**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7699-45-8 |Zinc bromide | 100 | 231-718-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs
moisture from the air).
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May cause severe skin irritation with possible burns, especially if
skin is wet or moist.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause severe irritation of the upper respiratory tract with
pain, burns, and inflammation.
Chronic:
Prolonged exposure may cause mental changes such as hallucinations,
depression, psychosis, and possibly coma.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Treat
symptomatically and supportively. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7699-45-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: off-white
Odor: odorless
pH: ~4
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 650 deg C
Freezing/Melting Point: 394 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 697 deg C
Solubility in water: Soluble in water.
Specific Gravity/Density: 4.201
Molecular Formula: ZnBr2
Molecular Weight: 225.188
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, moisture, excess heat.
Incompatibilities with Other Materials:
Explosive when mixed with sodium and potassium.
Hazardous Decomposition Products:
Hydrogen bromide, toxic fumes of zinc oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7699-45-8: ZH1150000
LD50/LC50:
Not available.
Carcinogenicity:
Zinc bromide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 7699-45-8: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 7/8 Keep container tightly closed and dry.
S 28 After contact with skin, wash immediately
with...
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7699-45-8: No information available.
Canada
CAS# 7699-45-8 is listed on Canada's DSL List.
CAS# 7699-45-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7699-45-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/12/1998 Revision #3 Date: 11/19/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Vinyl Acetate
| 108-05-4 |
|
Dichlorophenylphosphine, 97%
| 644-97-3 |
|
5-Nitro-2-N-(Propylamino)Pyridine
| 25948-11-2 |
|
Ethyl cellulose, Ethoxyl Content 48%, 4 CPS
| 9004-57-3 |
|
Crotyl alcohol, 90% (gc)
| 6117-91-5 |
|
Lead(ii) methanethiolate, 99% (titr.)
| 35029-96-0 |
|
3-exo-Hydroxymethylbicyclo[2.2.1]heptyl-2-exo-amine hydrochloride,
| |
|
4,4'-Sulfonyldiphenol, 99.7% (HPLC)
| 80-09-1 |
|
(Diphenylthiocarbazono)phenylmercury
| 56724-82-4 |
|
3-Iodotoluene, 99%
| 625-95-6 |
|
1(2-Methoxyphenyl)piperazine hydrochloride, 99%(tlc)
| 5464-78-8 |
|
3,3-Dimethyl-1-Butene, 95%
| 558-37-2 |
|
Benzyltriethylammonium chloride, 98%
| 56-37-1 |
|
1-Cyclohexene-1-carboxylic acid, 96% (GC)
| 636-82-8 |
|
4-Bromo-2-Fluorobenzonitrile, 99+%
| 105942-08-3 |
|
Eicosanoic acid, 99%
| 506-30-9 |
|
2,3-Dichlorotoluene, 98%
| 32768-54-0 |
|
3-Methoxy-1-butanol, 99%
| 2517-43-3 |
|
Germanium Tetrachloride, 99.99%
| 10038-98-9 |
|
2-Naphthaldehyde, 98%
| 66-99-9 |
|
1-Pentanesulfonic acid sodium salt premixed concentrate (Low UV)
| 67-56-1 |
|
Cis-1,2-Cyclohexanedimethanol, 98%
| 15753-50-1 |
|
Tetrabutylammonium Bromide,99% (titr.)
| 1643-19-2 |
|
N,N'-Bis(Phenylmethylene)-1,2-Ethylenediamine, 99.5+%
| 0-01-1 |
|
Wood's Metal
| 7439-92-1 |
|
N,N-Diethyldodecanamide, 98+%
| 3352-87-2 |
|
Thiocarbanilide, 98%
| 102-08-9 |
|
2-Hydroxy-5-nitropyridine, 99+%
| 5418-51-9 |
|
Xylenes, mixed isomers with ethylbenzene (Flash Point 26.1C / 79F;
| 100-41-4 |
|
Xylenol Orange Tetrasodium Salt
| 3618-43-7 |
|
Nile Red, 99% (UV-VIS)
| 7385-67-3 |
|
1-Aminoindan, 99%
| 34698-41-4 |
|
4-Fluorobenzyl Alcohol, 98%
| 459-56-3 |
|
Brilliant Sulphaflavine
| 2391-30-2 |
|
4,4'-Diaminostilbene-2,2'-Disulfonic Acid, 95% (UV-Vis)
| 81-11-8 |
|
n-Methylacetoacetamide, 70 wt % aqueous solution
| 7732-18-5 |
|
Zinc Metal Powder
| 7440-66-6 |
|
cis-1,2-Cyclohexanedicarboxylic anhydride, 99%
| 13149-00-3 |
|
5-Methoxy-2-Methylbenzothiazole
| 2941-69-7 |
|
Zinc acetate dihydrate
| 557-34-6 |
|
Methyl Yellow, indicator grade
| 60-11-7 |
|
Aristolochic acid, mixture of I and II (approx. 1:1)
| 313-67-7 |
|
Ethyl 5-bromo-2-chlorobenzoate, 97%
| 76008-73-6 |
|
Butyl stearate, mixture of ca. 55-65% stearyl- and 25-40% cetyl-
| 111-06-8 |
|
Zinc bromide
| 7699-45-8 |
|
Zinc Carbonate
| 3486-35-9 |
|
(r)-(-)-2-Amino-3-methyl-1-butanol
| 4276-09-9 |
|
Alpha-Fluorocinnamic Acid, 98%
| 350-90-3 |
|
Zinc chloride
| 7646-85-7 |
|
(Iodomethyl)trimethylsilane, 99%
| 4206-67-1 |
|
|