**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 5743-04-4 |Cadmium acetate dihydrate | 98 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN N
Risk Phrases: 20/21/22 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Very
toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Effects of contact may be delayed.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation. Effects of inhalation may be
delayed.
Chronic:
May cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, or water spray.
For large fires, use dry chemical, carbon dioxide, alcohol-resistant
foam, or water spray. Cool containers with flooding quantities of
water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. See 29CFR 1910.1027 for regulations applying to all
occupational exposures to cadmium and cadmium compounds, in all
forms.
Exposure Limits
CAS# 543-90-8:
United Kingdom, WEL - TWA: (listed as cadmium compounds): 0.025 m
TWA (except cadmium oxide fume, cadmium sulphide, cadmium sulphid
United Kingdom, WEL - STEL: (listed as cadmium compounds): 0.075
mg/m3 STEL (except cadmium oxide fume, cadmium sulphide, cadmium
sulphide
United States OSHA: 2.5 ??g/m3 Action Level (as Cd); 5 ??g/m3 PEL (
Cd. Do not eat, drink or chew t obacco or gum or apply cosmetics
regulated areas. Carcinogen: dust can cause lung and kidney
disease. See 29 CFR 1910.1027) (listed under Cadmium compounds).
Belgium - TWA: (listed as cadmium compounds): 0.002 mg/m3 VLE
(respirable particulates, as Cd); 0.01 mg/m3 VLE (inhalable part
France - VME: (listed as cadmium compounds): 0.05 mg/m3 VME (as C
Germany: (listed as cadmium compounds): 0.05 mg/m3 VME (as Cd)
Japan: (listed as cadmium compounds): 0.05 mg/m3 OEL (as Cd)
Malaysia: (listed as cadmium compounds): 0.01 mg/m3 TWA (as Cd);
0.002 mg/m3 TWA (respirable fraction, as Cd)
Russia: (listed as cadmium compounds): 0.05 mg/m3 TWA (as Cd)
Russia: (listed as cadmium compounds): 0.01 mg/m3 STEL (as Cd)
Spain: (listed as cadmium compounds): 0.01 mg/m3 VLA-ED (inhalabl
fraction, except cadmium sulfoselenide and cadmium
CAS# 5743-04-4:
United Kingdom, WEL - TWA: (listed as cadmium compounds): 0.025 m
TWA (except cadmium oxide fume, cadmium sulphide, cadmium sulphid
United Kingdom, WEL - STEL: (listed as cadmium compounds): 0.075
mg/m3 STEL (except cadmium oxide fume, cadmium sulphide, cadmium
sulphide
United States OSHA: 2.5 ??g/m3 Action Level (as Cd); 5 ??g/m3 PEL (
Cd. Do not eat, drink or chew t obacco or gum or apply cosmetics
regulated areas. Carcinogen: dust can cause lung and kidney
disease. See 29 CFR 1910.1027) (listed under Cadmium compounds).
Belgium - TWA: (listed as cadmium compounds): 0.002 mg/m3 VLE
(respirable particulates, as Cd); 0.01 mg/m3 VLE (inhalable part
France - VME: (listed as cadmium compounds): 0.05 mg/m3 VME (as C
Germany: (listed as cadmium compounds): 0.05 mg/m3 VME (as Cd)
Japan: (listed as cadmium compounds): 0.05 mg/m3 OEL (as Cd)
Malaysia: (listed as cadmium compounds): 0.01 mg/m3 TWA (as Cd);
0.002 mg/m3 TWA (respirable fraction, as Cd)
Netherlands: (listed as cadmium inorganic compounds): 0.005 mg/m3
(as Cd)
Russia: (listed as cadmium compounds): 0.05 mg/m3 TWA (as Cd)
Russia: (listed as cadmium compounds): 0.01 mg/m3 STEL (as Cd)
Spain: (listed as cadmium compounds): 0.01 mg/m3 VLA-ED (inhalabl
fraction, except cadmium sulfoselenide and cadmium
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: slight acetic acid odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble.
Specific Gravity/Density:
Molecular Formula: C4H6CdO4.2H2O
Molecular Weight: 266.52
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Cadmium fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 543-90-8: EU9810000
CAS# 5743-04-4: AF7505000
LD50/LC50:
CAS# 543-90-8: Oral, rat: LD50 = 333 mg/kg.
CAS# 5743-04-4: Oral, rat: LD50 = 360 mg/kg.
Carcinogenicity:
Cadmium acetate anhydrous -
California: carcinogen, initial date 10/1/87 (listed as Cadmium compou
NTP: Known carcinogen (listed as Cadmium compounds).
IARC: Group 1 carcinogen (listed as Cadmium compounds).
Cadmium acetate dihydrate -
California: carcinogen, initial date 10/1/87 (listed as Cadmium compou
NTP: Known carcinogen (listed as Cadmium compounds).
