Product Name: Farmoz Judgement Herbicide
Page: 1 of 5
This revision issued: March, 2006
Section 1 - Identification of Chemical Product and Company
Farmoz Pty Ltd, Suite 1, Level 4, Building B Telephone (02)9431 7800 (24 hours)
207 Pacific Highway St Leonards, NSW 2068 Fax (02)9431 7700
ACN 050 328 973
Substance: Flamprop-M-Methyl is an arylaniline derivative.
Farmoz Judgement Herbicide
Trade Name:
Product Use: Agricultural herbicide for use as described on the product label.
Creation Date: March, 2006
Revision Date: March, 2006
Section 2 - Hazards Identification
Statement of Hazardous Nature
This product is classified as: Hazardous according to the criteria of NOHSC Australia.
Dangerous according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: R10, R22, R65. Flammable. Harmful if swallowed. Harmful: May cause lung damage if swallowed.
Safety Phrases: S16, S20, S23, S46, S24/25. Keep away from sources of ignition - No smoking. When using, do
not eat or drink. Do not breathe vapours or spray mist. If swallowed, contact a doctor or Poisons Information Centre
immediately and show this container or label. Avoid contact with skin and eyes.
SUSDP Classification: S5
ADG Classification: Class 3 (FLAMMABLE LIQUID, N.O.S.)
UN Number: 1993
Emergency Overview
Physical Description & colour: Clear yellow liquid.
Odour: Characteristic odour.
Major Health Hazards: harmful if swallowed, if aspirated, may cause lung damage.
Potential Health Effects
Inhalation
Short term exposure: Available data indicates that this product is not harmful. However product may be mildly
irritating, although unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term inhalation.
Skin Contact:
Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in
normal use. However product may be irritating, but is unlikely to cause anything more than mild transient discomfort.
Long Term exposure: No data for health effects associated with long term skin exposure.
Eye Contact:
Short term exposure: This product may be irritating to eyes, but is unlikely to cause anything more than mild
transient discomfort.
Long Term exposure: No data for health effects associated with long term eye exposure.
Ingestion:
Short term exposure: Significant oral exposure is considered to be unlikely. Because of the low viscosity of this
product, it may directly enter the lungs if swallowed, or if subsequently vomited. Once in the lungs, it is very difficult to
remove and can cause severe injury or death. However, this product may be irritating to mucous membranes but is
unlikely to cause anything more than transient discomfort.
Long Term exposure: No data for health effects associated with long term ingestion.
Carcinogen Status:
NOHSC: No significant ingredient is classified as carcinogenic by NOHSC.
NTP: No significant ingredient is classified as carcinogenic by NTP.
IARC: No significant ingredient is classified as carcinogenic by NOHSC.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Judgement Herbicide
Page: 2 of 5
This revision issued: March, 2006
Section 3 - Composition/Information on Ingredients
TWA (mg/m3) STEL (mg/m3)
Ingredients CAS No Conc,%
Flamprop-M-Methyl 90134-59-1 7.5 not set not set
Aromatic hydrocarbons 64742-94-5 30-60 not set not set
Other non hazardous ingredients secret to 100 not set not set
Cyclohexanone 108-94-1 20 100 not set
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non
hazardous ingredients are also possible.
The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5
day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer
than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the
STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
Section 4 - First Aid Measures
General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by
this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all
times. Have this MSDS with you when you call.
Inhalation: No first aid measures normally required. However, if inhalation has occurred, and irritation has
developed, remove to fresh air and observe until recovered. If irritation becomes painful or persists more than about
30 minutes, seek medical advice.
Skin Contact: Gently blot away excess liquid. Wash gently and thoroughly with water (use non-abrasive soap if
necessary) for 5 minutes or until chemical is removed.
Eye Contact: No effects expected. If irritation does occur, flush contaminated eye(s) with lukewarm, gently flowing
water for 5 minutes or until the product is removed. Obtain medical advice if irritation becomes painful or lasts more
than a few minutes. Take special care if exposed person is wearing contact lenses.
Ingestion: If swallowed, do NOT induce vomiting. Wash mouth with water and contact a Poisons Information
Centre, or call a doctor.
Section 5 - Fire Fighting Measures
Fire and Explosion Hazards: This product is classified as flammable. There is a moderate risk of an explosion
from this product if commercial quantities are involved in a fire. Firefighters should take care and appropriate
precautions. Any explosion will likely spread the fire to surrounding materials. Water spray may be used to cool drums
involved in a fire, reducing the chances of an explosion. Violent steam generation or eruption may occur upon
application of direct water stream on hot liquids. Vapours from this product are heavier than air and may accumulate
in sumps, pits and other low-lying spaces, forming potentially explosive mixtures. They may also flash back
considerable distances.
