**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 61247-57-2 |Niobium(IV)chloride-tetrahydrofuran co| ca. 100 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F C
Risk Phrases: 11 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Causes burns.Moisture sensitive.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable solid.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT get water inside
containers. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not get in eyes,
on skin, or on clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Do not ingest or
inhale. Use with adequate ventilation. Do not allow contact with
water. Discard contaminated shoes. Do not pressurize, cut, weld,
braze, solder, drill, grind, or expose empty containers to heat,
sparks or open flames. Keep from contact with moist air and steam.
Handle under argon.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Flammables-area.
Keep refrigerated. (Store below 4C/39F.) Store protected from
moisture. Store under argon.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 61247-57-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: gold
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 93 deg C
Autoignition Temperature: Not available.
Flash Point: 49 deg C ( 120.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H16Cl4NbO2
Molecular Weight: 378.93
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
May decompose on exposure to moist air or water.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 61247-57-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Niobium(IV)chloride-tetrahydrofuran complex -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.*
Hazard Class: 4.1 (8)
UN Number: 2925
Packing Group: III
IMO
Shipping Name: FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 4.1 (8)
UN Number: 2925
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 4.1 (8)
UN Number: 2925
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 25 Avoid contact with eyes.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 61247-57-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 61247-57-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 61247-57-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/24/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Palladium(ii) trifluoroacetate
| 42196-31-6 |
|
Nitrilotriacetic acid, disodium salt, 99+%
| 15467-20-6 |
|
Tetramethylphosphonium Bromide, 98%
| 4519-28-2 |
|
Zinc trifluoromethanesulfonate, 98%
| 54010-75-2 |
|
Phosphomolybdic acid, ammonium salt hydrate
| 54723-94-3 |
|
Triethylphosphine, 99%
| 554-70-1 |
|
5-Chloro-N-Methyl-2-Nitrobenzenamine, 99%
| 35966-84-8 |
|
Cadmium acetate dihydrate, 98%
| 543-90-8 |
|
(1-Bromoethyl)benzene, 97%
| 585-71-7 |
|
1,2,4-Tribromobenzene
| 615-54-3 |
|
3,5-Dibromo-4-Hydroxybenzoic Acid, 99%
| 3337-62-0 |
|
3,6-Thioxanthenediamine-10,10-Dioxide
| 10215-25-5 |
|
Rubidium Carbonate, 99%
| 584-09-8 |
|
Europium(iii) carbonate hydrate, 99.9%
| 5895-48-7 |
|
Dimethylmercury, 95%
| 593-74-8 |
|
2,5-Dimethyltetrahydrofuran 99% , Mixture of Cis/Trans
| 1003-38-9 |
|
Triphenylantimony dichloride, 99%
| 594-31-0 |
|
Tetraethylgermane, 99%
| 597-63-7 |
|
Zinc Acetate Dihydrate, Reagent ACS, 98+%
| 5970-45-6 |
|
(s)-(-)-1,2-Propanediol di-p-tosylate, 99%
| 60434-71-1 |
|
Lead(II)Acetate Trihydrate, 99.999%
| 6080-56-4 |
|
Lithium Formate Monohydrate, 98%
| 6108-23-2 |
|
Niobium(iv) chloride-tetrahydrofuran complex
| 61247-57-2 |
|
Tributyltin deuteride
| 6180-99-0 |
|
Tri-m-tolylphosphine, 98%
| 6224-63-1 |
|
Chlorotriphenyltin, 95%
| 639-58-7 |
|
Triisopropylphosphine
| 6476-36-4 |
|
bis(Diethylamino)chlorophosphine, 97%
| 685-83-6 |
|
Benzylmagnesium chloride, 2.0 m solution i n tetrahydrofuran
| 6921-34-2 |
|
Calcium Iodide Hydrate, 98%
| 71626-98-7 |
|
Dysprosium, ingot, 99.9%
| 7429-91-6 |
|
Dysprosium, chip, 99.9%
| 7429-91-6 |
|
Lutetium, ingot, 99.9%
| 7439-94-3 |
|
Manganese, powder, -325 mesh, 99+%
| 7439-96-5 |
|
Neodymium, ingot, 99.9%
| 7440-00-8 |
|
Niobium, powder, -60 to -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, rod, 6.35 mm diam., 99.8%
| 7440-03-1 |
|
Niobium, powder, -325 mesh, 99.8%
| 7440-03-1 |
|
Niobium, wire, 1.0 mm diam., 99.8%
| 7440-03-1 |
|
Palladium on calcium carbonate, unreduced (5% Pd)
| 471-34-1 |
|
Palladium on Barium Sulfate, Reduced (5% Pd)
| 7440-05-3 |
|
Palladium on barium carbonate, reduced (5% pd)
| 7440-05-3 |
|
1-(2-Aminophenyl)Pyrrole, 98+%
| 6025-60-1 |
|
Praseodymium, foil, 0.25 mm thick, 99.9%
| 7440-10-0 |
|
Praseodymium, chip, 99.9%
| 7440-10-0 |
|
Praseodymium, powder, -40 mesh, 99.9%
| 7440-10-0 |
|
Praseodymium, ingot, 99.9%
| 7440-10-0 |
|
Rhenium on carbon (5% re)
| 7440-15-5 |
|
Rhenium, foil, 0.1 mm thick, 99.98%
| 7440-15-5 |
|
Silver, Wire, 0.5 mm Diam., 99.9%
| 7440-22-4 |
|
|