**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7439-92-1 |Lead | 25.0% | 231-100-4 |
|----------------|--------------------------------------|----------|-----------|
| 7440-31-5 |Tin | 13.0% | 231-141-8 |
|----------------|--------------------------------------|----------|-----------|
| 7440-43-9 |Cadmium | 12.0% | 231-152-8 |
|----------------|--------------------------------------|----------|-----------|
| 7440-69-9 |Bismuth | 50.0% | 231-177-4 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Dust may cause mechanical irritation.
Skin:
Dust may cause mechanical irritation. May be absorbed through the
skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause liver and kidney damage.
May cause perforation of the digestive tract. May cause vascular
collapse and damage.
Inhalation:
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count.
Chronic:
May cause reproductive and fetal effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid. Gently lift eyelids and flush continuously with
water.
Skin:
Get medical aid if irritation develops or persists. Flush skin with
plenty of soap and water.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid prolonged or
repeated contact with skin. Avoid contact with eyes. Do not ingest
or inhale.
Storage:
Store in a cool, dry place. Keep away from strong acids.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
See 29CFR 1910.1027 for regulations applying to all occupational
exposures to cadmium and cadmium compounds, in all forms.
Exposure Limits
CAS# 7439-92-1:
United Kingdom, WEL - TWA: 0.15 mg/m3 TWA
United Kingdom, WEL - STEL: 0.45 mg/m3 TWA
United States OSHA: ; 50 ??g/m3 PEL (as Pb); 30 ??g/m3 Action Level
Pb. Poison - see 29 CFR 1910.10 25)
Belgium - TWA: (listed as lead, inorganic compounds): 0.15 mg/m3
(dust and fume)
France - VME: 0.1 mg/m3 VME
Germany: 0.1 mg/m3 TWA (inhalable fraction)
Japan: 0.1 mg/m3 OEL
Malaysia: 0.05 mg/m3 TWA
Netherlands: 0.15 mg/m3 MAC
Russia: 0.01 mg/m3 TWA
Russia: 0.005 mg/m3 STEL
Spain: 0.15 mg/m3 VLA-ED
CAS# 7440-31-5:
United States OSHA: 2 mg/m3 TWA
Belgium - TWA: 2 mg/m3 VLE
Germany: 2 mg/m3 TWA (inhalable fraction)
Malaysia: 2 mg/m3 TWA
Netherlands: 2 mg/m3 MAC
Spain: 2 mg/m3 VLA-ED
CAS# 7440-43-9:
United Kingdom, WEL - TWA: 0.025 mg/m3 TWA
United Kingdom, WEL - STEL: 0.075 mg/m3 STEL
United States OSHA: 0.2 mg/m3 TWA (dust); 0.1 mg/m3 TWA (fume); 0
mg/m3 Ceiling (dust); 0.3 mg/m3 Ceiling (fume); 2.5 ??g/m3 Action
Level; 5 ??g/m3 TWA (Do not eat, drink or chew tobacco or gum or
apply cosmetics in regulated areas. Carcinogen - dust can cause l
and kidn
Belgium - TWA: 0.002 mg/m3 VLE (respirable particulates); 0.01 mg
VLE (inhalable particulate
France - VME: 0.05 mg/m3 VME
Germany: 0.03 mg/m3 TWA (dusts/aerosols, inhalable fraction, batt
production - thermal
Japan: 0.05 mg/m3 OEL
Malaysia: 0.01 mg/m3 TWA; 0.002 mg/m3 TWA (respirable fraction)
Netherlands: (listed as chromium compounds): 0.01 mg/m3 STEL
Netherlands: 0.005 mg/m3 MAC
Russia: 0.05 mg/m3 TWA
Russia: 0.01 mg/m3 STEL
Spain: 0.01 mg/m3 VLA-ED (inhalable fraction); 0.002 mg/m3 VLA-ED
(respirable fraction)
CAS# 7440-69-9:
Russia: 0.5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 185 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Insoluble in water
Specific Gravity/Density: 9.4
Molecular Formula: Mixture
Molecular Weight: Not available
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Acids.
Incompatibilities with Other Materials:
Contact with acids may yield flammable and explosive gas. May be
compatible with strong oxidizing agents.
Hazardous Decomposition Products:
Tin/tin oxides, lead/lead oxides, bismuth oxide, toxic chromium oxide
fumes.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7439-92-1: OF7525000
CAS# 7440-31-5: XP7320000
CAS# 7440-43-9: EU9800000
CAS# 7440-69-9: EB2600000
LD50/LC50:
Not available.
Not available.
CAS# 7440-43-9: Inhalation, rat: LC50 = 25 mg/m3/30M; Oral, mouse:
LD50 = 890 mg/kg; Oral, rat: LD50 = 2330 mg/kg.
CAS# 7440-69-9: Oral, mouse: LD50 = 10 gm/kg; Oral, rat: LD50 = 5000
mg/kg.
Carcinogenicity:
Lead -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
California: carcinogen, initial date 10/1/92
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Tin -
Not listed by ACGIH, IARC, or NTP.
Cadmium -
ACGIH: A2 - Suspected Human Carcinogen (listed as Cadmium compoun
California: carcinogen, initial date 10/1/87
NTP: Known carcinogen
IARC: Group 1 carcinogen
Bismuth -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7439-92-1: 10 lb final RQ (no reporting of releases of this hazardo
USA RQ: CAS# 7440-43-9: 10 lb final RQ (no reporting of releases of this hazardo
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7439-92-1: No information available.
