**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 122-04-3 |4-Nitrobenzoyl chloride | 98 | 204-517-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Moisture sensitive.
Potential Health Effects
Eye:
Lachrymator (substance which increases the flow of tears). Causes
severe eye irritation and burns.
Skin:
Causes severe skin irritation and burns.
Ingestion:
May cause severe and permanent damage to the digestive tract.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use of
water will produce irritating and toxic vapors of hydrogen chloride.
Hydrochloric acid solutions react with most metals, forming flammable
hydrogen gas.
Extinguishing Media:
Do NOT use water directly on fire. Use carbon dioxide or dry
chemical. Do NOT get water inside containers.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Provide ventilation. Do not expose
spill to water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Keep container tightly closed.
Do not ingest or inhale. Use with adequate ventilation. Discard
contaminated shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 122-04-3:
Russia: 0.2 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Flakes
Color: yellow
Odor: pungent odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 202-205 deg C @ 105 mm Hg
Freezing/Melting Point: > 71.5 deg C
Autoignition Temperature: Not available.
Flash Point: 102 deg C ( 215.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Hydrolysis.
Specific Gravity/Density:
Molecular Formula: C7H4ClNO3
Molecular Weight: 185.57
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Material hydrolyzes
in contact with moisture/water releasing toxic and corrosive fumes
of hydrogen chloride and aqueous hydrochloric acid.
Conditions to Avoid:
Dust generation, moisture.
Incompatibilities with Other Materials:
Alcohols, strong bases, strong oxidizing agents, amines.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, phosgene, carbon monoxide, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 122-04-3: DM6651000
LD50/LC50:
CAS# 122-04-3: Oral, mouse: LD50 = 3440 mg/kg; Oral, rabbit: LD50 =
4750 mg/kg; Oral, rat: LD50 = 5600 mg/kg.
Carcinogenicity:
4-Nitrobenzoyl chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, N.O.S.*
Hazard Class: 8
UN Number: 1759
Packing Group: II
IMO
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE SOLID, N.O.S.
Hazard Class: 8
UN Number: 1759
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 122-04-3: 2
Canada
CAS# 122-04-3 is listed on Canada's DSL List.
CAS# 122-04-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 122-04-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/14/1998 Revision #3 Date: 9/30/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3'-Aminoacetophenone, 97%
| 99-03-6 |
|
8-Azaguanine, 98%
| 134-58-7 |
|
N,N-Dimethyl-p-phenylenediamine oxalate, 99% (titr.)
| 62778-12-5 |
|
4-Ethoxy-2-Buten-1-ol, 98% (Mixt. Cis and Trans Isomers)
| 123093-78-7 |
|
Decanoyl Chloride, 98%
| 112-13-0 |
|
N,N'-Bis(3-Aminopropyl)-1,3-Propane- Diamine, 97% (Titr.)
| 4605-14-5 |
|
2,3-Bis-(Bromomethyl)Quinoxaline, 98%
| 3138-86-1 |
|
4-N-propylbiphenyl-4'-carboxylic acid, 98%
| 88038-94-2 |
|
4-Nitrobenzoyl chloride, 98%
| 122-04-3 |
|
N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine, 99% (titr.)
| 140-07-8 |
|
2-(4-Carboxyphenoxy)-2-Pivaloyl-2',4'-Dichloroacetanilide, 96% (HPLC)
| 58161-93-6 |
|
Ethyl 7-nitroindole-2-carboxylate, 95+%
| 6960-46-9 |
|
Cyclohexanecarboxylic Acid Chloride, 98% by Titration
| 2719-27-9 |
|
Gadolinium atomic absorption standard solution, 1 mg/ml Gd in 2% HNO3
| 7440-54-2 |
|
trans-1,2-Dichlorocyclohexane, 97%
| 822-86-6 |
|
Ethyl 4-fluorobenzoate ,99%
| 451-46-7 |
|
4-Aminophenyl ether, 98%
| 101-80-4 |
|
Dodecylthioacetonitrile, 92% (GC)
| 51956-42-4 |
|
Cyclopropyl bromide, 99%
| 4333-56-6 |
|
Hydrogenhexahydroxyplatinate (IV), ca. 64% Pt
| 51850-20-5 |
|
Trimethyl-1,5,9-Cyclododecatriene (Mixture of Isomers), 98%
| 27193-69-7 |
|
4,4'-Diamino-2,2'-biphenyldisulfonic acid (techn), 85% (titr.)
| 117-61-3 |
|
Valeramide
| 626-97-1 |
|
4-(Chloromethyl)-3,5-Dimethyl-Isoxazole 98%
| 19788-37-5 |
|
1,2,4-Trimethylbenzene, 98%
| 95-63-6 |
|
Sec-Butyl Disulfide, 98%
| 593-30-6 |
|
Platinum(ii) chloride, 73% pt
| 10025-65-7 |
|
8-Azahypoxanthine, 98%
| 2683-90-1 |
|
(2-Bromoethyl)-Trimethylammonium Bromide, 98%
| 2758-06-7 |
|
3',5'-Dihydroxyacetophenone, 97%
| 51863-60-6 |
|
4,5-Dimethoxy-2-Mercapto-Benzylamine Hydrochloride, 92%
| 21407-29-4 |
|
4-Amino-2-methylmercaptoquinazoline
| 63963-40-6 |
|
Z-1,3-Dichloropropene
| 542-75-6 |
|
4-Fluorosulfonyl-1-hydroxy-2-naphthoic acid, 99%
| 839-78-1 |
|
Tris(2-ethylhexyl)trimellitate, 98%
| 3319-31-1 |
|
4-Methoxyphenol, 99%
| 150-76-5 |
|
Rose bengal, high purity biological stain
| 632-69-9 |
|
Thionicotinamide, 99%
| 4621-66-3 |
|
Magnesium iodate tetrahydrate, 98%
| 0-00-1 |
|
Harmaline hydrochloride dihydrate
| 6027-98-1 |
|
Trans-Aconitic Acid, 98%
| 4023-65-8 |
|
3,4-Dichlorobenzophenone, 99%
| 6284-79-3 |
|
1,4-Dichloro-2,3-butanediol, mixture of DL- and meso, 99.0%
| 2419-73-0 |
|
Di-n-octadecyl phosphite, 95% c18, (gc)
| 19047-85-9 |
|
Aza-12-Crown-4, 99.5+%
| 41775-76-2 |
|
4-Isopropylaniline, 99%
| 99-88-7 |
|
sec-Butylbenzene, 99+%
| 135-98-8 |
|
Ethyl Carbanilate
| 101-99-5 |
|
2-Chloronicotinic Acid, 98%
| 2942-59-8 |
|
2-Bromoacetamide, 98%
| 683-57-8 |
|
|