**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 65-85-0 |Benzoic acid | >99.5 | 200-618-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed.
Potential Health Effects
Eye:
Causes severe eye irritation and possible injury. Inhalation of
dust may cause tearing.
Skin:
Causes moderate skin irritation. May cause allergic contact
dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May be harmful if swallowed.
Inhalation:
Inhalation of dust may cause irritation of the nose and throat.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. During a fire, irritating and
highly toxic gases may be generated by thermal decomposition or
combustion. This material in sufficient quantity and reduced particle
size is capable of creating a dust explosion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Avoid generating dusty conditions. Provide
ventilation. Cover with soda ash or sodium bicarbonate and place in a
closed container for disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Wash clothing before reuse. Avoid breathing
dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR ??1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Appearance: white
Odor: pleasant odor
pH: 2.8 (sat soln)
Vapor Pressure: 1 mm Hg @ 96 deg C
Viscosity: Not available.
Boiling Point: 249 deg C
Freezing/Melting Point: 122-123 deg C
Autoignition Temperature: 571 deg C ( 1,059.80 deg F)
Flash Point: 121 deg C ( 249.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Slightly soluble.
Specific Gravity/Density: 1.3210g/cm3
Molecular Formula: C7H6O2
Molecular Weight: 122.12
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Volatile in steam.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases, amines, ammonia, isocyanates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 65-85-0: DG0875000
LD50/LC50:
CAS# 65-85-0: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Mild; Inhalation, rat: LC50 = >26 mg/m3/1H;
Oral, mouse: LD50 = 1940 mg/kg; Oral, rat: LD50 = 1700 mg/kg; Skin,
rabbit: LD50 = >10 gm/kg.
Carcinogenicity:
Benzoic acid -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Mosquito Fish: LC50 = 180 mg/L; 96 Hr; UnspecifiedBacteria:
Phytobacterium phosphoreum: EC50 = 16.9 mg/L; 96 Hr; Microtox test @
15CIf released on land, benzoic acid should leach into the ground
due to its low soil adsorption and biodegrade (half-life <1 wk). If
released in water, benzoic acid should also readily biodegrade
(half-life 0.2-3.6 days). Adsorption to sediment and volatilization
should not be significant.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 65-85-0: 1
United Kingdom Occupational Exposure Limits
Canada
CAS# 65-85-0 is listed on Canada's DSL List.
CAS# 65-85-0 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 65-85-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/23/1999 Revision #5 Date: 9/28/2001
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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25,27-Dimethoxy-26-(N-tosyl)carbamoyloxy-p-tert-butylcalix[4]arene,
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Poly-D-leucine
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MOPSO, Biograde
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PIPES 1.5 Na Salt, Biograde
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4-(Methylthio)benzaldehyde, 98%
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TES, biograde
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1,1,2,2-Tetrabromoethane
| 79-27-6 |
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Barium hydroxide octahydrate, reagent ACS, 98+%
| 12230-71-6 |
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Vinylbenzyl Alcohol, Mixture of Isomers
| 7732-18-5 |
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Triethyl orthopropionate,98+%
| 115-80-0 |
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1-Chloro-1-Phenylethane, 97%
| 672-65-1 |
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Fluorescein isothiocyanate I hydrochloride, 99%, certified
| 0-01-1 |
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Barium sulfate, extra pure
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Ammonium Persulfate, DNase, RNase and Protease Free
| 7727-54-0 |
|
Benzaldehyde
| 100-52-7 |
|
Phenol, Stabilized, DNase, RNase and Protease free
| 108-95-2 |
|
Acetylsalicylic Acid 99%
| 50-78-2 |
|
Boric Acid
| 10043-35-3 |
|
N,N-Dimethylformamide, DNase, RNase, Protease free
| 68-12-2 |
|
Methyl sulfoxide, DNase, RNase, Protease free
| 67-68-5 |
|
DL-Dithiothreitol, DNase, RNase, Protease Free
| 27565-41-9 |
|
Benzoic acid, p.a.
| 65-85-0 |
|
Benzophenone, 99+%
| 119-61-9 |
|
Benzotriazol-1-yloxytris(dimethylamino) phosphonium
| 56602-33-6 |
|
Benzoyl peroxide, 75%, remainder water
| 94-36-0 |
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Methylcyclohexane, 99%
| 108-87-2 |
|
(1S)-1-(2-Chlorophenyl)Ethane-1,2-Diol, 95%
| 0-01-1 |
|
m-Toluoyl chloride, 99%
| 1711-06-4 |
|
(-)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97%
| 0-01-1 |
|
Bismuth(III) oxide
| 1304-76-3 |
|
(S)-(-)-2-(tert-Butoxycarbonylamino)3-phenyl-1-propanol, 98%
| 66605-57-0 |
|
Formamide, DNase, RNase and Protease free
| 75-12-7 |
|
Beeswax, White
| 8012-89-3 |
|
Tin(IV) chloride pentahydrate, 98+%
| 7646-78-8 |
|
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| 7240-90-6 |
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Bromocresol Purple, Indicator Grade
| 115-40-2 |
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| 56-81-5 |
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| 10127-02-3 |
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