CAS# 7440-31-5: No information available.
CAS# 7440-43-9: No information available.
CAS# 7440-69-9: No information available.
Canada
CAS# 7439-92-1 is listed on Canada's DSL List.
CAS# 7440-31-5 is listed on Canada's DSL List.
CAS# 7440-43-9 is listed on Canada's DSL List.
CAS# 7440-69-9 is listed on Canada's DSL List.
CAS# 7439-92-1 is listed on Canada's Ingredient Disclosure List.
CAS# 7440-31-5 is listed on Canada's Ingredient Disclosure List.
CAS# 7440-43-9 is listed on Canada's Ingredient Disclosure List.
CAS# 7440-69-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7439-92-1 is listed on the TSCA inventory.
CAS# 7440-31-5 is listed on the TSCA inventory.
CAS# 7440-43-9 is listed on the TSCA inventory.
CAS# 7440-69-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 61 May cause harm to the unborn child.
R 62 Possible risk of impaired fertility.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
MSDS Creation Date: 12/12/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Vinyl Acetate
| 108-05-4 |
|
Dichlorophenylphosphine, 97%
| 644-97-3 |
|
5-Nitro-2-N-(Propylamino)Pyridine
| 25948-11-2 |
|
Ethyl cellulose, Ethoxyl Content 48%, 4 CPS
| 9004-57-3 |
|
Crotyl alcohol, 90% (gc)
| 6117-91-5 |
|
Lead(ii) methanethiolate, 99% (titr.)
| 35029-96-0 |
|
3-exo-Hydroxymethylbicyclo[2.2.1]heptyl-2-exo-amine hydrochloride,
| |
|
4,4'-Sulfonyldiphenol, 99.7% (HPLC)
| 80-09-1 |
|
(Diphenylthiocarbazono)phenylmercury
| 56724-82-4 |
|
3-Iodotoluene, 99%
| 625-95-6 |
|
1(2-Methoxyphenyl)piperazine hydrochloride, 99%(tlc)
| 5464-78-8 |
|
3,3-Dimethyl-1-Butene, 95%
| 558-37-2 |
|
Benzyltriethylammonium chloride, 98%
| 56-37-1 |
|
1-Cyclohexene-1-carboxylic acid, 96% (GC)
| 636-82-8 |
|
4-Bromo-2-Fluorobenzonitrile, 99+%
| 105942-08-3 |
|
Eicosanoic acid, 99%
| 506-30-9 |
|
2,3-Dichlorotoluene, 98%
| 32768-54-0 |
|
3-Methoxy-1-butanol, 99%
| 2517-43-3 |
|
Germanium Tetrachloride, 99.99%
| 10038-98-9 |
|
2-Naphthaldehyde, 98%
| 66-99-9 |
|
1-Pentanesulfonic acid sodium salt premixed concentrate (Low UV)
| 67-56-1 |
|
Cis-1,2-Cyclohexanedimethanol, 98%
| 15753-50-1 |
|
Tetrabutylammonium Bromide,99% (titr.)
| 1643-19-2 |
|
N,N'-Bis(Phenylmethylene)-1,2-Ethylenediamine, 99.5+%
| 0-01-1 |
|
Wood's Metal
| 7439-92-1 |
|
N,N-Diethyldodecanamide, 98+%
| 3352-87-2 |
|
Thiocarbanilide, 98%
| 102-08-9 |
|
2-Hydroxy-5-nitropyridine, 99+%
| 5418-51-9 |
|
Xylenes, mixed isomers with ethylbenzene (Flash Point 26.1C / 79F;
| 100-41-4 |
|
Xylenol Orange Tetrasodium Salt
| 3618-43-7 |
|
Nile Red, 99% (UV-VIS)
| 7385-67-3 |
|
1-Aminoindan, 99%
| 34698-41-4 |
|
4-Fluorobenzyl Alcohol, 98%
| 459-56-3 |
|
Brilliant Sulphaflavine
| 2391-30-2 |
|
4,4'-Diaminostilbene-2,2'-Disulfonic Acid, 95% (UV-Vis)
| 81-11-8 |
|
n-Methylacetoacetamide, 70 wt % aqueous solution
| 7732-18-5 |
|
Zinc Metal Powder
| 7440-66-6 |
|
cis-1,2-Cyclohexanedicarboxylic anhydride, 99%
| 13149-00-3 |
|
5-Methoxy-2-Methylbenzothiazole
| 2941-69-7 |
|
Zinc acetate dihydrate
| 557-34-6 |
|
Methyl Yellow, indicator grade
| 60-11-7 |
|
Aristolochic acid, mixture of I and II (approx. 1:1)
| 313-67-7 |
|
Ethyl 5-bromo-2-chlorobenzoate, 97%
| 76008-73-6 |
|
Butyl stearate, mixture of ca. 55-65% stearyl- and 25-40% cetyl-
| 111-06-8 |
|
Zinc bromide
| 7699-45-8 |
|
Zinc Carbonate
| 3486-35-9 |
|
(r)-(-)-2-Amino-3-methyl-1-butanol
| 4276-09-9 |
|
Alpha-Fluorocinnamic Acid, 98%
| 350-90-3 |
|
Zinc chloride
| 7646-85-7 |
|
(Iodomethyl)trimethylsilane, 99%
| 4206-67-1 |
|
|