Product Name: Farmoz 2,4-D LV Ester 600
Page: 1 of 5
This revision issued: September, 2005
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: 2,4-D is an aryloxyalkanoic acid derivative. It is present as the Iso-octyl ester.
Farmoz 2,4-D LV Ester 600
Trade Name:
Product Use: Agricultural herbicide for use as described on the product label.
Creation Date: September, 2005
Revision Date: September, 2005
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
This product does not meet the criteria of the Australian Dangerous Goods (ADG) Code. However, this is a C1
Combustible Liquid and for storage meets the definition of Dangerous Goods. Note too that this product is a marine
pollutant, so for marine transport, is UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
Risk Phrases: R20/21/22, R52/53. Harmful by inhalation, in contact with skin, and if swallowed. Harmful to aquatic
organisms, may cause long-term adverse effects to the aquatic environment.
Safety Phrases: S2, S13, S20, S23, S24, S38, S45, S24/25, S36/39. Keep out of reach of children. Keep away
from food, drink and animal feeding stuffs. When using, do not eat or drink. Do not breathe vapours or mists. Avoid
contact with skin. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you
feel unwell, contact a doctor or Poisons Information Centre immediately (show the label where possible). Avoid
contact with skin and eyes. Wear suitable protective clothing and eye/face protection.
SUSDP Classification: S5
ADG Classification: None allocated. Not a Dangerous Good under the ADG Code.
UN Number: None allocated
Emergency Overview
Physical Description & colour: Clear brown liquid.
Odour: Characteristic solvent odour.
Major Health Hazards: harmful by inhalation, in contact with skin, and if swallowed.
The oral LD50 of 2,4-D ranges from 375 to 666 mg/kg in the rat, 370 mg/kg in mice, and from less than 320 to 1000
mg/kg in guinea pigs. The dermal LD50 values are 1500 mg/kg in rats and 1400 mg/kg in rabbits, respectively. In
humans, prolonged breathing of 2,4-D causes coughing, burning, dizziness, and temporary loss of muscle
coordination. Other symptoms of poisoning can be fatigue and weakness with possible nausea. On rare occasions
following high levels of exposure, there can be inflammation of the nerve endings with muscular effects.
Potential Health Effects
See section 11 for Chronic exposure studies.
Inhalation
Short term exposure: Significant inhalation exposure is considered to be unlikely. Available data shows that this
product is harmful, but symptoms are not available.
Skin Contact:
Short term exposure: Available data shows that this product is harmful, but symptoms are not available. In
addition product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Eye Contact:
Short term exposure: Exposure via eyes is considered to be unlikely. This product may be irritating to eyes, but is
unlikely to cause anything more than mild transient discomfort.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Available data shows that this product
is harmful, but symptoms are not available. This product is unlikely to cause any irritation problems in the short or long
term.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz 2,4-D LV Ester 600
Page: 2 of 5
This revision issued: September, 2005
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by IARC.
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
2,4-D, present as the isooctyl ester 25168-26-7 600g/L * not set not set
Calcium dodecylbenzene sulphonate 26264-06-2 100g/L not set not set
Hydrocarbon solvent 64792-94-5 80g/L not set not set
Other non hazardous ingredients secret to 100% not set not set
* Note that this is the 2,4-D equivalent - the ester is present at a somewhat higher concentration.
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should
not be repeated for more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is
used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: If symptoms of poisoning become evident, contact a Poisons Information Centre, or call a doctor at
once. Remove source of contamination or move victim to fresh air. If breathing is difficult, oxygen may be beneficial if
administered by trained personnel, preferably on a doctor's advice. DO NOT allow victim to move about
unnecessarily. Symptoms of pulmonary oedema can be delayed up to 48 hours after exposure.
Skin Contact: Wash gently and thoroughly with warm water (use non-abrasive soap if necessary) for 10-20 minutes
or until product is removed. Under running water, remove contaminated clothing, shoes and leather goods (e.g.
watchbands and belts) and completely decontaminate them before reuse or discard.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing
water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more
than a few minutes.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as a C1 combustible product. There is a slight risk of an
explosion from this product if commercial quantities are involved in a fire. Violent steam generation or eruption may
occur upon application of direct water stream on hot liquids. Vapours from this product are heavier than air and may
accumulate in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash
back considerable distances.
