**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 471-34-1 |Carbonic acid, calcium salt (1:1) | 95 | 207-439-9 |
|----------------|--------------------------------------|----------|-----------|
| 7440-05-3 |Palladium | 5 | 231-115-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause sensitization by skin contact.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Chronic ingestion may cause hypercalcemia, alkalosis, and kidney
damage. May also produce "milk-alkali syndrome" characterized by
neurological symptoms such as irritability, lethargy, stupor, and
coma.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Chronic ingestion may cause hypercalcemia, alkalosis, and kidney
damage. May also produce "milk-alkali syndrome" characterized by
neurological symptoms such as irritability, lethargy, stupor, and
coma.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Use
agent most appropriate to extinguish fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Minimize dust generation and accumulation.
Avoid breathing dust, vapor, mist, or gas. Do not get on skin or in
eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep away from strong acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low. Use
process enclosure, local exhaust ventilation, or other engineering
controls to control airborne levels.
Exposure Limits
CAS# 471-34-1:
United Kingdom, WEL - TWA: (listed as calcium carbonate): 10 mg/m
TWA (inhalable dust); 4 mg/m3 TWA (respirable dust)
United Kingdom, WEL - STEL: (listed as calcium carbonate): 30 mg/
STEL (inhalable dust); 12 mg/m3 STEL (respirable dust)
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction) (listed under Calcium carbonate).
Belgium - TWA: (listed as calcium carbonate): 10 mg/m3 VLE
France - VME: (listed as calcium carbonate): 10 mg/m3 VME
Germany: (listed as calcium carbonate): 10 mg/m3 VME
Japan: (listed as calcium carbonate): 1 mg/m3 OEL (respirable dus
4 mg/m3 OEL (total dust)
Malaysia: (listed as calcium carbonate): 10 mg/m3 TWA (particulat
matter containing no asbestos and <1% crystalline sili
Netherlands: 10 mg/m3 MAC
Russia: 6 mg/m3 TWA
Spain: 10 mg/m3 VLA-ED
CAS# 7440-05-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: gray or dark gray
Odor: Odorless.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: >600 deg C
Solubility in water: insoluble
Specific Gravity/Density: 12.02 g/cm3
Molecular Formula: Not applicable.
Molecular Weight:
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, acids.
Incompatibilities with Other Materials:
Fluorine, acids, aluminum, ammonium salts, mercury + hydrogen,
hydrogen + hydrogen peroxide, isopropyl alcohol, formic acid and
sodium tetrahydroborate.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, hydrogen gas, calcium oxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 471-34-1: FF9335000
CAS# 7440-05-3: RT3480500 RT3593400
LD50/LC50:
CAS# 471-34-1: Draize test, rabbit, eye: 750 ug/24H Severe; Draize
test, rabbit, skin: 500 mg/24H Moderate; Oral, rat: LD50 = 6450
mg/kg.
CAS# 7440-05-3.
Carcinogenicity:
Carbonic acid, calcium salt (1:1) -
Not listed by ACGIH, IARC, or NTP.
Palladium -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
This chemical is expected to cause no oxygen depletion in aquatic
systems. It has a low potential to affect aquatic organisms. Acute
aquatic effects: 48-hour LC50; Mosquito fish: 56,000 mg/L.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 471-34-1: 0
CAS# 7440-05-3: 0
Canada
CAS# 471-34-1 is listed on Canada's DSL List.
CAS# 7440-05-3 is listed on Canada's DSL List.
CAS# 471-34-1 is not listed on Canada's Ingredient Disclosure List.
CAS# 7440-05-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 471-34-1 is listed on the TSCA inventory.
CAS# 7440-05-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 36 Irritating to eyes.
