**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-10-1 |Methyl isobutyl ketone | >98.5 | 203-550-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN F
Risk Phrases: 11 36/37 20 66
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes and respiratory system. Harmful
by inhalation. Repeated exposure may cause skin dryness or cracking.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain. Vapors
cause eye irritation.
Skin:
Prolonged and/or repeated contact may cause irritation and/or
dermatitis. A single prolonged skin exposure is not likely to result
in the material being absorbed in harmful amounts.
Ingestion:
May cause effects similar to those for inhalation exposure.
Aspiration of material into the lungs may cause chemical
pneumonitis, which may be fatal.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation. Exposure produces
central nervous system depression. May cause liver abnormalities.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. This material has caused kidney effects in male rats
which are not considered relevant to humans.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors are
heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas.
Extinguishing Media:
Water may be ineffective. In case of fire, use carbon dioxide, dry
chemical powder or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Use only with adequate
ventilation. Keep away from heat, sparks and flame. Avoid breathing
vapor or mist.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Containers should be dated when opened and tested
periodically for the presence of peroxides. Should crystals form in a
peroxidizable liquid, peroxidation may have occurred and the product
should be considered extremely dangerous. In this instance, the
container should only be opened remotely by professionals. All
peroxidizable substances should be stored away from heat and light
and be protected from ignition sources.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 108-10-1:
United Kingdom, WEL - TWA: 50 ppm TWA; 208 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 416 mg/m3 STEL
United States OSHA: 100 ppm TWA; 410 mg/m3 TWA
Belgium - TWA: 20 ppm VLE; 83 mg/m3 VLE
Belgium - STEL: 50 ppm VLE; 208 mg/m3 VLE
France - VME: 50 ppm VME; 205 mg/m3 VME
Germany: 20 ppm TWA; 83 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 200 mg/m3 OEL
Malaysia: 50 ppm TWA; 205 mg/m3 TWA
Netherlands: 50 ppm STEL; 208 mg/m3 STEL
Netherlands: 25 ppm MAC; 104 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 20 ppm VLA-ED; 83 mg/m3 VLA-ED
Spain: 50 ppm VLA-EC; 208 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: Sweet, camphor-like.
pH: Not available.
Vapor Pressure: 19.9 mm Hg @ 25 deg C
Viscosity: 0.61 cps @ 20 deg C
Boiling Point: 117 deg C @ 760 mm Hg
Freezing/Melting Point: -84 deg C
Autoignition Temperature: 448 deg C ( 838.40 deg F)
Flash Point: 14 deg C ( 57.20 deg F)
Explosion Limits, lower: 1.2% @ 93C
Explosion Limits, upper: 8.0% @ 93C
Decomposition Temperature:
Solubility in water: Moderately Soluble.
Specific Gravity/Density: 0.80 g/cm3
Molecular Formula: C6H12O
Molecular Weight: 100.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form
and accumulate peroxides which may explode when subjected to heat or
shock. This material is most hazardous when peroxide levels are
concentrated by distillation or evaporation.
Conditions to Avoid:
Ignition sources, excess heat, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-10-1: SA9275000
LD50/LC50:
CAS# 108-10-1: Draize test, rabbit, eye: 40 mg Severe; Draize test,
rabbit, eye: 100 uL/24H Moderate; Draize test, rabbit, skin: 500
mg/24H Mild; Inhalation, mouse: LC50 = 23300 mg/m3; Inhalation,
mouse: LC50 = 23300 mg/m3; Inhalation, rat: LC50 = 100 gm/m3; Oral,
mouse: LD50 = 1900 mg/kg; Oral, mouse: LD50 = 2850 mg/kg; Oral, rat:
LD50 = 2080 mg/kg; Oral, rat: LD50 = 4600 mg/kg.
Carcinogenicity:
Methyl isobutyl ketone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Fathead Minnow: LC50 = 505 mg/L; 96 Hr.; Flow through; 25
degrees C, pH 7.5Fish: Goldfish: LC50 = 460 mg/L; 24 Hr.;
UnspecifiedWater flea Daphnia: EC50 = 4280.0 mg/L; 24 Hr.;
UnspecifiedAlgae: EC50 = 400 mg/L; 96 Hr.; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 79.6 mg/L; 5 minutes; Microtox
test
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: METHYL ISOBUTYL KETONE
Hazard Class: 3
UN Number: 1245
Packing Group: II
IMO
Shipping Name: METHYL ISOBUTYL KETONE
Hazard Class: 3.2
UN Number: 1245
Packing Group: II
RID/ADR
Shipping Name: METHYL ISOBUTYL KETONE
Hazard Class: 3
UN Number: 1245
Packing group: II
USA RQ: CAS# 108-10-1: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20 Harmful by inhalation.
