**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1002-28-4 |3-Hexyn-1-ol | 98 | 213-685-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary
edema. Inhalation at high concentrations may cause CNS depression and
asphixiation.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Water may be ineffective.
Material is lighter than water and a fire may be spread by the use of
water. Combustible liquid. Vapors may be heavier than air. They can
spread along the ground and collect in low or confined areas.
Containers may explode when heated.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Sweep up
or absorb material, then place into a suitable clean, dry, closed
container for disposal. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 1002-28-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 63.0 - 64.0 deg C @ 12 mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 63 deg C ( 145.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.8980 g/cm3
Molecular Formula: C6H10O
Molecular Weight: 98.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1002-28-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-Hexyn-1-ol -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 1002-28-4: No information available.
Canada
CAS# 1002-28-4 is listed on Canada's DSL List.
CAS# 1002-28-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1002-28-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Potassium Iodide, 99%, Briquettes
| 7681-11-0 |
|
Potassium Iodide, 99.995%
| 7681-11-0 |
|
Palladium on carbon (10%) (50% wet with water for safety)
| 7440-05-3 |
|
Ruthenium(IV) Oxide, Anhydrous, 99.5+%
| 12036-10-1 |
|
Carbazole, 99% (UV-Vis)
| 86-74-8 |
|
Calcium Carbonate, 98.5%
| 471-34-1 |
|
Calcium Carbonate (Chips), 97% (Titr.)
| 471-34-1 |
|
Ethyl 2-benzylacetoacetate, 97%
| 620-79-1 |
|
2-(4-Nitrophenoxy)tetradecanoyl Chloride, 92% (HPLC)
| 116526-84-2 |
|
Calcium Carbonate, Light Powder
| 471-34-1 |
|
1,5-Difluoro-2,4-dinitrobenzene, 97 %
| 327-92-4 |
|
Calcium Carbonate, Reagent ACS (Powder), 99+% (Titr.)
| 471-34-1 |
|
Calcium Carbonate, P.A. (Precipitated, Heavy)
| 471-34-1 |
|
Calcium Carbonate, Low in Alkalies, Reagent ACS (Powder), 99+%
| 471-34-1 |
|
Calcium Chloride, Anhydrous Powder, 95%, P.A.
| 10043-52-4 |
|
Calcium Chloride Dihydrate 77 - 80% CaCl2 Flakes for Drying Purposes
| 10035-04-8 |
|
Calcium Chloride Dihydrate, P.A.
| 10035-04-8 |
|
Calcium Chloride Dihydrate, Reagent ACS
| 10035-04-8 |
|
Hydrochloric Acid, 0.1 N Solution
| 7647-01-0 |
|
Calcium Fluoride, 99%, Anhydrous
| 7789-75-5 |
|
Benzoyl Chloride, 99%
| 98-88-4 |
|
Deoxycholic acid, sodium salt, 99%
| 302-95-4 |
|
Methyl myristate 99%
| 124-10-7 |
|
Methyltriphenoxyphosphonium iodide
| 17579-99-6 |
|
Copper phthalocyanine-3,4',4",4"'-tetrasul fonic acid,tetrasodium
| 123439-80-5 |
|
Ethylenebis(oxyethylenenitrilo)tetraacetic acid, 97%
| 67-42-5 |
|
Ethylenebis(oxyethylenenitrilo)tetraacetic acid, 99%
| 67-42-5 |
|
Poly(Methyl Methacrylate), Average M.W. 15000(GPC)
| 9011-14-7 |
|
Poly(Methyl Methacrylate), Sec. Stand., M. W. 93300, N.N. 46400, Fine
| 9011-14-7 |
|
Poly(Methyl Methacrylate), Nominal M.W. 38000, Beads
| 9011-14-7 |
|
Poly(Methyl Methacrylate), Average M.W. 500.000
| 9011-14-7 |
|
Heparin Sodium
| 9041-08-1 |
|
Iodine, reagent ACS, 99.8%
| 7553-56-2 |
|
Iodine, resublimed, p.a.
| 7553-56-2 |
|
Iodine, 0.1N Standard Solution
| 7553-56-2 |
|
3,3'-Diethyloxadicarbocyanine Iodide, Laser Grade, 99% (UV-Vis)
| 14806-50-9 |
|
Copper (II) Chloride Dihydrate, Tech., 95%
| 10125-13-0 |
|
Copper (II) Chloride Dihydrate, Reagent (Powder), 99% (Titr.)
| 10125-13-0 |
|
Copper (II) Chloride Dihydrate, P.A.
| 10125-13-0 |
|
Copper (I) Chloride, 95+%
| 7758-89-6 |
|
Copper (I) Chloride, Purified, 99%
| 7758-89-6 |
|
3-Hexyn-1-ol, 98%
| 1002-28-4 |
|
Copper (I) Chloride, 99.99%
| 7758-89-6 |
|
Copper (I) Chloride, P.A.
| 7758-89-6 |
|
Copper (I) Chloride, Reagent ACS (Powder), 90+% (Titr.)
| 7758-89-6 |
|
Cyclohexane, Reagent ACS, Spectro Grade, 99+% (GC)
| 110-82-7 |
|
Cyclohexane, 99+%
| 110-82-7 |
|
Cyclohexane, P.A.
| 110-82-7 |
|
Cyclohexane for HPLC
| 110-82-7 |
|
Ammonium molybdate(VI) tetrahydrate, p.a.
| 12027-67-7 |
|
|