IARC: Group 1 carcinogen (listed as Cadmium compounds).
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing Group: III
IMO
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing Group: III
RID/ADR
Shipping Name: CADMIUM COMPOUND
Hazard Class: 6.1
UN Number: 2570
Packing group: III
USA RQ: CAS# 543-90-8: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 22 Do not breathe dust.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 543-90-8: 3
CAS# 5743-04-4: No information available.
Canada
CAS# 543-90-8 is listed on Canada's DSL List.
CAS# 543-90-8 is listed on Canada's Ingredient Disclosure List.
CAS# 5743-04-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 543-90-8 is listed on the TSCA inventory.
CAS# 5743-04-4 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 3/18/1999 Revision #3 Date: 2/17/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Palladium(ii) trifluoroacetate
| 42196-31-6 |
|
Nitrilotriacetic acid, disodium salt, 99+%
| 15467-20-6 |
|
Tetramethylphosphonium Bromide, 98%
| 4519-28-2 |
|
Zinc trifluoromethanesulfonate, 98%
| 54010-75-2 |
|
Phosphomolybdic acid, ammonium salt hydrate
| 54723-94-3 |
|
Triethylphosphine, 99%
| 554-70-1 |
|
5-Chloro-N-Methyl-2-Nitrobenzenamine, 99%
| 35966-84-8 |
|
Cadmium acetate dihydrate, 98%
| 543-90-8 |
|
(1-Bromoethyl)benzene, 97%
| 585-71-7 |
|
1,2,4-Tribromobenzene
| 615-54-3 |
|
3,5-Dibromo-4-Hydroxybenzoic Acid, 99%
| 3337-62-0 |
|
3,6-Thioxanthenediamine-10,10-Dioxide
| 10215-25-5 |
|
Rubidium Carbonate, 99%
| 584-09-8 |
|
Europium(iii) carbonate hydrate, 99.9%
| 5895-48-7 |
|
Dimethylmercury, 95%
| 593-74-8 |
|
2,5-Dimethyltetrahydrofuran 99% , Mixture of Cis/Trans
| 1003-38-9 |
|
Triphenylantimony dichloride, 99%
| 594-31-0 |
|
Tetraethylgermane, 99%
| 597-63-7 |
|
Zinc Acetate Dihydrate, Reagent ACS, 98+%
| 5970-45-6 |
|
(s)-(-)-1,2-Propanediol di-p-tosylate, 99%
| 60434-71-1 |
|
Lead(II)Acetate Trihydrate, 99.999%
| 6080-56-4 |
|
Lithium Formate Monohydrate, 98%
| 6108-23-2 |
|
Niobium(iv) chloride-tetrahydrofuran complex
| 61247-57-2 |
|
Tributyltin deuteride
| 6180-99-0 |
|
Tri-m-tolylphosphine, 98%
| 6224-63-1 |
|
Chlorotriphenyltin, 95%
| 639-58-7 |
|
Triisopropylphosphine
| 6476-36-4 |
|
bis(Diethylamino)chlorophosphine, 97%
| 685-83-6 |
|
Benzylmagnesium chloride, 2.0 m solution i n tetrahydrofuran
| 6921-34-2 |
|
Calcium Iodide Hydrate, 98%
| 71626-98-7 |
|
Dysprosium, ingot, 99.9%
| 7429-91-6 |
|
Dysprosium, chip, 99.9%
| 7429-91-6 |
|
Lutetium, ingot, 99.9%
| 7439-94-3 |
|
Manganese, powder, -325 mesh, 99+%
| 7439-96-5 |
|
Neodymium, ingot, 99.9%
| 7440-00-8 |
|
Niobium, powder, -60 to -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, rod, 6.35 mm diam., 99.8%
| 7440-03-1 |
|
Niobium, powder, -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, wire, 1.0 mm diam., 99.8%
| 7440-03-1 |
|
Palladium on calcium carbonate, unreduced (5% Pd)
| 471-34-1 |
|
Palladium on Barium Sulfate, Reduced (5% Pd)
| 7440-05-3 |
|
Palladium on barium carbonate, reduced (5% pd)
| 7440-05-3 |
|
1-(2-Aminophenyl)Pyrrole, 98+%
| 6025-60-1 |
|
Praseodymium, foil, 0.25 mm thick, 99.9%
| 7440-10-0 |
|
Praseodymium, chip, 99.9%
| 7440-10-0 |
|
Praseodymium, powder, -40 mesh, 99.9%
| 7440-10-0 |
|
Praseodymium, ingot, 99.9%
| 7440-10-0 |
|
Rhenium on carbon (5% re)
| 7440-15-5 |
|
Rhenium, foil, 0.1 mm thick, 99.98%
| 7440-15-5 |
|
Silver, Wire, 0.5 mm Diam., 99.9%
| 7440-22-4 |
|
|