R 36/37 Irritating to eyes and respiratory system.
R 66 Repeated exposure may cause skin dryness or
cracking.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
WGK (Water Danger/Protection)
CAS# 108-10-1: 1
Canada
CAS# 108-10-1 is listed on Canada's DSL List.
CAS# 108-10-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-10-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 5/19/1999 Revision #5 Date: 7/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Manganese(IV) Oxide, 99+%, -100 Mesh
| 1313-13-9 |
|
Manganese (II) Sulfate Monohydrate, P. A.
| 10034-96-5 |
|
D-(+)-Mannitol, 98%
| 69-65-8 |
|
D-Mannitol, Reagent ACS
| 69-65-8 |
|
Mercuric acetate, 98%
| 1600-27-7 |
|
Mercury(II) chloride, p.a.
| 7487-94-7 |
|
Mercury (II) Nitrate Monohydrate, P.A.
| 7783-34-8 |
|
Mercury (II) Oxide, Red, 99%
| 21908-53-2 |
|
Mercury (II) Oxide, Yellow
| 21908-53-2 |
|
Mercury (II) Sulfate, 99+%
| 7783-35-9 |
|
Furan, stabilized with 0.025 to 0.04% BHT, 98%
| 110-00-9 |
|
Dimethyl maleate, 96%
| 624-48-6 |
|
Furan
| 110-00-9 |
|
Mercury, 99.999%
| 7439-97-6 |
|
4,4'- Methylenebis-(n,n-dimethylaniline) 99+% (titr.)
| 101-61-1 |
|
2-Methoxyethanol, spectrophotometric grade, 99+%
| 109-86-4 |
|
Methyl cellulose (viscosity: ca 15 cP(2% solution in water))
| 9004-67-5 |
|
5-Amino-1H-Tetrazole Monohydrate, 99%
| 4418-61-5 |
|
Rhenium Heptasulfide, 99%
| 12038-67-4 |
|
4-Methyl-2-Pentanone, 99.5%
| 108-10-1 |
|
Glutaric acid, 99%
| 110-94-1 |
|
4-Methyl-2-Pentanone, P.A.
| 108-10-1 |
|
4-Methyl-2-pentanone
| 108-10-1 |
|
Methyl methacrylate, 99%, stabilized with 10 - 20 ppm MEHQ
| 80-62-6 |
|
1-Ethylpiperidine, 99%
| 766-09-6 |
|
Methyl P-Hydroxybenzoate, 99%
| 99-76-3 |
|
Hydrazine hydrate, 80% (Hydrazine, 51%)
| 302-01-2 |
|
Methyl Red, indicator, p.a.
| 493-52-7 |
|
Methyl Salicylate, 98%
| 119-36-8 |
|
Dichloromethane, stabilized with amylene
| 75-09-2 |
|
Dichloromethane, 99.8%, Spectr. Grade, Stab. With 50 ppm Amylene
| 75-09-2 |
|
Dichloromethane for HPLC, Stabilized With 50 ppm Amylene
| 75-09-2 |
|
Dichloromethane, >99% (GC)
| 75-09-2 |
|
Dichloromethane, Reagent ACS, 99.5% (GC)
| 75-09-2 |
|
Dichloromethane, Reagent ACS, Spectro Grade, 99.5% (GC)
| 75-09-2 |
|
Aniline-2-sulfonic acid, tech., 83%
| 88-21-1 |
|
Ninhydrin, spectrophotometric grade
| 485-47-2 |
|
Cineole, 99%
| 470-82-6 |
|
Phenyl isothiocyanate
| 103-72-0 |
|
Sodium phosphate, monobasic, monohydrate, p.a.
| 7558-80-7 |
|
Morpholine, 99+%
| 110-91-8 |
|
N-Amyl Acetate, 98%
| 628-63-7 |
|
Tetrabutylammonium Phosphate, HPLC Grade, 99% (Titr.)
| 5574-97-0 |
|
n-Butyl acetate, 99+%
| 123-86-4 |
|
4'-Hydroxy-2'-methylacetophenone, 97%
| 875-59-2 |
|
1-Butanol, 99%
| 71-36-3 |
|
1-Bromobutane, 99%
| 109-65-9 |
|
1-Chlorobutane, 99+%
| 109-69-3 |
|
Normal-Butylamine, 99.5% (GC)
| 109-73-9 |
|
3,5-Diiodo-l-tyrosine,dihydrate, 99%
| 300-39-0 |
|
|