**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10025-65-7 |Platinum (III) chloride | 73.0 | 233-034-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38 42/43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. May cause
sensitization by inhalation and skin contact.
Potential Health Effects
Eye:
Causes eye irritation. In the eyes, the dusts cause a burning
sensation, tearing, and conjunctival hyperemia (an excess of blood
in a part), sometimes associated with photophobia.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Contact with the skin may cause urticaria (hives).
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May cause asthmatic attacks due
to allergic sensitization of the respiratory tract. Causes irritation
of mucous membrane. Inhalation may produce tearing, sneezing,
rhinorrhea (the free discharge of a thin nasal mucus), cough, dyspnea
(labored breathing), bronchial asthma, and cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation may cause effects similar to those of acute inhalation.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 10025-65-7:
United States OSHA: 0.002 mg/m3 TWA (as Pt) (listed under Platin
soluble salts).
Belgium - TWA: (listed as platinum soluble salts): 0.002 mg/m3 VL
(as Pt)
Japan: (listed as platinum soluble salts): 0.001 mg/m3 OEL (as Pt
Malaysia: (listed as platinum soluble salts): 0.002 mg/m3 TWA (as
Netherlands: (listed as platinum soluble salts): 0.002 mg/m3 MAC
Pt)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: yellow-green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 581 deg C dec
Autoignition Temperature: Not available.
Flash Point: 580 deg C ( 1,076.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 580 deg C
Solubility in water: insoluble
Specific Gravity/Density: 5.87
Molecular Formula: Cl2Pt
Molecular Weight: 266.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10025-65-7: TP2275000
LD50/LC50:
CAS# 10025-65-7: Draize test, rabbit, skin: 100 mg/24H Mild; Oral,
rat: LD50 = 3423 mg/kg.
Carcinogenicity:
Platinum (III) chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3260
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 42/43 May cause sensitization by inhalation and
skin contact.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 10025-65-7: 1
Canada
CAS# 10025-65-7 is listed on Canada's DSL List.
CAS# 10025-65-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10025-65-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3'-Aminoacetophenone, 97%
| 99-03-6 |
|
8-Azaguanine, 98%
| 134-58-7 |
|
N,N-Dimethyl-p-phenylenediamine oxalate, 99% (titr.)
| 62778-12-5 |
|
4-Ethoxy-2-Buten-1-ol, 98% (Mixt. Cis and Trans Isomers)
| 123093-78-7 |
|
Decanoyl Chloride, 98%
| 112-13-0 |
|
N,N'-Bis(3-Aminopropyl)-1,3-Propane- Diamine, 97% (Titr.)
| 4605-14-5 |
|
2,3-Bis-(Bromomethyl)Quinoxaline, 98%
| 3138-86-1 |
|
4-N-propylbiphenyl-4'-carboxylic acid, 98%
| 88038-94-2 |
|
4-Nitrobenzoyl chloride, 98%
| 122-04-3 |
|
N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine, 99% (titr.)
| 140-07-8 |
|
2-(4-Carboxyphenoxy)-2-Pivaloyl-2',4'-Dichloroacetanilide, 96% (HPLC)
| 58161-93-6 |
|
Ethyl 7-nitroindole-2-carboxylate, 95+%
| 6960-46-9 |
|
Cyclohexanecarboxylic Acid Chloride, 98% by Titration
| 2719-27-9 |
|
Gadolinium atomic absorption standard solution, 1 mg/ml Gd in 2% HNO3
| 7440-54-2 |
|
trans-1,2-Dichlorocyclohexane, 97%
| 822-86-6 |
|
Ethyl 4-fluorobenzoate ,99%
| 451-46-7 |
|
4-Aminophenyl ether, 98%
| 101-80-4 |
|
Dodecylthioacetonitrile, 92% (GC)
| 51956-42-4 |
|
Cyclopropyl bromide, 99%
| 4333-56-6 |
|
Hydrogenhexahydroxyplatinate (IV), ca. 64% Pt
| 51850-20-5 |
|
Trimethyl-1,5,9-Cyclododecatriene (Mixture of Isomers), 98%
| 27193-69-7 |
|
4,4'-Diamino-2,2'-biphenyldisulfonic acid (techn), 85% (titr.)
| 117-61-3 |
|
Valeramide
| 626-97-1 |
|
4-(Chloromethyl)-3,5-Dimethyl-Isoxazole 98%
| 19788-37-5 |
|
1,2,4-Trimethylbenzene, 98%
| 95-63-6 |
|
Sec-Butyl Disulfide, 98%
| 593-30-6 |
|
Platinum(ii) chloride, 73% pt
| 10025-65-7 |
|
8-Azahypoxanthine, 98%
| 2683-90-1 |
|
(2-Bromoethyl)-Trimethylammonium Bromide, 98%
| 2758-06-7 |
|
3',5'-Dihydroxyacetophenone, 97%
| 51863-60-6 |
|
4,5-Dimethoxy-2-Mercapto-Benzylamine Hydrochloride, 92%
| 21407-29-4 |
|
4-Amino-2-methylmercaptoquinazoline
| 63963-40-6 |
|
Z-1,3-Dichloropropene
| 542-75-6 |
|
4-Fluorosulfonyl-1-hydroxy-2-naphthoic acid, 99%
| 839-78-1 |
|
Tris(2-ethylhexyl)trimellitate, 98%
| 3319-31-1 |
|
4-Methoxyphenol, 99%
| 150-76-5 |
|
Rose bengal, high purity biological stain
| 632-69-9 |
|
Thionicotinamide, 99%
| 4621-66-3 |
|
Magnesium iodate tetrahydrate, 98%
| 0-00-1 |
|
Harmaline hydrochloride dihydrate
| 6027-98-1 |
|
Trans-Aconitic Acid, 98%
| 4023-65-8 |
|
3,4-Dichlorobenzophenone, 99%
| 6284-79-3 |
|
1,4-Dichloro-2,3-butanediol, mixture of DL- and meso, 99.0%
| 2419-73-0 |
|
Di-n-octadecyl phosphite, 95% c18, (gc)
| 19047-85-9 |
|
Aza-12-Crown-4, 99.5+%
| 41775-76-2 |
|
4-Isopropylaniline, 99%
| 99-88-7 |
|
sec-Butylbenzene, 99+%
| 135-98-8 |
|
Ethyl Carbanilate
| 101-99-5 |
|
2-Chloronicotinic Acid, 98%
| 2942-59-8 |
|
2-Bromoacetamide, 98%
| 683-57-8 |
|
|