**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 103-72-0 |Phenyl isothiocyanate | >97 | 203-138-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Vapors cause eye irritation. Lachrymator (substance which
increases the flow of tears). Liquid will cause burns.
Skin:
Causes severe skin irritation. Harmful if absorbed through the skin.
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Repeated exposure may cause sensitization dermatitis. Chronic
exposure may cause effects similar to those of acute exposure.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid and
vapor. Vapors are heavier than air and may travel to a source of
ignition and flash back. Vapors can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation. Evacuate unnecessary personnel. Approach spill
from upwind.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Do not get in eyes,
on skin, or on clothing. Keep container tightly closed. Avoid
ingestion and inhalation. Do not breathe vapor. Keep away from heat
and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 103-72-0:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear slightly yellow
Odor: mustard-like - penetrating odor
pH: Not available.
Vapor Pressure: 0.17 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 221 deg C @ 760 mm Hg
Freezing/Melting Point: -21 deg C
Autoignition Temperature: Not available.
Flash Point: 87 deg C ( 188.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: >260 deg C
Solubility in water: insoluble
Specific Gravity/Density: 1.1300 g/cm3
Molecular Formula: C7H5NS
Molecular Weight: 135.19
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 103-72-0: NX9275000
LD50/LC50:
CAS# 103-72-0: Oral, mouse: LD50 = 87 mg/kg.
Carcinogenicity:
Phenyl isothiocyanate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 103-72-0: 2
Canada
CAS# 103-72-0 is listed on Canada's DSL List.
CAS# 103-72-0 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 103-72-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/08/1997 Revision #3 Date: 10/10/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Manganese(IV) Oxide, 99+%, -100 Mesh
| 1313-13-9 |
|
Manganese (II) Sulfate Monohydrate, P. A.
| 10034-96-5 |
|
D-(+)-Mannitol, 98%
| 69-65-8 |
|
D-Mannitol, Reagent ACS
| 69-65-8 |
|
Mercuric acetate, 98%
| 1600-27-7 |
|
Mercury(II) chloride, p.a.
| 7487-94-7 |
|
Mercury (II) Nitrate Monohydrate, P.A.
| 7783-34-8 |
|
Mercury (II) Oxide, Red, 99%
| 21908-53-2 |
|
Mercury (II) Oxide, Yellow
| 21908-53-2 |
|
Mercury (II) Sulfate, 99+%
| 7783-35-9 |
|
Furan, stabilized with 0.025 to 0.04% BHT, 98%
| 110-00-9 |
|
Dimethyl maleate, 96%
| 624-48-6 |
|
Furan
| 110-00-9 |
|
Mercury, 99.999%
| 7439-97-6 |
|
4,4'- Methylenebis-(n,n-dimethylaniline) 99+% (titr.)
| 101-61-1 |
|
2-Methoxyethanol, spectrophotometric grade, 99+%
| 109-86-4 |
|
Methyl cellulose (viscosity: ca 15 cP(2% solution in water))
| 9004-67-5 |
|
5-Amino-1H-Tetrazole Monohydrate, 99%
| 4418-61-5 |
|
Rhenium Heptasulfide, 99%
| 12038-67-4 |
|
4-Methyl-2-Pentanone, 99.5%
| 108-10-1 |
|
Glutaric acid, 99%
| 110-94-1 |
|
4-Methyl-2-Pentanone, P.A.
| 108-10-1 |
|
4-Methyl-2-pentanone
| 108-10-1 |
|
Methyl methacrylate, 99%, stabilized with 10 - 20 ppm MEHQ
| 80-62-6 |
|
1-Ethylpiperidine, 99%
| 766-09-6 |
|
Methyl P-Hydroxybenzoate, 99%
| 99-76-3 |
|
Hydrazine hydrate, 80% (Hydrazine, 51%)
| 302-01-2 |
|
Methyl Red, indicator, p.a.
| 493-52-7 |
|
Methyl Salicylate, 98%
| 119-36-8 |
|
Dichloromethane, stabilized with amylene
| 75-09-2 |
|
Dichloromethane, 99.8%, Spectr. Grade, Stab. With 50 ppm Amylene
| 75-09-2 |
|
Dichloromethane for HPLC, Stabilized With 50 ppm Amylene
| 75-09-2 |
|
Dichloromethane, >99% (GC)
| 75-09-2 |
|
Dichloromethane, Reagent ACS, 99.5% (GC)
| 75-09-2 |
|
Dichloromethane, Reagent ACS, Spectro Grade, 99.5% (GC)
| 75-09-2 |
|
Aniline-2-sulfonic acid, tech., 83%
| 88-21-1 |
|
Ninhydrin, spectrophotometric grade
| 485-47-2 |
|
Cineole, 99%
| 470-82-6 |
|
Phenyl isothiocyanate
| 103-72-0 |
|
Sodium phosphate, monobasic, monohydrate, p.a.
| 7558-80-7 |
|
Morpholine, 99+%
| 110-91-8 |
|
N-Amyl Acetate, 98%
| 628-63-7 |
|
Tetrabutylammonium Phosphate, HPLC Grade, 99% (Titr.)
| 5574-97-0 |
|
n-Butyl acetate, 99+%
| 123-86-4 |
|
4'-Hydroxy-2'-methylacetophenone, 97%
| 875-59-2 |
|
1-Butanol, 99%
| 71-36-3 |
|
1-Bromobutane, 99%
| 109-65-9 |
|
1-Chlorobutane, 99+%
| 109-69-3 |
|
Normal-Butylamine, 99.5% (GC)
| 109-73-9 |
|
3,5-Diiodo-l-tyrosine,dihydrate, 99%
| 300-39-0 |
|
|