**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 111-34-2 |n-Butyl vinyl ether | 98 | 203-860-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11 19
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May form explosive peroxides.
Potential Health Effects
Eye:
Causes mild eye irritation.
Skin:
Causes mild skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Extremely flammable
liquid and vapor. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. May form explosive peroxides. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. Will be easily ignited by heat,
sparks or flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. In case of fire, use water, dry chemical,
chemical foam, or alcohol-resistant foam. Use water spray to cool
fire-exposed containers. Water may be ineffective. Use agent most
appropriate to extinguish fire. For large fires, use water spray,
fog or alcohol-resistant foam. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Avoid contact with eyes, skin, and clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Take precautionary measures against static
discharges. Keep away from heat, sparks and flame. Avoid ingestion
and inhalation. Wash clothing before reuse. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Keep refrigerated. (Store below 4C/39F.)
Containers should be dated when opened and tested periodically for
the presence of peroxides. Should crystals form in a peroxidizable
liquid, peroxidation may have occurred and the product should be
considered extremely dangerous. In this instance, the container
should only be opened remotely by professionals. All peroxidizable
substances should be stored away from heat and light and be protected
from ignition sources.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 111-34-2:
Russia: 20 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 42 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 94 deg C @ 760 mm Hg
Freezing/Melting Point: -92 deg C
Autoignition Temperature: 225 deg C ( 437.00 deg F)
Flash Point: -9 deg C ( 15.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in alcohol and ether
Specific Gravity/Density: .7740g/cm3
Molecular Formula: C6H12O
Molecular Weight: 100.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form
and accumulate peroxides which may explode when subjected to heat or
shock. This material is most hazardous when peroxide levels are
concentrated by distillation or evaporation.
Conditions to Avoid:
Ignition sources, exposure to air, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 111-34-2: KN5950000
LD50/LC50:
CAS# 111-34-2: Inhalation, mouse: LC50 = 62 gm/m3/2H; Inhalation,
mouse: LC50 = 62000 mg/m3; Oral, rat: LD50 = 10 gm/kg; Skin, rabbit:
LD50 = 4240 uL/kg.
Carcinogenicity:
n-Butyl vinyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BUTYL VINYL ETHER, INHIBITED
Hazard Class: 3
UN Number: 2352
Packing Group: II
IMO
Shipping Name: BUTYL VINYL ETHER, INHIBITED
Hazard Class: 3.2
UN Number: 2352
Packing Group: II
RID/ADR
Shipping Name: BUTYL VINYL ETHER, INHIBITED
Hazard Class: 3
UN Number: 2352
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
R 19 May form explosive peroxides.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 111-34-2: 1
Canada
CAS# 111-34-2 is listed on Canada's DSL List.
CAS# 111-34-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 111-34-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/14/1998 Revision #3 Date: 7/22/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dichlorodimethylsilane, 99%
| 75-78-5 |
|
2-Mesitylenesulfonyl Chloride, 99%
| 773-64-8 |
|
5-Norbornen-2-ol (mixture of endo and exo), 99%
| 13080-90-5 |
|
1,3-Dithiane, 97%
| 505-23-7 |
|
Alpha-D-Cellobiose Octaacetate
| 5346-90-7 |
|
4-Bromobiphenyl, 99%
| 92-66-0 |
|
1,2,3-Heptanetriol
| 103404-57-5 |
|
1-Bromononane, 97%
| 693-58-3 |
|
2-Vinylnaphthalene, 98% Stabilized with 0.4% P-Tert.-Butylcatechol
| 827-54-3 |
|
4-Nitrophenylhydrazine, 10-18% water added, 95%
| 100-16-3 |
|
2-Methyl-1-pentene, 99%
| 763-29-1 |
|
2,5-Dimethylanisole, 99%
| 1706-11-2 |
|
1-Decene, 95%
| 872-05-9 |
|
Methyl s-(-)-lactate, 98%
| 27871-49-4 |
|
3,5-Dibromo-O-Phenylenediamine Mono- Hydrochloride, 99%
| 75568-11-5 |
|
2'-Methylacetophenone, 98%
| 577-16-2 |
|
Ethyl 1-piperidineacetate, 98+%
| 23853-10-3 |
|
1,1,4,4-Tetraphenyl-1,3-Butadiene, Scintillation Grade, 99+%
| 1450-63-1 |
|
3-Chloropropanesulfonyl Chloride, 96%
| 1633-82-5 |
|
Nigrosine, water soluble
| 8005-03-6 |
|
Platinum(ii) iodide, 98.5%
| 7790-39-8 |
|
n-Benzyltropinone, 96% (tlc)
| 28957-72-4 |
|
Acetonylacetone, 97%
| 110-13-4 |
|
(1,4'-Bipiperidine)-4'-carboxamide, 99+%
| 39633-82-4 |
|
Tetraethyleneglycol Monomethyl Ether, 98% (GC)
| 23783-42-8 |
|
Metaldehyde
| 108-62-3 |
|
n-Butyl vinyl ether, 98%
| 111-34-2 |
|
Poly(Alpha-Methylstyrene)
| 25014-31-7 |
|
Copper(II) acetylacetonate, 99%
| 13395-16-9 |
|
Perfluoro(methylcyclohexane), 96%
| 355-02-2 |
|
4-Bromo-2-Fluorophenol, 98%
| 2105-94-4 |
|
2,4-Hexadienoic acid
| 110-44-1 |
|
4-Octyloxyaniline, 98% (Titr.)
| 39905-45-8 |
|
D(+)-galacturonic acid monohydrate, 99%
| 685-73-4 |
|
1,3,3-Trimethoxypropene, 96% (GC), Cis/Trans Mixture: 20/80,
| 17576-35-1 |
|
Sodium Omadine , 40% Aqueous Solution
| 3811-73-2 |
|
Dibenzothiophene sulfone, 97%
| 1016-05-3 |
|
Ethyl 3-Pyridylacetate, 99%
| 39931-77-6 |
|
Iodoacetamide, 98%
| 144-48-9 |
|
Sodium nitroferricyanide dihydrate, reagent ACS, crystals
| 13755-38-9 |
|
1,3-Propane sultone, 99% (gc)
| 1120-71-4 |
|
2-Bromo-4'-methoxyacetophenone, 98%
| 2632-13-5 |
|
2-Thiopheneglyoxylic acid, 97%
| 4075-59-6 |
|
2-Chloro-4-Fluorobenzylcyanide, 99+%
| 75279-56-0 |
|
2-Acetylthiazole, 99%
| 24295-03-2 |
|
2-(Trifluoromethyl)-phenothiazine, 97%
| 92-30-8 |
|
m-Anisic acid, 98%
| 586-38-9 |
|
2-(N-Butylperfluorooctanesulfonamido)ethyl acrylate, stabilized, 77%
| 383-07-3 |
|
3,4-Dichlorobenzaldehyde, 98%
| 6287-38-3 |
|
Silver Vanadate, 98% (Titr.)
| 13497-94-4 |
|
|