does not cause cancer.
Organ toxicity: Low doses of Diuron over extended periods of time can cause enlargement to the liver and the
spleen.
Fate in humans and animals: Diuron is excreted in the faeces and urine of test animals. Breakdown of the
compound is similar in animals, plants, and soil. Cows fed very low doses of Diuron in their diets had small amounts
of residues in whole milk. Cattle fed small amounts accumulated low levels of Diuron in fat and muscle, liver, and
kidney.
Classification of Hazardous Ingredients
Ingredient Risk Phrases
Diuron >=1%Conc<10%: Xn; R40 (Hazardous Substances Information System)
Section 12 - Ecological Information
Effects on birds: Diuron is slightly toxic to birds. In bobwhite quail, the dietary LC50 is 1730 ppm. In Japanese quail
and ring-necked pheasant, it is greater than 5000 ppm. The LC50 is approximately 5000 ppm in mallard ducks.
Effects on aquatic organisms: The LC50 (48 hour) values for Diuron range from 4.3 mg/L to 42 mg/L in fish, and
range from 1 mg/L to 2.5 mg/L for aquatic invertebrates. The LC50 (96-hour) is 3.5 mg/L for rainbow trout. Thus,
Diuron is moderately toxic to fish and highly toxic to aquatic invertebrates.
Effects on other organisms: Diuron is non-toxic to bees.
Environmental Fate:
Breakdown in soil and groundwater: Diuron is moderately to highly persistent in soils. Residue half -lives are from
1 month to 1 year. Some pineapple fields contained residues 3 years after the last application. Mobility in the soil is
related to organic matter and to the type of the residue. The metabolites are less mobile than the parent compound. In
California, Diuron has been found in groundwater in the 2 to 3 ppb range. It has also been found in Ontario
groundwater where it has been linked with land applications.
Breakdown in water: Diuron is relatively stable in neutral water. Microbes are the primary agents in the degradation
of Diuron in aquatic environments.
Breakdown in vegetation: Diuron is readily absorbed through the root system of plants and less readily through the
leaves and stems.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz Escalate Ultra Cotton Defoliant
Page: 5 of 5
This revision issued: June, 2005
Section 13 - Disposal Considerations
Disposal: Instructions concerning the disposal of this product and its containers are given on the product label.
These should be carefully followed.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are to be found in the public AICS Database.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, June, 2005.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
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