**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 21407-29-4 |4,5-Dimethoxy-2-Mercapto-Benzylamine H| 92 | unlisted |
| |ydrochloride | | |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Stench.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause perforation of the digestive
tract. Mercaptans may cause nausea and headache. Exposure to high
concentrations of mercaptans can produce unconsciousness with
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), cold extremities and rapid pulse. May cause systemic
effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. Exposure to high
concentrations of mercaptans can produce unconsciousness with
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), cold extremities and rapid pulse. Mercaptans may cause
nausea and headache.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Contact with metals may
evolve flammable hydrogen gas. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Do not breathe dust,
vapor, mist, or gas. Do not get in eyes, on skin, or on clothing.
Keep container tightly closed. Do not ingest or inhale. Discard
contaminated shoes.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 21407-29-4:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: beige
Odor: stench
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 175.00 - 180.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density:
Molecular Formula: C9H13NO2S.HCl
Molecular Weight: 235.73
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of
sulfur, irritating and toxic fumes and gases, carbon dioxide,
hydrogen sulfide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 21407-29-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4,5-Dimethoxy-2-Mercapto-Benzylamine Hydrochloride -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: II
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 21407-29-4: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 21407-29-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 21407-29-4 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #5 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
3'-Aminoacetophenone, 97%
| 99-03-6 |
|
8-Azaguanine, 98%
| 134-58-7 |
|
N,N-Dimethyl-p-phenylenediamine oxalate, 99% (titr.)
| 62778-12-5 |
|
4-Ethoxy-2-Buten-1-ol, 98% (Mixt. Cis and Trans Isomers)
| 123093-78-7 |
|
Decanoyl Chloride, 98%
| 112-13-0 |
|
N,N'-Bis(3-Aminopropyl)-1,3-Propane- Diamine, 97% (Titr.)
| 4605-14-5 |
|
2,3-Bis-(Bromomethyl)Quinoxaline, 98%
| 3138-86-1 |
|
4-N-propylbiphenyl-4'-carboxylic acid, 98%
| 88038-94-2 |
|
4-Nitrobenzoyl chloride, 98%
| 122-04-3 |
|
N,N,N',N'-Tetrakis(2-hydroxyethyl)ethylenediamine, 99% (titr.)
| 140-07-8 |
|
2-(4-Carboxyphenoxy)-2-Pivaloyl-2',4'-Dichloroacetanilide, 96% (HPLC)
| 58161-93-6 |
|
Ethyl 7-nitroindole-2-carboxylate, 95+%
| 6960-46-9 |
|
Cyclohexanecarboxylic Acid Chloride, 98% by Titration
| 2719-27-9 |
|
Gadolinium atomic absorption standard solution, 1 mg/ml Gd in 2% HNO3
| 7440-54-2 |
|
trans-1,2-Dichlorocyclohexane, 97%
| 822-86-6 |
|
Ethyl 4-fluorobenzoate ,99%
| 451-46-7 |
|
4-Aminophenyl ether, 98%
| 101-80-4 |
|
Dodecylthioacetonitrile, 92% (GC)
| 51956-42-4 |
|
Cyclopropyl bromide, 99%
| 4333-56-6 |
|
Hydrogenhexahydroxyplatinate (IV), ca. 64% Pt
| 51850-20-5 |
|
Trimethyl-1,5,9-Cyclododecatriene (Mixture of Isomers), 98%
| 27193-69-7 |
|
4,4'-Diamino-2,2'-biphenyldisulfonic acid (techn), 85% (titr.)
| 117-61-3 |
|
Valeramide
| 626-97-1 |
|
4-(Chloromethyl)-3,5-Dimethyl-Isoxazole 98%
| 19788-37-5 |
|
1,2,4-Trimethylbenzene, 98%
| 95-63-6 |
|
Sec-Butyl Disulfide, 98%
| 593-30-6 |
|
Platinum(ii) chloride, 73% pt
| 10025-65-7 |
|
8-Azahypoxanthine, 98%
| 2683-90-1 |
|
(2-Bromoethyl)-Trimethylammonium Bromide, 98%
| 2758-06-7 |
|
3',5'-Dihydroxyacetophenone, 97%
| 51863-60-6 |
|
4,5-Dimethoxy-2-Mercapto-Benzylamine Hydrochloride, 92%
| 21407-29-4 |
|
4-Amino-2-methylmercaptoquinazoline
| 63963-40-6 |
|
Z-1,3-Dichloropropene
| 542-75-6 |
|
4-Fluorosulfonyl-1-hydroxy-2-naphthoic acid, 99%
| 839-78-1 |
|
Tris(2-ethylhexyl)trimellitate, 98%
| 3319-31-1 |
|
4-Methoxyphenol, 99%
| 150-76-5 |
|
Rose bengal, high purity biological stain
| 632-69-9 |
|
Thionicotinamide, 99%
| 4621-66-3 |
|
Magnesium iodate tetrahydrate, 98%
| 0-00-1 |
|
Harmaline hydrochloride dihydrate
| 6027-98-1 |
|
Trans-Aconitic Acid, 98%
| 4023-65-8 |
|
3,4-Dichlorobenzophenone, 99%
| 6284-79-3 |
|
1,4-Dichloro-2,3-butanediol, mixture of DL- and meso, 99.0%
| 2419-73-0 |
|
Di-n-octadecyl phosphite, 95% c18, (gc)
| 19047-85-9 |
|
Aza-12-Crown-4, 99.5+%
| 41775-76-2 |
|
4-Isopropylaniline, 99%
| 99-88-7 |
|
sec-Butylbenzene, 99+%
| 135-98-8 |
|
Ethyl Carbanilate
| 101-99-5 |
|
2-Chloronicotinic Acid, 98%
| 2942-59-8 |
|
2-Bromoacetamide, 98%
| 683-57-8 |
|
|