**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10125-13-0 |Copper(II) Chloride Dihydrate | 99% | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to eyes, respiratory system and
skin.Hygroscopic (absorbs moisture from the air).The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation. Exposure to particulates or solution may
cause conjunctivitis, ulceration, and corneal abnormalities.
Contact with the eyes may cause corneal damage. May cause chemical
conjunctivitis.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
May cause irritation with burning pain, itching and redness.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause hemorrhaging of the
digestive tract. The toxicological properties of this substance have
not been fully investigated.
Inhalation:
Causes respiratory tract irritation. May cause ulceration and
perforation of the nasal septum if inhaled in excessive quantities.
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count. The toxicological properties of this substance have
not been fully investigated. May be harmful if inhaled. Can produce
delayed pulmonary edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed. Individuals with Wilson's disease are unable to
metabolize copper. Thus, copper accumulates in various tissues and
may result in liver, kidney, and brain damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Wear
appropriate protective clothing to prevent contact with skin and
eyes. Wear a self-contained breathing apparatus (SCBA) to prevent
contact with thermal decomposition products. Use extinguishing media
appropriate to the surrounding fire. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10125-13-0:
United Kingdom, WEL - TWA: (listed as copper): 0.2 mg/m3 TWA (fum
1 mg/m3 TWA (dust and mist)
United Kingdom, WEL - STEL: (listed as copper): 0.6 mg/m3 STEL
(fume); 2 mg/m3 STEL (dust and mist)
United States OSHA: 0.1 mg/m3 TWA (fume); 1 mg/m3 TWA (dusts and
mists) (listed under Copper).
Belgium - TWA: (listed as copper): 0.2 mg/m3 VLE (fume); 1 mg/m3
(dust and mist)
France - VME: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 V
(dust, as Cu)
France - VLE: (listed as copper): 2 mg/m3 VLE (dust, as Cu)
Germany: (listed as copper): 0.2 mg/m3 VME (fume); 1 mg/m3 VME (d
as Cu)
Malaysia: (listed as copper): 0.2 mg/m3 TWA (fume, as Cu); 1 mg/m
TWA (dust and mist, as Cu)
Netherlands: (listed as copper): 0.2 mg/m3 MAC (smoke); 1 mg/m3 M
(dust)
Russia: (listed as copper): 1 mg/m3 TWA (dust)
Russia: (listed as copper): 0.5 mg/m3 STEL (dust)
Spain: (listed as copper): 0.2 mg/m3 VLA-ED (fume); 1 mg/m3 VLA-E
(dust and mist, as Cu)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: green
Odor: odorless
pH: 3.6 for 0.2 M soln.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 1819 deg F
Freezing/Melting Point: 212 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 1819 deg F
Solubility in water: 1150 g/l (5% aq.sol.) in water.
Specific Gravity/Density: 2.54 (water=1)
Molecular Formula: CuCl2.2H2O
Molecular Weight: 170.4788
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, acids, excess heat, exposure
to moist air or water.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, chloride
fumes.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10125-13-0: GL7030000
LD50/LC50:
Not available.
Carcinogenicity:
Copper(II) Chloride Dihydrate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: COPPER CHLORIDE
Hazard Class: 8
UN Number: 2802
Packing Group: III
IMO
Shipping Name: COPPER CHLORIDE
Hazard Class: 8
UN Number: 2802
Packing Group: III
RID/ADR
Shipping Name: COPPER CHLORIDE
Hazard Class: 8
UN Number: 2802
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 20 When using do not eat or drink.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10125-13-0: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10125-13-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10125-13-0 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/09/1999 Revision #3 Date: 1/03/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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