**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 110-13-4 |Acetonylacetone | 97 | 203-738-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Combustible liquid.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system effects.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode if exposed
to fire.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire. Cool containers with flooding quantities of water until well
after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use with adequate
ventilation. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Avoid ingestion and inhalation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Store in a cool, dry place.
Keep container closed when not in use. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 110-13-4:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slight brown
Odor: Not available.
pH: Not available.
Vapor Pressure: 0.57 mbar @ 20
Viscosity: Not available.
Boiling Point: 191 deg C @ 760 mm Hg
Freezing/Melting Point: -6 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 78 deg C ( 172.40 deg F)
Explosion Limits, lower: 1.50 vol %
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: .9730g/cm3
Molecular Formula: C6H10O2
Molecular Weight: 114.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, acids, excess heat.
Incompatibilities with Other Materials:
Strong oxidants.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 110-13-4: MO3150000
LD50/LC50:
CAS# 110-13-4: Dermal, guinea pig: LD50 = 6.6 mL/kg; Draize test,
rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 100 mg/24H
Moderate; Inhalation, rat: LC50 = 2000 ppm/4H; Oral, mouse: LD50 =
2386 mg/kg; Oral, rat: LD50 = 1600 mg/kg.
Carcinogenicity:
Acetonylacetone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 110-13-4: No information available.
Canada
CAS# 110-13-4 is listed on Canada's DSL List.
CAS# 110-13-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 110-13-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/20/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Dichlorodimethylsilane, 99%
| 75-78-5 |
|
2-Mesitylenesulfonyl Chloride, 99%
| 773-64-8 |
|
5-Norbornen-2-ol (mixture of endo and exo), 99%
| 13080-90-5 |
|
1,3-Dithiane, 97%
| 505-23-7 |
|
Alpha-D-Cellobiose Octaacetate
| 5346-90-7 |
|
4-Bromobiphenyl, 99%
| 92-66-0 |
|
1,2,3-Heptanetriol
| 103404-57-5 |
|
1-Bromononane, 97%
| 693-58-3 |
|
2-Vinylnaphthalene, 98% Stabilized with 0.4% P-Tert.-Butylcatechol
| 827-54-3 |
|
4-Nitrophenylhydrazine, 10-18% water added, 95%
| 100-16-3 |
|
2-Methyl-1-pentene, 99%
| 763-29-1 |
|
2,5-Dimethylanisole, 99%
| 1706-11-2 |
|
1-Decene, 95%
| 872-05-9 |
|
Methyl s-(-)-lactate, 98%
| 27871-49-4 |
|
3,5-Dibromo-O-Phenylenediamine Mono- Hydrochloride, 99%
| 75568-11-5 |
|
2'-Methylacetophenone, 98%
| 577-16-2 |
|
Ethyl 1-piperidineacetate, 98+%
| 23853-10-3 |
|
1,1,4,4-Tetraphenyl-1,3-Butadiene, Scintillation Grade, 99+%
| 1450-63-1 |
|
3-Chloropropanesulfonyl Chloride, 96%
| 1633-82-5 |
|
Nigrosine, water soluble
| 8005-03-6 |
|
Platinum(ii) iodide, 98.5%
| 7790-39-8 |
|
n-Benzyltropinone, 96% (tlc)
| 28957-72-4 |
|
Acetonylacetone, 97%
| 110-13-4 |
|
(1,4'-Bipiperidine)-4'-carboxamide, 99+%
| 39633-82-4 |
|
Tetraethyleneglycol Monomethyl Ether, 98% (GC)
| 23783-42-8 |
|
Metaldehyde
| 108-62-3 |
|
n-Butyl vinyl ether, 98%
| 111-34-2 |
|
Poly(Alpha-Methylstyrene)
| 25014-31-7 |
|
Copper(II) acetylacetonate, 99%
| 13395-16-9 |
|
Perfluoro(methylcyclohexane), 96%
| 355-02-2 |
|
4-Bromo-2-Fluorophenol, 98%
| 2105-94-4 |
|
2,4-Hexadienoic acid
| 110-44-1 |
|
4-Octyloxyaniline, 98% (Titr.)
| 39905-45-8 |
|
D(+)-galacturonic acid monohydrate, 99%
| 685-73-4 |
|
1,3,3-Trimethoxypropene, 96% (GC), Cis/Trans Mixture: 20/80,
| 17576-35-1 |
|
Sodium Omadine , 40% Aqueous Solution
| 3811-73-2 |
|
Dibenzothiophene sulfone, 97%
| 1016-05-3 |
|
Ethyl 3-Pyridylacetate, 99%
| 39931-77-6 |
|
Iodoacetamide, 98%
| 144-48-9 |
|
Sodium nitroferricyanide dihydrate, reagent ACS, crystals
| 13755-38-9 |
|
1,3-Propane sultone, 99% (gc)
| 1120-71-4 |
|
2-Bromo-4'-methoxyacetophenone, 98%
| 2632-13-5 |
|
2-Thiopheneglyoxylic acid, 97%
| 4075-59-6 |
|
2-Chloro-4-Fluorobenzylcyanide, 99+%
| 75279-56-0 |
|
2-Acetylthiazole, 99%
| 24295-03-2 |
|
2-(Trifluoromethyl)-phenothiazine, 97%
| 92-30-8 |
|
m-Anisic acid, 98%
| 586-38-9 |
|
2-(N-Butylperfluorooctanesulfonamido)ethyl acrylate, stabilized, 77%
| 383-07-3 |
|
3,4-Dichlorobenzaldehyde, 98%
| 6287-38-3 |
|
Silver Vanadate, 98% (Titr.)
| 13497-94-4 |
|
|