Fire decomposition products from this product may be toxic if inhaled. Take appropriate protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: >75掳C
Upper Flammability Limit: 6%
Lower Flammability Limit: 1%
Autoignition temperature: Approx 500掳C
Flammability Class: C1
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Wear full
protective clothing including eye/face protection. All skin areas should be covered. See below under Personal
Protection regarding Australian Standards relating to personal protective equipment. Suitable materials for protective
clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective goggles. If
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz 2,4-D LV Ester 600
Page: 3 of 5
This revision issued: September, 2005
there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you
use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned below (section 8).
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage,
and dispose of promptly. Recycle containers wherever possible after careful cleaning. Refer to product label for
specific instructions. After spills, wash area preventing runoff from entering drains. If a significant quantity of material
enters drains, advise emergency services. Full details regarding disposal of used containers, spillage and unused
material may be found on the label. If there is any conflict between this MSDS and the label, instructions on the label
prevail. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing
before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: Note that this product is combustible and therefore, for Storage, meets the definition of Dangerous Goods
in some states. If you store large quantities (tonnes) of such products, we suggest that you consult your state's
Dangerous Goods authority in order to clarify your obligations regarding their storage.
Protect this product from light. Store in the closed original container in a dry, cool, well-ventilated area out of direct
sunlight. Make sure that the product does not come into contact with substances listed under "Incompatibilities" in
Section 10. Some liquid preparations settle or separate on standing and may require stirring before use. Check
packaging - there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
The ADI for 2,4-D is set at 0.01mg/kg/day. The corresponding NOEL is set at 1mg/kg/day. ADI means Acceptable
Daily Intake and NOEL means No-observable-effect-level. Values taken from Australian ADI List, Dec 2004.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used in a well ventilated area. If natural ventilation is inadequate, use of a
fan is suggested.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when product is being used.
Skin Protection: Prevent skin contact by wearing impervious gloves, clothes and, preferably, apron. Make sure that
all skin areas are covered. See below for suitable material types.
Protective Material Types: We suggest that protective clothing be made from the following: rubber, PVC.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above.
Safety deluge showers should, if practical, be provided near to where this product is being used.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Clear brown liquid.
Odour: Characteristic solvent odour.
Boiling Point: Solvent boils in the range 190-350掳C
Freezing/Melting Point: Approx -5掳C
Volatiles: No specific data. Expected to be low at 100掳C.
Vapour Pressure: 0.198 kPa at 25掳C (solvent)
Vapour Density: Approx 5
Specific Gravity: 1.11
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz 2,4-D LV Ester 600
Page: 4 of 5
This revision issued: September, 2005
Odour Threshold: No data.
Evaporation Rate: No data.
Coeff Oil/water distribution: No data
Autoignition temp: Approx 500掳C
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Protect this product from light. Store in the closed original container in a dry, cool, well-
ventilated area out of direct sunlight.
Incompatibilities: strong acids, strong bases, strong oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Oxides of
sulfur (sulfur dioxide is a respiratory hazard) and other sulfur compounds. Most will have a foul odour. Water, calcium
compounds. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of
vision, disturbance of judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Chronic toxicity: Rats given high amounts, 50 mg/kg/day, of 2,4-D in the diet for 2 years showed no adverse effects.
Dogs fed lower amounts in their food for 2 years died, probably because dogs do not excrete organic acids efficiently.
A human given a total of 16.3 g in 32 days therapeutically, lapsed into a stupor and showed signs of incoordination,
weak reflexes, and loss of bladder control.
Reproductive effects: High levels of 2,4-D (about 50 mg/kg/day) administered orally to pregnant rats did not cause
any adverse effects on birth weights or litter size. The evidence suggests that if 2,4-D causes reproductive effects in
animals, this only occurs at very high doses. Thus reproductive problems associated with 2,4-D are unlikely in
humans under normal circumstances.
Teratogenic effects: 2,4-D may cause birth defects at high doses. Rats fed 150 mg/kg/day on days 6 to 15 of
pregnancy had offspring with increased skeletal abnormalities, such as delayed bone development and wavy ribs.
This suggests that 2,4-D exposure is unlikely to be teratogenic in humans at expected exposure levels.
