**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-65-9 |BUTYL BROMIDE | >99% | 203-691-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to respiratory system.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Flammable Liquid. Can release vapors that form explosive
mixtures at temperatures above the flashpoint.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wear a self contained breathing apparatus and appropriate personal
protection. (See Exposure Controls, Personal Protection section).
Scoop up with a nonsparking tool, then place into a suitable
container for disposal. Remove all sources of ignition. Absorb spill
using an absorbent, non-combustible material such as earth, sand, or
vermiculite. Do not use combustible materials such as sawdust.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with skin and eyes. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Avoid ingestion and inhalation. Do not ingest or inhale.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear very light yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: 40 mm Hg @ 25 C
Viscosity: Not available.
Boiling Point: 100.0 - 104.0 deg C @ 760.00mm Hg
Freezing/Melting Point: - 112.00 - - 0.00 deg
Autoignition Temperature: 265 deg C ( 509.00 deg F)
Flash Point: 13 deg C ( 55.40 deg F)
Explosion Limits, lower: 2.60 vol %
Explosion Limits, upper: 6.60 vol %
Decomposition Temperature:
Solubility in water: 0.608 G/L WATER (30C)
Specific Gravity/Density: 1.2760g/cm3
Molecular Formula: C4H9Br
Molecular Weight: 137.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, magnesium, sodium, potassium.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-65-9: EJ6225000
LD50/LC50:
CAS# 109-65-9: Inhalation, mouse: LC50 = 25000 mg/m3/2H; Inhalation,
rat: LC50 = 47000 mg/m3/2H; Oral, rat: LD50 = 2761 mg/kg.
Carcinogenicity:
BUTYL BROMIDE -
Not listed by ACGIH, IARC, or NTP.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: 1-BROMOBUTANE
Hazard Class: 3
UN Number: 1126
Packing Group: II
IMO
Shipping Name: 1-BROMOBUTANE
Hazard Class: 3.2
UN Number: 1126
Packing Group: II
RID/ADR
Shipping Name: 1-BROMOBUTANE
Hazard Class: 3
UN Number: 1126
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 37 Irritating to respiratory system.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 109-65-9: 2
United Kingdom Occupational Exposure Limits
United Kingdom Maximum Exposure Limits
Canada
CAS# 109-65-9 is listed on Canada's DSL List.
CAS# 109-65-9 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 109-65-9: OEL-RUSSIA:STEL 0.3 mg/m3;Skin
US FEDERAL
TSCA
CAS# 109-65-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Manganese(IV) Oxide, 99+%, -100 Mesh
| 1313-13-9 |
|
Manganese (II) Sulfate Monohydrate, P. A.
| 10034-96-5 |
|
D-(+)-Mannitol, 98%
| 69-65-8 |
|
D-Mannitol, Reagent ACS
| 69-65-8 |
|
Mercuric acetate, 98%
| 1600-27-7 |
|
Mercury(II) chloride, p.a.
| 7487-94-7 |
|
Mercury (II) Nitrate Monohydrate, P.A.
| 7783-34-8 |
|
Mercury (II) Oxide, Red, 99%
| 21908-53-2 |
|
Mercury (II) Oxide, Yellow
| 21908-53-2 |
|
Mercury (II) Sulfate, 99+%
| 7783-35-9 |
|
Furan, stabilized with 0.025 to 0.04% BHT, 98%
| 110-00-9 |
|
Dimethyl maleate, 96%
| 624-48-6 |
|
Furan
| 110-00-9 |
|
Mercury, 99.999%
| 7439-97-6 |
|
4,4'- Methylenebis-(n,n-dimethylaniline) 99+% (titr.)
| 101-61-1 |
|
2-Methoxyethanol, spectrophotometric grade, 99+%
| 109-86-4 |
|
Methyl cellulose (viscosity: ca 15 cP(2% solution in water))
| 9004-67-5 |
|
5-Amino-1H-Tetrazole Monohydrate, 99%
| 4418-61-5 |
|
Rhenium Heptasulfide, 99%
| 12038-67-4 |
|
4-Methyl-2-Pentanone, 99.5%
| 108-10-1 |
|
Glutaric acid, 99%
| 110-94-1 |
|
4-Methyl-2-Pentanone, P.A.
| 108-10-1 |
|
4-Methyl-2-pentanone
| 108-10-1 |
|
Methyl methacrylate, 99%, stabilized with 10 - 20 ppm MEHQ
| 80-62-6 |
|
1-Ethylpiperidine, 99%
| 766-09-6 |
|
Methyl P-Hydroxybenzoate, 99%
| 99-76-3 |
|
Hydrazine hydrate, 80% (Hydrazine, 51%)
| 302-01-2 |
|
Methyl Red, indicator, p.a.
| 493-52-7 |
|
Methyl Salicylate, 98%
| 119-36-8 |
|
Dichloromethane, stabilized with amylene
| 75-09-2 |
|
Dichloromethane, 99.8%, Spectr. Grade, Stab. With 50 ppm Amylene
| 75-09-2 |
|
Dichloromethane for HPLC, Stabilized With 50 ppm Amylene
| 75-09-2 |
|
Dichloromethane, >99% (GC)
| 75-09-2 |
|
Dichloromethane, Reagent ACS, 99.5% (GC)
| 75-09-2 |
|
Dichloromethane, Reagent ACS, Spectro Grade, 99.5% (GC)
| 75-09-2 |
|
Aniline-2-sulfonic acid, tech., 83%
| 88-21-1 |
|
Ninhydrin, spectrophotometric grade
| 485-47-2 |
|
Cineole, 99%
| 470-82-6 |
|
Phenyl isothiocyanate
| 103-72-0 |
|
Sodium phosphate, monobasic, monohydrate, p.a.
| 7558-80-7 |
|
Morpholine, 99+%
| 110-91-8 |
|
N-Amyl Acetate, 98%
| 628-63-7 |
|
Tetrabutylammonium Phosphate, HPLC Grade, 99% (Titr.)
| 5574-97-0 |
|
n-Butyl acetate, 99+%
| 123-86-4 |
|
4'-Hydroxy-2'-methylacetophenone, 97%
| 875-59-2 |
|
1-Butanol, 99%
| 71-36-3 |
|
1-Bromobutane, 99%
| 109-65-9 |
|
1-Chlorobutane, 99+%
| 109-69-3 |
|
Normal-Butylamine, 99.5% (GC)
| 109-73-9 |
|
3,5-Diiodo-l-tyrosine,dihydrate, 99%
| 300-39-0 |
|
|