Fire decomposition products from this product are likely to be toxic and corrosive if inhaled. Take appropriate
protective measures.
Extinguishing Media: Preferred extinguishing media are carbon dioxide, dry chemical, foam, water fog. Foam is
the preferred medium for large fires. Ensure that no spillage enters drains or water courses.
Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade.
Flash point: Approx 44掳C (cyclohexanone)
Upper Flammability Limit: 9.4%
Lower Flammability Limit: 1.1% (cyclohexanone)
Autoignition temperature: No data.
Flammability Class: Flammable
Section 6 - Accidental Release Measures
Accidental release: In the event of a major spill, prevent spillage from entering drains or water courses. Evacuate
the spill area and deny entry to unnecessary and unprotected personnel. Immediately call the Fire Brigade. As a
minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include Viton, Nitrile. Eye/face
protective equipment should comprise as a minimum, protective goggles. If there is a significant chance that vapours
or mists are likely to build up in the cleanup area, we recommend that you use a respirator. It should be fitted with a
type G cartridge, suitable for agricultural chemicals. Otherwise, not normally necessary.
Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill
is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Judgement Herbicide
Page: 3 of 5
This revision issued: March, 2006
or waterways. Avoid using sawdust or other combustible material. Any electrical equipment should be non-sparking.
Any equipment capable of building an electrostatic charge should be electrically grounded. Sweep up and shovel or
collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle
containers wherever possible after careful cleaning. Refer to product label for specific instructions. After spills, wash
area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency
services. Full details regarding disposal of used containers, spillage and unused material may be found on the label. If
there is any conflict between this MSDS and the label, instructions on the label prevail. Ensure legality of disposal by
consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise
laundry of nature of contamination when sending contaminated clothing to laundry.
Section 7 - Handling and Storage
Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check
Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed.
The measures detailed below under "Storage" should be followed during handling in order to minimise risks to
persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible
materials listed in Section 10.
Storage: This product is a Scheduled Poison. Observe all relevant regulations regarding sale, transport and storage
of this schedule of poison. Store in a cool, well ventilated area, and make sure that surrounding electrical devices and
switches are suitable. Check containers periodically for leaks. Containers should be kept closed in order to minimise
contamination and possible evaporation. Make sure that the product does not come into contact with substances
listed under "Incompatibilities" in Section 10. If you keep more than 10000kg or L of Dangerous Goods of Packaging
Group III, you may be required to license the premises or notify your Dangerous Goods authority. If you have any
doubts, we suggest you contact your Dangerous Goods authority in order to clarify your obligations. Check packaging
- there may be further storage instructions on the label.
Section 8 - Exposure Controls and Personal Protection
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye
Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210.
TWA (mg/m3) STEL (mg/m3)
Exposure Limits
Cyclohexanone 100 not set
No special equipment is usually needed when occasionally handling small quantities. The following instructions are
for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems.
Ventilation: This product should only be used where there is ventilation that is adequate to keep exposure below
the TWA levels. If necessary, use a fan.
Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being
used.
Skin Protection: You should avoid contact even with mild skin irritants. Therefore you should wear suitable
impervious elbow-length gloves and facial protection when handling this product. See below for suitable material
types.
Protective Material Types: We suggest that protective clothing be made from the following materials: Viton,
nitrile.
Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult
the Australian Standard mentioned above. Otherwise, not normally necessary.
Section 9 - Physical and Chemical Properties:
Physical Description & colour: Clear yellow liquid.
Odour: Characteristic odour.
Boiling Point: Not available. Cyclohexanone boils about 155掳C
Freezing/Melting Point: No specific data. Liquid at normal temperatures.
Volatiles: No specific data. Expected to be low at 100掳C.
Vapour Pressure: No data.
Vapour Density: No data.
Specific Gravity: 0.98 approx
Water Solubility: Emulsifiable.
pH: No data.
Volatility: No data.
Odour Threshold: No data.
Evaporation Rate: No data.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Judgement Herbicide
Page: 4 of 5
This revision issued: March, 2006
Coeff Oil/water distribution: No data
Autoignition temp: No data.
Section 10 - Stability and Reactivity
Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have
any doubts, contact the supplier for advice on shelf life properties.
Conditions to Avoid: Keep away from sources of sparks or ignition. Store in the closed original container in a dry,
cool, well-ventilated area out of direct sunlight.
Incompatibilities: strong acids, strong bases, oxidising agents.
Fire Decomposition: Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Nitrogen and
its compounds, and under some circumstances, oxides of nitrogen. Occasionally hydrogen cyanide gas. Hydrogen
chloride gas, other compounds of chlorine. Hydrogen fluoride gas and other compounds of fluorine. Water. Carbon
monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of
judgment, and unconsciousness followed by coma and death.
Polymerisation: This product will not undergo polymerisation reactions.
