**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 100-16-3 |4-Nitrophenylhydrazine | 82-90 | 202-824-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | 10-18 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN F
Risk Phrases: 11 22 36/37/38 5
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful if swallowed. Irritating to eyes,
respiratory system and skin. Heating may cause an explosion.Highly
flammable.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. Ingestion of large amounts may cause
CNS depression.
Inhalation:
Causes respiratory tract irritation. Aspiration may lead to
pulmonary edema. May be harmful if inhaled. Vapors may cause
dizziness or suffocation. May cause burning sensation in the chest.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Exposure to heat may promote violent decomposition.
During a fire, irritating and highly toxic gases may be generated by
thermal decomposition or combustion. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Will be easily ignited by heat, sparks or flame.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Use with adequate ventilation. Wash clothing before
reuse. Do not pressurize, cut, weld, braze, solder, drill, grind, or
expose empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Refrigerator/flammables.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 100-16-3:
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: brown - orange to brown
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 157 deg C (dec)
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 157 deg C
Solubility in water: slightly soluble in cold water
Specific Gravity/Density: Not available.
Molecular Formula: NHNH2C6H4NO2
Molecular Weight: 153.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, dust generation, excess heat, temperatures above
55C.
Incompatibilities with Other Materials:
Strong bases, oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 100-16-3: MV8225000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
Not available.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Oral, Mouse,: LD50 = 250mg/kg.
Carcinogenicity:
4-Nitrophenylhydrazine -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 5 Heating may cause an explosion.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 100-16-3: No information available.
CAS# 7732-18-5: No information available.
Canada
CAS# 100-16-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 100-16-3 is not listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 100-16-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 8/24/1997 Revision #5 Date: 4/19/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dichlorodimethylsilane, 99%
| 75-78-5 |
|
2-Mesitylenesulfonyl Chloride, 99%
| 773-64-8 |
|
5-Norbornen-2-ol (mixture of endo and exo), 99%
| 13080-90-5 |
|
1,3-Dithiane, 97%
| 505-23-7 |
|
Alpha-D-Cellobiose Octaacetate
| 5346-90-7 |
|
4-Bromobiphenyl, 99%
| 92-66-0 |
|
1,2,3-Heptanetriol
| 103404-57-5 |
|
1-Bromononane, 97%
| 693-58-3 |
|
2-Vinylnaphthalene, 98% Stabilized with 0.4% P-Tert.-Butylcatechol
| 827-54-3 |
|
4-Nitrophenylhydrazine, 10-18% water added, 95%
| 100-16-3 |
|
2-Methyl-1-pentene, 99%
| 763-29-1 |
|
2,5-Dimethylanisole, 99%
| 1706-11-2 |
|
1-Decene, 95%
| 872-05-9 |
|
Methyl s-(-)-lactate, 98%
| 27871-49-4 |
|
3,5-Dibromo-O-Phenylenediamine Mono- Hydrochloride, 99%
| 75568-11-5 |
|
2'-Methylacetophenone, 98%
| 577-16-2 |
|
Ethyl 1-piperidineacetate, 98+%
| 23853-10-3 |
|
1,1,4,4-Tetraphenyl-1,3-Butadiene, Scintillation Grade, 99+%
| 1450-63-1 |
|
3-Chloropropanesulfonyl Chloride, 96%
| 1633-82-5 |
|
Nigrosine, water soluble
| 8005-03-6 |
|
Platinum(ii) iodide, 98.5%
| 7790-39-8 |
|
n-Benzyltropinone, 96% (tlc)
| 28957-72-4 |
|
Acetonylacetone, 97%
| 110-13-4 |
|
(1,4'-Bipiperidine)-4'-carboxamide, 99+%
| 39633-82-4 |
|
Tetraethyleneglycol Monomethyl Ether, 98% (GC)
| 23783-42-8 |
|
Metaldehyde
| 108-62-3 |
|
n-Butyl vinyl ether, 98%
| 111-34-2 |
|
Poly(Alpha-Methylstyrene)
| 25014-31-7 |
|
Copper(II) acetylacetonate, 99%
| 13395-16-9 |
|
Perfluoro(methylcyclohexane), 96%
| 355-02-2 |
|
4-Bromo-2-Fluorophenol, 98%
| 2105-94-4 |
|
2,4-Hexadienoic acid
| 110-44-1 |
|
4-Octyloxyaniline, 98% (Titr.)
| 39905-45-8 |
|
D(+)-galacturonic acid monohydrate, 99%
| 685-73-4 |
|
1,3,3-Trimethoxypropene, 96% (GC), Cis/Trans Mixture: 20/80,
| 17576-35-1 |
|
Sodium Omadine , 40% Aqueous Solution
| 3811-73-2 |
|
Dibenzothiophene sulfone, 97%
| 1016-05-3 |
|
Ethyl 3-Pyridylacetate, 99%
| 39931-77-6 |
|
Iodoacetamide, 98%
| 144-48-9 |
|
Sodium nitroferricyanide dihydrate, reagent ACS, crystals
| 13755-38-9 |
|
1,3-Propane sultone, 99% (gc)
| 1120-71-4 |
|
2-Bromo-4'-methoxyacetophenone, 98%
| 2632-13-5 |
|
2-Thiopheneglyoxylic acid, 97%
| 4075-59-6 |
|
2-Chloro-4-Fluorobenzylcyanide, 99+%
| 75279-56-0 |
|
2-Acetylthiazole, 99%
| 24295-03-2 |
|
2-(Trifluoromethyl)-phenothiazine, 97%
| 92-30-8 |
|
m-Anisic acid, 98%
| 586-38-9 |
|
2-(N-Butylperfluorooctanesulfonamido)ethyl acrylate, stabilized, 77%
| 383-07-3 |
|
3,4-Dichlorobenzaldehyde, 98%
| 6287-38-3 |
|
Silver Vanadate, 98% (Titr.)
| 13497-94-4 |
|
|