**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7553-56-2 |Iodine | 99.8 | 231-442-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/21 50
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and in contact with skin. Very toxic to
aquatic organisms.Corrosive.
Potential Health Effects
Eye:
Causes severe eye irritation. May cause eye burns. Vapor or mist
may cause irritation and severe burns.
Skin:
Causes skin burns. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. May cause burns to the digestive
tract. May cause thyroid abnormalities.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. May cause epiphoria, which is an excessive flow of
tears.
Chronic:
Chronic exposure can lead to iodism characterized by salivation,
nasal discharge, sneezing, conjunctivitis, fever, laryngitis,
bronchitis, stomatitis, and skin rashes. Chronic exposure can affect
thyroid function. May cause kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Rinse area with large amounts of water
for at least 15 minutes. Remove contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn. During a fire, irritating
and highly toxic gases may be generated by thermal decomposition or
combustion. Use water spray to keep fire-exposed containers cool.
Containers may explode when heated.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Keep container tightly
closed. Avoid contact with clothing and other combustible materials.
Do not get on skin or in eyes. Do not ingest or inhale.
Storage:
Do not store near combustible materials. Keep away from food and
drinking water. Keep away from strong acids. Keep away from metals.
Keep away from reducing agents.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 7553-56-2:
United Kingdom, OES - STEL: 0.1 ppm STEL; 1.1 mg/m3 STEL
United States OSHA: ; 0.1 ppm Ceiling; 1 mg/m3 Ceiling
Belgium - STEL: 0.1 ppm VLE; 1 mg/m3 VLE
France - VLE: 0.1 ppm VLE; 1 mg/m3 VLE
Germany: 0.1 ppm TWA; 1.1 mg/m3 TWA
Germany: Skin absorber
Japan: 0.1 ppm OEL; 1 mg/m3 OEL
Malaysia: 0.1 ppm Ceiling; 1.0 mg/m3 Ceiling
Russia: 1 mg/m3 TWA
Spain: 0.1 ppm VLA-EC; 1 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear impervious gloves.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: black-violet
Odor: iodine-like
pH: 5.4 (sat soln)
Vapor Pressure: 1 mm Hg @ 38.7
Viscosity: Not available.
Boiling Point: 184.35 deg C
Freezing/Melting Point: 113.5 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Sublimes
Solubility in water: Slightly soluble.
Specific Gravity/Density: 4.93
Molecular Formula: I2
Molecular Weight: 253.81
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Powdered aluminum, active metals. Acetylene, acetaldehyde cause
explosive reactions. Iodine reacts with ammonium hydroxide to form
shock sensitive compounds that are explosive when dry.
Hazardous Decomposition Products:
Hydrogen iodide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7553-56-2: NN1575000
LD50/LC50:
CAS# 7553-56-2: Oral, mouse: LD50 = 22 gm/kg; Oral, mouse: LD50 =
1000 mg/kg; Oral, rabbit: LD50 = 10 gm/kg; Oral, rat: LD50 = 14
gm/kg.
Carcinogenicity:
Iodine -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish, LC50: 28.5 mg/kg
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/21 Harmful by inhalation and in contact with
skin.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 25 Avoid contact with eyes.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7553-56-2: 1
Canada
CAS# 7553-56-2 is listed on Canada's DSL List.
CAS# 7553-56-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7553-56-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #7 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Potassium Iodide, 99%, Briquettes
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Carbazole, 99% (UV-Vis)
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Calcium Carbonate, 98.5%
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Calcium Carbonate (Chips), 97% (Titr.)
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Ethyl 2-benzylacetoacetate, 97%
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2-(4-Nitrophenoxy)tetradecanoyl Chloride, 92% (HPLC)
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Calcium Carbonate, Light Powder
| 471-34-1 |
|
1,5-Difluoro-2,4-dinitrobenzene, 97 %
| 327-92-4 |
|
Calcium Carbonate, Reagent ACS (Powder), 99+% (Titr.)
| 471-34-1 |
|
Calcium Carbonate, P.A. (Precipitated, Heavy)
| 471-34-1 |
|
Calcium Carbonate, Low in Alkalies, Reagent ACS (Powder), 99+%
| 471-34-1 |
|
Calcium Chloride, Anhydrous Powder, 95%, P.A.
| 10043-52-4 |
|
Calcium Chloride Dihydrate 77 - 80% CaCl2 Flakes for Drying Purposes
| 10035-04-8 |
|
Calcium Chloride Dihydrate, P.A.
| 10035-04-8 |
|
Calcium Chloride Dihydrate, Reagent ACS
| 10035-04-8 |
|
Hydrochloric Acid, 0.1 N Solution
| 7647-01-0 |
|
Calcium Fluoride, 99%, Anhydrous
| 7789-75-5 |
|
Benzoyl Chloride, 99%
| 98-88-4 |
|
Deoxycholic acid, sodium salt, 99%
| 302-95-4 |
|
Methyl myristate 99%
| 124-10-7 |
|
Methyltriphenoxyphosphonium iodide
| 17579-99-6 |
|
Copper phthalocyanine-3,4',4",4"'-tetrasul fonic acid,tetrasodium
| 123439-80-5 |
|
Ethylenebis(oxyethylenenitrilo)tetraacetic acid, 97%
| 67-42-5 |
|
Ethylenebis(oxyethylenenitrilo)tetraacetic acid, 99%
| 67-42-5 |
|
Poly(Methyl Methacrylate), Average M.W. 15000(GPC)
| 9011-14-7 |
|
Poly(Methyl Methacrylate), Sec. Stand., M. W. 93300, N.N. 46400, Fine
| 9011-14-7 |
|
Poly(Methyl Methacrylate), Nominal M.W. 38000, Beads
| 9011-14-7 |
|
Poly(Methyl Methacrylate), Average M.W. 500.000
| 9011-14-7 |
|
Heparin Sodium
| 9041-08-1 |
|
Iodine, reagent ACS, 99.8%
| 7553-56-2 |
|
Iodine, resublimed, p.a.
| 7553-56-2 |
|
Iodine, 0.1N Standard Solution
| 7553-56-2 |
|
3,3'-Diethyloxadicarbocyanine Iodide, Laser Grade, 99% (UV-Vis)
| 14806-50-9 |
|
Copper (II) Chloride Dihydrate, Tech., 95%
| 10125-13-0 |
|
Copper (II) Chloride Dihydrate, Reagent (Powder), 99% (Titr.)
| 10125-13-0 |
|
Copper (II) Chloride Dihydrate, P.A.
| 10125-13-0 |
|
Copper (I) Chloride, 95+%
| 7758-89-6 |
|
Copper (I) Chloride, Purified, 99%
| 7758-89-6 |
|
3-Hexyn-1-ol, 98%
| 1002-28-4 |
|
Copper (I) Chloride, 99.99%
| 7758-89-6 |
|
Copper (I) Chloride, P.A.
| 7758-89-6 |
|
Copper (I) Chloride, Reagent ACS (Powder), 90+% (Titr.)
| 7758-89-6 |
|
Cyclohexane, Reagent ACS, Spectro Grade, 99+% (GC)
| 110-82-7 |
|
Cyclohexane, 99+%
| 110-82-7 |
|
Cyclohexane, P.A.
| 110-82-7 |
|
Cyclohexane for HPLC
| 110-82-7 |
|
Ammonium molybdate(VI) tetrahydrate, p.a.
| 12027-67-7 |
|
|