Section 11 - Toxicological Information
Local Effects:
Target Organs: none known
Classification of Hazardous Ingredients
Ingredient Risk Phrases
Aromatic Hydrocarbons Conc>=10%: Xn; R65
Section 12 - Ecological Information
This product is biodegradable. It will not accumulate in the soil or water or cause long term problems.
For flamprop-M-methyl
Acute Toxicity - Fish : LC50 (96 hr) for rainbow trout is 4 mg/l
Acute Toxicity - Birds:
Not toxic to birds. LD50 for bobwhite quail, pheasants, mallard ducks, chicken, partridges and pigeons is >1,000 mg/kg
Not toxic to bees.
Section 13 - Disposal Considerations
Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so
each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of
Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails
should disposal be considered. Note that properties of a product may change in use, so that the following suggestions
may not always be appropriate. The following may help you in properly addressing this matter for this product. Special
help is available for the disposal of Agricultural Chemicals. The product label will give general advice regarding
disposal of small quantities, and how to cleanse containers. However, for help with the collection of unwanted rural
chemicals, contact ChemClear 1800 008 182 http://www.chemclear.com.au/ and for help with the disposal of empty
drums, contact DrumMuster http://www.drummuster.com.au/ where you will find contact details for your area.
Section 14 - Transport Information
ADG Code: 1993, FLAMMABLE LIQUID, N.O.S.
Hazchem Code: 3[Y]
Special Provisions: SP109, SP185, SP274
Dangerous Goods Class: Class 3, Flammable liquids.
Packaging Group: III
Packaging Method: 3.8.3, RT1
Class 3 Flammable Liquids shall not be loaded in the same vehicle or packed in the same freight container with
Classes 1 (Explosives), 2.1 (Flammable Gases where flammable liquids and flammable gases are both in bulk), 2.3
(Toxic Gases), 4.2 (Spontaneously Combustible Substances), 5.1 (Oxidising Agents), 5.2 (Organic Peroxides), 6
(Toxic Substances, except Flammable Liquid is nitromethane), and 7 (Radioactive Substances). They may however
be loaded in the same vehicle or packed in the same freight container with Classes 2.1 (Flammable Gases except
where the Flammable Liquids and Flammable Gases are in bulk), 2.2 (Non-Flammable Non-Toxic Gases), 4.1
(Flammable Solids), 4.3 (Dangerous When Wet Substances), 6 (Toxic Substances, except where Flammable Liquid is
nitromethane), 8 (Corrosive Substances), 9 (Miscellaneous Dangerous Goods), Foodstuffs or foodstuff empties.
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Product Name: Farmoz Judgement Herbicide
Page: 5 of 5
This revision issued: March, 2006
Section 15 - Regulatory Information
AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations.
The following ingredients: Flamprop-M-Methyl, Aromatic hydrocarbon, (a liquid hydrocarbon) are mentioned in the
SUSDP.
Section 16 - Other Information
This MSDS contains only safety-related information. For other data see product literature.
Acronyms:
ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail
AICS Australian Inventory of Chemical Substances
CAS number Chemical Abstracts Service Registry Number
Hazchem Code Emergency action code of numbers and letters that provide information to
emergency services especially firefighters
IARC International Agency for Research on Cancer
NOHSC National Occupational Health and Safety Commission
NOS Not otherwise specified
NTP National Toxicology Program (USA)
R-Phrase Risk Phrase
SUSDP Standard for the Uniform Scheduling of Drugs & Poisons
UN Number United Nations Number
Contact Points:
Call Farmoz on (02)9431 7800 and ask for the technical manager. Fax: (02)9431 7700
Police and Fire Brigade: Dial 000
Emergency contact: 1800 024 973 (24 hours)
If ineffective: Dial Poisons Information Centre
(13 1126 from anywhere in Australia)
The information contained in this Material Safety Data Sheet is provided in good faith and is believed to be correct at the date
hereof. However, it is expected that individuals receiving the information will exercise their independent judgement in determining
its appropriateness for a particular purpose. Farmoz Pty Ltd makes no representation as to the accuracy or comprehensiveness of
the information and to the full extent allowed by law excludes all liability whatsoever, whether with respect to negligence or
otherwise, for any loss or damage arising from or connection with the supply or use of the information in this Material Safety Data
Sheet.
Please read all labels carefully before using product.
This MSDS is prepared in accord with the NOHSC document 鈥淣ational Code of Practice for the
Preparation of Material Safety Data Sheets鈥? 2nd Edition [NOHSC:2011(2003)]
Copyright 漏 Kilford & Kilford Pty Ltd, March, 2006.
http://www.kilford.com.au/ Phone (02)9251 4532
MATERIAL SAFETY DATA SHEET
Issued by: Farmoz Pty Ltd Phone: (02)9431 7800
Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
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