MSDS Creation Date: 1/12/1998 Revision #3 Date: 2/25/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Palladium(ii) trifluoroacetate
| 42196-31-6 |
|
Nitrilotriacetic acid, disodium salt, 99+%
| 15467-20-6 |
|
Tetramethylphosphonium Bromide, 98%
| 4519-28-2 |
|
Zinc trifluoromethanesulfonate, 98%
| 54010-75-2 |
|
Phosphomolybdic acid, ammonium salt hydrate
| 54723-94-3 |
|
Triethylphosphine, 99%
| 554-70-1 |
|
5-Chloro-N-Methyl-2-Nitrobenzenamine, 99%
| 35966-84-8 |
|
Cadmium acetate dihydrate, 98%
| 543-90-8 |
|
(1-Bromoethyl)benzene, 97%
| 585-71-7 |
|
1,2,4-Tribromobenzene
| 615-54-3 |
|
3,5-Dibromo-4-Hydroxybenzoic Acid, 99%
| 3337-62-0 |
|
3,6-Thioxanthenediamine-10,10-Dioxide
| 10215-25-5 |
|
Rubidium Carbonate, 99%
| 584-09-8 |
|
Europium(iii) carbonate hydrate, 99.9%
| 5895-48-7 |
|
Dimethylmercury, 95%
| 593-74-8 |
|
2,5-Dimethyltetrahydrofuran 99% , Mixture of Cis/Trans
| 1003-38-9 |
|
Triphenylantimony dichloride, 99%
| 594-31-0 |
|
Tetraethylgermane, 99%
| 597-63-7 |
|
Zinc Acetate Dihydrate, Reagent ACS, 98+%
| 5970-45-6 |
|
(s)-(-)-1,2-Propanediol di-p-tosylate, 99%
| 60434-71-1 |
|
Lead(II)Acetate Trihydrate, 99.999%
| 6080-56-4 |
|
Lithium Formate Monohydrate, 98%
| 6108-23-2 |
|
Niobium(iv) chloride-tetrahydrofuran complex
| 61247-57-2 |
|
Tributyltin deuteride
| 6180-99-0 |
|
Tri-m-tolylphosphine, 98%
| 6224-63-1 |
|
Chlorotriphenyltin, 95%
| 639-58-7 |
|
Triisopropylphosphine
| 6476-36-4 |
|
bis(Diethylamino)chlorophosphine, 97%
| 685-83-6 |
|
Benzylmagnesium chloride, 2.0 m solution i n tetrahydrofuran
| 6921-34-2 |
|
Calcium Iodide Hydrate, 98%
| 71626-98-7 |
|
Dysprosium, ingot, 99.9%
| 7429-91-6 |
|
Dysprosium, chip, 99.9%
| 7429-91-6 |
|
Lutetium, ingot, 99.9%
| 7439-94-3 |
|
Manganese, powder, -325 mesh, 99+%
| 7439-96-5 |
|
Neodymium, ingot, 99.9%
| 7440-00-8 |
|
Niobium, powder, -60 to -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, rod, 6.35 mm diam., 99.8%
| 7440-03-1 |
|
Niobium, powder, -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, wire, 1.0 mm diam., 99.8%
| 7440-03-1 |
|
Palladium on calcium carbonate, unreduced (5% Pd)
| 471-34-1 |
|
Palladium on Barium Sulfate, Reduced (5% Pd)
| 7440-05-3 |
|
Palladium on barium carbonate, reduced (5% pd)
| 7440-05-3 |
|
1-(2-Aminophenyl)Pyrrole, 98+%
| 6025-60-1 |
|
Praseodymium, foil, 0.25 mm thick, 99.9%
| 7440-10-0 |
|
Praseodymium, chip, 99.9%
| 7440-10-0 |
|
Praseodymium, powder, -40 mesh, 99.9%
| 7440-10-0 |
|
Praseodymium, ingot, 99.9%
| 7440-10-0 |
|
Rhenium on carbon (5% re)
| 7440-15-5 |
|
Rhenium, foil, 0.1 mm thick, 99.98%
| 7440-15-5 |
|
Silver, Wire, 0.5 mm Diam., 99.9%
| 7440-22-4 |
|
|