**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7646-85-7 |Zinc chloride | >97 | 231-592-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C N
Risk Phrases: 22 34 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Causes burns. Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic environment.
Potential Health Effects
Eye:
May cause irreversible eye injury. Contact with eyes may cause
severe irritation, and possible eye burns.
Skin:
Causes skin burns. Not expected to cause an allergic skin reaction.
Ingestion:
Harmful if swallowed. May cause corrosion and permanent tissue
destruction of the esophagus and digestive tract.
Inhalation:
May cause cyanosis (bluish discoloration of skin due to deficient
oxygenation of the blood). Irritation may lead to chemical
pneumonitis and pulmonary edema. Inhalation of fumes may cause metal
fume fever, which is characterized by flu-like symptoms with
metallic taste, fever, chills, cough, weakness, chest pain, muscle
pain and increased white blood cell count. Causes respiratory tract
irritation with possible burns.
Chronic:
Chronic exposure may cause effects similar to those of acute
exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Substance is
noncombustible. Contact with metals may evolve flammable hydrogen
gas.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not get in eyes, on skin, or on
clothing. Discard contaminated shoes. Do not breathe dust or fumes.
Storage:
Store in a cool, dry place. Corrosives area. Do not store in metal
containers. Keep containers tightly closed. Store protected from
moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 7646-85-7:
United Kingdom, WEL - TWA: 1 mg/m3 TWA (fume)
United Kingdom, WEL - STEL: 2 mg/m3 STEL (fume)
United States OSHA: 1 mg/m3 TWA (fume)
Belgium - TWA: 1 mg/m3 VLE (fumes)
Belgium - STEL: 2 mg/m3 VLE (fumes)
France - VME: 1 mg/m3 VME (fume)
Malaysia: 1 mg/m3 TWA (fume)
Netherlands: 1 mg/m3 MAC (smoke)
Spain: 1 mg/m3 VLA-ED (fume)
Spain: 2 mg/m3 VLA-EC (fume)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: odorless
pH: 4 (100 g/l)
Vapor Pressure: Negligible
Viscosity: Not applicable.
Boiling Point: 732 deg C
Freezing/Melting Point: 293 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Soluble in water.
Specific Gravity/Density: 2.91
Molecular Formula: ZnCl2
Molecular Weight: 136.29
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Deliquescent
(tending to absorb atmospheric water vapor and become liquid).
Conditions to Avoid:
Moisture, excess heat.
Incompatibilities with Other Materials:
Strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, toxic fumes of zinc oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7646-85-7: ZH1400000
LD50/LC50:
CAS# 7646-85-7: Oral, mouse: LD50 = 329 mg/kg; Oral, rat: LD50 = 350
mg/kg.
Carcinogenicity:
Zinc chloride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ZINC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 2331
Packing Group: III
IMO
Shipping Name: ZINC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 2331
Packing Group: III
RID/ADR
Shipping Name: ZINC CHLORIDE, ANHYDROUS
Hazard Class: 8
UN Number: 2331
Packing group: III
USA RQ: CAS# 7646-85-7: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C N
Risk Phrases:
R 22 Harmful if swallowed.
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7646-85-7: 1
Canada
CAS# 7646-85-7 is listed on Canada's DSL List.
CAS# 7646-85-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7646-85-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/19/1998 Revision #6 Date: 1/14/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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3-exo-Hydroxymethylbicyclo[2.2.1]heptyl-2-exo-amine hydrochloride,
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4,4'-Sulfonyldiphenol, 99.7% (HPLC)
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4-Bromo-2-Fluorobenzonitrile, 99+%
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| 506-30-9 |
|
2,3-Dichlorotoluene, 98%
| 32768-54-0 |
|
3-Methoxy-1-butanol, 99%
| 2517-43-3 |
|
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| 10038-98-9 |
|
2-Naphthaldehyde, 98%
| 66-99-9 |
|
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| 67-56-1 |
|
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| 15753-50-1 |
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| 1643-19-2 |
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|
Wood's Metal
| 7439-92-1 |
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| 3352-87-2 |
|
Thiocarbanilide, 98%
| 102-08-9 |
|
2-Hydroxy-5-nitropyridine, 99+%
| 5418-51-9 |
|
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| 100-41-4 |
|
Xylenol Orange Tetrasodium Salt
| 3618-43-7 |
|
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| 7385-67-3 |
|
1-Aminoindan, 99%
| 34698-41-4 |
|
4-Fluorobenzyl Alcohol, 98%
| 459-56-3 |
|
Brilliant Sulphaflavine
| 2391-30-2 |
|
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| 81-11-8 |
|
n-Methylacetoacetamide, 70 wt % aqueous solution
| 7732-18-5 |
|
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| 7440-66-6 |
|
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| 13149-00-3 |
|
5-Methoxy-2-Methylbenzothiazole
| 2941-69-7 |
|
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| 557-34-6 |
|
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| 60-11-7 |
|
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| 313-67-7 |
|
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| 76008-73-6 |
|
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| 111-06-8 |
|
Zinc bromide
| 7699-45-8 |
|
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|
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| 350-90-3 |
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| 7646-85-7 |
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|