**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10038-98-9 |Germanium Tetrachloride | 99.99% | 233-116-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 14 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Reacts violently with water. Causes burns.Water-reactive.
Potential Health Effects
Eye:
Lachrymator (substance which increases the flow of tears). Causes
eye irritation and possible burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. Inhalation may be fatal as a result of spasm,
inflammation, edema of the larynx and bronchi, chemical pneumonitis
and pulmonary edema.
Chronic:
May cause liver and kidney damage.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not allow
water to get into the container because of violent reaction. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a tightly closed container. Keep under a nitrogen blanket.
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 10038-98-9:
Russia: 1 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: Peculiar, acidic odor.
pH: Not available.
Vapor Pressure: 76 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 82 - 84 deg C @ 760.00mm Hg
Freezing/Melting Point: -49.5 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: decomposes
Specific Gravity/Density: 1.8440g/cm3
Molecular Formula: Cl4Ge
Molecular Weight: 214.40
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, contact with water, exposure to moist air or
water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10038-98-9: LY5225000
LD50/LC50:
CAS# 10038-98-9: Draize test, rabbit, eye: 50 mg Severe; Inhalation,
mouse: LC50 = 44 gm/m3/2H; Inhalation, mouse: LC50 = 44000 mg/m3/2H.
Carcinogenicity:
Germanium Tetrachloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
cfr. MSDS UM
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE LIQUID, N.O.S.*
Hazard Class: 8
UN Number: 1760
Packing Group: II
IMO
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing Group: II
RID/ADR
Shipping Name: CORROSIVE LIQUID, N.O.S.
Hazard Class: 8
UN Number: 1760
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 14 Reacts violently with water.
R 34 Causes burns.
Safety Phrases:
S 8 Keep container dry.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10038-98-9: No information available.
Canada
CAS# 10038-98-9 is listed on Canada's DSL List.
CAS# 10038-98-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 10038-98-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/18/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
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Vinyl Acetate
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Dichlorophenylphosphine, 97%
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5-Nitro-2-N-(Propylamino)Pyridine
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Ethyl cellulose, Ethoxyl Content 48%, 4 CPS
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Crotyl alcohol, 90% (gc)
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Lead(ii) methanethiolate, 99% (titr.)
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3-exo-Hydroxymethylbicyclo[2.2.1]heptyl-2-exo-amine hydrochloride,
| |
|
4,4'-Sulfonyldiphenol, 99.7% (HPLC)
| 80-09-1 |
|
(Diphenylthiocarbazono)phenylmercury
| 56724-82-4 |
|
3-Iodotoluene, 99%
| 625-95-6 |
|
1(2-Methoxyphenyl)piperazine hydrochloride, 99%(tlc)
| 5464-78-8 |
|
3,3-Dimethyl-1-Butene, 95%
| 558-37-2 |
|
Benzyltriethylammonium chloride, 98%
| 56-37-1 |
|
1-Cyclohexene-1-carboxylic acid, 96% (GC)
| 636-82-8 |
|
4-Bromo-2-Fluorobenzonitrile, 99+%
| 105942-08-3 |
|
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| 506-30-9 |
|
2,3-Dichlorotoluene, 98%
| 32768-54-0 |
|
3-Methoxy-1-butanol, 99%
| 2517-43-3 |
|
Germanium Tetrachloride, 99.99%
| 10038-98-9 |
|
2-Naphthaldehyde, 98%
| 66-99-9 |
|
1-Pentanesulfonic acid sodium salt premixed concentrate (Low UV)
| 67-56-1 |
|
Cis-1,2-Cyclohexanedimethanol, 98%
| 15753-50-1 |
|
Tetrabutylammonium Bromide,99% (titr.)
| 1643-19-2 |
|
N,N'-Bis(Phenylmethylene)-1,2-Ethylenediamine, 99.5+%
| 0-01-1 |
|
Wood's Metal
| 7439-92-1 |
|
N,N-Diethyldodecanamide, 98+%
| 3352-87-2 |
|
Thiocarbanilide, 98%
| 102-08-9 |
|
2-Hydroxy-5-nitropyridine, 99+%
| 5418-51-9 |
|
Xylenes, mixed isomers with ethylbenzene (Flash Point 26.1C / 79F;
| 100-41-4 |
|
Xylenol Orange Tetrasodium Salt
| 3618-43-7 |
|
Nile Red, 99% (UV-VIS)
| 7385-67-3 |
|
1-Aminoindan, 99%
| 34698-41-4 |
|
4-Fluorobenzyl Alcohol, 98%
| 459-56-3 |
|
Brilliant Sulphaflavine
| 2391-30-2 |
|
4,4'-Diaminostilbene-2,2'-Disulfonic Acid, 95% (UV-Vis)
| 81-11-8 |
|
n-Methylacetoacetamide, 70 wt % aqueous solution
| 7732-18-5 |
|
Zinc Metal Powder
| 7440-66-6 |
|
cis-1,2-Cyclohexanedicarboxylic anhydride, 99%
| 13149-00-3 |
|
5-Methoxy-2-Methylbenzothiazole
| 2941-69-7 |
|
Zinc acetate dihydrate
| 557-34-6 |
|
Methyl Yellow, indicator grade
| 60-11-7 |
|
Aristolochic acid, mixture of I and II (approx. 1:1)
| 313-67-7 |
|
Ethyl 5-bromo-2-chlorobenzoate, 97%
| 76008-73-6 |
|
Butyl stearate, mixture of ca. 55-65% stearyl- and 25-40% cetyl-
| 111-06-8 |
|
Zinc bromide
| 7699-45-8 |
|
Zinc Carbonate
| 3486-35-9 |
|
(r)-(-)-2-Amino-3-methyl-1-butanol
| 4276-09-9 |
|
Alpha-Fluorocinnamic Acid, 98%
| 350-90-3 |
|
Zinc chloride
| 7646-85-7 |
|
(Iodomethyl)trimethylsilane, 99%
| 4206-67-1 |
|
|