**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 10326-27-9 |Barium chloride dihydrate | > 99 | unlisted |
|----------------|--------------------------------------|----------|-----------|
| 10361-37-2 |Barium chloride anhydrous | - | 233-788-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Harmful by inhalation.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain. May cause
conjunctivitis.
Skin:
Causes skin irritation. Prolonged contact with the skin, especially
if the skin is wet or moist, causes necrosis.
Ingestion:
Harmful if swallowed. May cause kidney damage. May cause severe
digestive tract irritation with abdominal pain, nausea, vomiting and
diarrhea. May cause hemorrhaging of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing,
give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Substance is noncombustible; use agent most
appropriate to extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Minimize dust generation and accumulation.
Avoid contact with skin and eyes. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Keep away from sources of ignition.
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR
1910.134 or European Standard EN 149. Always use a
NIOSH or European Standard EN 149 approved respirator
when necessary.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: white
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 2840 deg F
Freezing/Melting Point: 1760 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: 59% @ 100C
Specific Gravity/Density: 3.86 (water=1)
Molecular Formula: BaCl2
Molecular Weight: 208.236
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
Ignition sources, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Incompatible with bromine trifluoride and 2-furan percarboxylic acid
(explodes at room temperature). Reacts violently with sulfuric acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 10326-27-9: CQ8751000
CAS# 10361-37-2: CQ8750000
LD50/LC50:
Not available.
CAS# 10361-37-2: Oral, rat: LD50 = 118 mg/kg.
Carcinogenicity:
Barium chloride dihydrate -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
Barium chloride anhydrous -
ACGIH: A4 - Not Classifiable as a Human Carcinogen (listed as **
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
IMO
Shipping Name: BARIUM COMPOUND, N.O.S.
Hazard Class: 6.1
UN Number: 1564
Packing Group: III
RID/ADR
Shipping Name: BARIUM COMPOUND, N.O.S.
Dangerous Goods Code: 6.1(60C)
UN Number: 1564
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 20 Harmful by inhalation.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 10326-27-9: 1
CAS# 10361-37-2: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 10361-37-2 is listed on Canada's DSL List.
CAS# 10326-27-9 is not listed on Canada's Ingredient Disclosure List.
CAS# 10361-37-2 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10326-27-9: OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3
OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3
OEL-BELGIUM:TWA 0.5 mg(Ba)/m3
OEL-DENMARK:TWA 0.5 mg(Ba)/m3
OEL-FINLAND:TWA 0.5 mg(Ba)/m3
OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust)
OEL-HUNGARY:STEL 0.5 mg(Ba)/m3
OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3
OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m
OEL-TURKEY:TWA 0.5 mg(Ba)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
CAS# 10361-37-2: OEL-AUSTRALIA:TWA 0.5 mg(Ba)/m3
OEL-AUSTRIA:TWA 0.5 mg(Ba)/m3
OEL-BELGIUM:TWA 0.5 mg(Ba)/m3
OEL-DENMARK:TWA 0.5 mg(Ba)/m3
OEL-FINLAND:TWA 0.5 mg(Ba)/m3
OEL-GERMANY:TWA 0.5 mg(Ba)/m3 (total dust)
OEL-HUNGARY:STEL 0.5 mg(Ba)/m3
OEL-THE NETHERLANDS:TWA 0.5 mg(Ba)/m3
OEL-THE PHILIPPINES:TWA 0.5 mg(Ba)/m3
OEL-POLAND:TWA 0.5 mg(Ba)/m3;STEL 1.5 mg(Ba)/m3
OEL-RUSSIA:STEL 0.3 mg/m3
OEL-SWITZERLAND:TWA 0.5 mg(Ba)/m3;STEL 1 mg(Ba)/m
OEL-TURKEY:TWA 0.5 mg(Ba)/m3
OEL-UNITED KINGDOM:TWA 0.5 mg(Ba)/m3
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 10326-27-9 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).
CAS# 10361-37-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/17/1998 Revision #5 Date: 10/12/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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25,27-Dimethoxy-26-(N-tosyl)carbamoyloxy-p-tert-butylcalix[4]arene,
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MOPSO, Biograde
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PIPES 1.5 Na Salt, Biograde
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|
TES, biograde
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|
1,1,2,2-Tetrabromoethane
| 79-27-6 |
|
Barium hydroxide octahydrate, reagent ACS, 98+%
| 12230-71-6 |
|
Vinylbenzyl Alcohol, Mixture of Isomers
| 7732-18-5 |
|
Triethyl orthopropionate,98+%
| 115-80-0 |
|
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| 672-65-1 |
|
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| 7727-43-7 |
|
Ammonium Persulfate, DNase, RNase and Protease Free
| 7727-54-0 |
|
Benzaldehyde
| 100-52-7 |
|
Phenol, Stabilized, DNase, RNase and Protease free
| 108-95-2 |
|
Acetylsalicylic Acid 99%
| 50-78-2 |
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Boric Acid
| 10043-35-3 |
|
N,N-Dimethylformamide, DNase, RNase, Protease free
| 68-12-2 |
|
Methyl sulfoxide, DNase, RNase, Protease free
| 67-68-5 |
|
DL-Dithiothreitol, DNase, RNase, Protease Free
| 27565-41-9 |
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| 65-85-0 |
|
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| 119-61-9 |
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| 56602-33-6 |
|
Benzoyl peroxide, 75%, remainder water
| 94-36-0 |
|
Methylcyclohexane, 99%
| 108-87-2 |
|
(1S)-1-(2-Chlorophenyl)Ethane-1,2-Diol, 95%
| 0-01-1 |
|
m-Toluoyl chloride, 99%
| 1711-06-4 |
|
(-)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97%
| 0-01-1 |
|
Bismuth(III) oxide
| 1304-76-3 |
|
(S)-(-)-2-(tert-Butoxycarbonylamino)3-phenyl-1-propanol, 98%
| 66605-57-0 |
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| 75-12-7 |
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| 8012-89-3 |
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