**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1003-38-9 |2,5-dimethyltetrahydrofuran | 99 | 213-707-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to eyes, respiratory system and skin.The
toxicological properties of this material have not been fully
investigated.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
Causes skin irritation. May cause irritation and dermatitis. May
cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Ingestion of large amounts may cause CNS
depression.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. Aspiration may lead
to pulmonary edema. Vapors may cause dizziness or suffocation. Can
produce delayed pulmonary edema. May cause burning sensation in the
chest.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Remove contaminated clothing and shoes.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Avoid ingestion and inhalation. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 1003-38-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 90 -92 deg C @ 760.00mmHg
Freezing/Melting Point: -45 deg C
Autoignition Temperature: Not available.
Flash Point: 26 deg C ( 78.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: miscible
Specific Gravity/Density: .8330g/cm3
Molecular Formula: C6H12O
Molecular Weight: 100.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1003-38-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2,5-dimethyltetrahydrofuran -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.2
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1003-38-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1003-38-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1003-38-9 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/01/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Palladium(ii) trifluoroacetate
| 42196-31-6 |
|
Nitrilotriacetic acid, disodium salt, 99+%
| 15467-20-6 |
|
Tetramethylphosphonium Bromide, 98%
| 4519-28-2 |
|
Zinc trifluoromethanesulfonate, 98%
| 54010-75-2 |
|
Phosphomolybdic acid, ammonium salt hydrate
| 54723-94-3 |
|
Triethylphosphine, 99%
| 554-70-1 |
|
5-Chloro-N-Methyl-2-Nitrobenzenamine, 99%
| 35966-84-8 |
|
Cadmium acetate dihydrate, 98%
| 543-90-8 |
|
(1-Bromoethyl)benzene, 97%
| 585-71-7 |
|
1,2,4-Tribromobenzene
| 615-54-3 |
|
3,5-Dibromo-4-Hydroxybenzoic Acid, 99%
| 3337-62-0 |
|
3,6-Thioxanthenediamine-10,10-Dioxide
| 10215-25-5 |
|
Rubidium Carbonate, 99%
| 584-09-8 |
|
Europium(iii) carbonate hydrate, 99.9%
| 5895-48-7 |
|
Dimethylmercury, 95%
| 593-74-8 |
|
2,5-Dimethyltetrahydrofuran 99% , Mixture of Cis/Trans
| 1003-38-9 |
|
Triphenylantimony dichloride, 99%
| 594-31-0 |
|
Tetraethylgermane, 99%
| 597-63-7 |
|
Zinc Acetate Dihydrate, Reagent ACS, 98+%
| 5970-45-6 |
|
(s)-(-)-1,2-Propanediol di-p-tosylate, 99%
| 60434-71-1 |
|
Lead(II)Acetate Trihydrate, 99.999%
| 6080-56-4 |
|
Lithium Formate Monohydrate, 98%
| 6108-23-2 |
|
Niobium(iv) chloride-tetrahydrofuran complex
| 61247-57-2 |
|
Tributyltin deuteride
| 6180-99-0 |
|
Tri-m-tolylphosphine, 98%
| 6224-63-1 |
|
Chlorotriphenyltin, 95%
| 639-58-7 |
|
Triisopropylphosphine
| 6476-36-4 |
|
bis(Diethylamino)chlorophosphine, 97%
| 685-83-6 |
|
Benzylmagnesium chloride, 2.0 m solution i n tetrahydrofuran
| 6921-34-2 |
|
Calcium Iodide Hydrate, 98%
| 71626-98-7 |
|
Dysprosium, ingot, 99.9%
| 7429-91-6 |
|
Dysprosium, chip, 99.9%
| 7429-91-6 |
|
Lutetium, ingot, 99.9%
| 7439-94-3 |
|
Manganese, powder, -325 mesh, 99+%
| 7439-96-5 |
|
Neodymium, ingot, 99.9%
| 7440-00-8 |
|
Niobium, powder, -60 to -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, rod, 6.35 mm diam., 99.8%
| 7440-03-1 |
|
Niobium, powder, -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, wire, 1.0 mm diam., 99.8%
| 7440-03-1 |
|
Palladium on calcium carbonate, unreduced (5% Pd)
| 471-34-1 |
|
Palladium on Barium Sulfate, Reduced (5% Pd)
| 7440-05-3 |
|
Palladium on barium carbonate, reduced (5% pd)
| 7440-05-3 |
|
1-(2-Aminophenyl)Pyrrole, 98+%
| 6025-60-1 |
|
Praseodymium, foil, 0.25 mm thick, 99.9%
| 7440-10-0 |
|
Praseodymium, chip, 99.9%
| 7440-10-0 |
|
Praseodymium, powder, -40 mesh, 99.9%
| 7440-10-0 |
|
Praseodymium, ingot, 99.9%
| 7440-10-0 |
|
Rhenium on carbon (5% re)
| 7440-15-5 |
|
Rhenium, foil, 0.1 mm thick, 99.98%
| 7440-15-5 |
|
Silver, Wire, 0.5 mm Diam., 99.9%
| 7440-22-4 |
|
|