Mutagenic effects: 2,4-D has been very extensively tested and was found to be nonmutagenic in most systems. 2,4-
D did not damage DNA in human lung cells. However, in one study, significant effects occurred in chromosomes in
cultured human cells at low exposure levels. The data suggest that 2,4-D is not mutagenic or has low mutagenic
potential.
Carcinogenic effects: 2,4-D fed to rats for 2 years caused an increase in malignant tumours. Female mice given a
single injection of 2,4-D developed cancer (reticulum-cell sarcomas). Another study in rodents shows a low incidence
of brain tumours at moderate exposure levels (45 mg/kg/day) over a lifetime. However, a number of questions have
been raised about the validity of this evidence and thus about the carcinogenic potential of 2,4-D. In humans, a variety
of studies give conflicting results. Several studies suggest an association of 2,4-D exposure with cancer. An increased
occurrence of non-Hodgkin's lymphoma was found among a Kansas and Nebraska farm population associated with
the spraying of 2,4-D. Other studies done in New Zealand, Washington, New York, Australia, and on Vietnam
veterans from the U.S. were all negative. There remains considerable controversy about the methods used in the
various studies and their results. Thus, the carcinogenic status of 2,4-D is not clear.
Organ toxicity: Most symptoms of 2,4-D exposure disappear within a few days, but there is a report of liver
dysfunction from long-term exposure.
Fate in humans and animals: The absorption of 2,4-D is almost complete in mammals after ingestion and nearly all
of the dose is excreted in the urine. The compound is readily absorbed through the skin and lungs. Men given 5
mg/kg excreted about 82% of the dose as unchanged 2,4-D. The half-life is between 10 and 20 hours in living
organisms. There is no evidence that 2,4-D accumulates to significant level in mammals or in other organisms.
Between 6 and 8 hours after doses of 1 mg/kg, peak concentrations of 2,4-D were found in the blood, liver, kidney,
lungs, and spleen of rats. There were lower levels in muscle and brain. After 24 hours, there were no detectable
tissue residues. Only traces of the compound have been found in the milk of lactating animals for 6 days following
exposure.
Section 12 - Ecological Information
Harmful to aquatic organisms, may cause long-term adverse effects to the aquatic environment. Insufficient data to be
sure of status.
Effects on birds: 2,4-D is harmful to wildfowl and slightly to moderately toxic to birds. The LD50 is 1000 mg/kg in
mallards, 272 mg/kg in pheasants, and 668 mg/kg in quail and pigeons.
Effects on aquatic organisms: Some formulations of 2,4-D are highly toxic to fish while others are less so. Limited
studies indicate a half-life of less than 2 days in fish and oysters. Concentrations of 10 mg/L for 85 days did not
adversely affect the survival of adult dungeness crabs. For immature crabs, the 96-hour LC50 is greater than 10 mg/L,
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Product Name: Farmoz 2,4-D LV Ester 600
Page: 5 of 5
This revision issued: September, 2005
indicating that 2,4-D is only slightly toxic. Brown shrimp showed a small increase in mortality at exposures of 2 mg/L
for 48 hours.
Effects on other organisms: Moderate doses of 2,4-D severely impaired honeybees brood production. At lower
levels of exposure, exposed bees lived significantly longer than the controls. The honeybee LD50 is 0.0115 mg/bee.
Breakdown in soil and groundwater: 2,4-D has low soil persistence. The half-life in soil is less than 7 days. Soil
microbes are primarily responsible for its disappearance.
Breakdown in water: In aquatic environments, microorganisms readily degrade 2,4-D. Rates of breakdown increase
with increased nutrients, sediment load, and dissolved organic carbon. Under oxygenated conditions the half-life is 1
week to several weeks.
Breakdown in vegetation: 2,4-D interferes with normal plant growth processes. Uptake of the compound is through
leaves, stems, and roots. Breakdown in plants is by a variety of biological and chemical pathways. 2,4-D is toxic to
most broad leaf crops, especially cotton, tomatoes, beets, and fruit trees.
Section 13 - Disposal Considerations
Disposal: Instructions concerning the disposal of this product and its containers are given on the product label.
These should be carefully followed.
Section 14 - Transport Information
ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary
unless required by other regulations.
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: 2,4-D, Hydrocarbon solvent, are mentioned in the SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, September, 2005.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
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