**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | < 4 | 231-791-2 |
|----------------|--------------------------------------|----------|-----------|
| 100037-69-2 |Piperazine-N,N'-bis(2-Ethanesulfonic A| > 96 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed.The toxicological properties of this material
have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. No sensitizing effects known.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
The toxicological properties of this substance have not been fully
investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust,
vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7732-18-5:
CAS# 100037-69-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: white
Odor: Not available.
pH: 6.5 - 7.1 @1% aq sol
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: > 300 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density:
Molecular Formula: C16H33N4Na3O12S4
Molecular Weight: 335.30
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7732-18-5: ZC0110000
CAS# 100037-69-2 unlisted.
LD50/LC50:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
CAS# 100037-69-2.
Carcinogenicity:
Water -
Not listed by ACGIH, IARC, or NTP.
Piperazine-N,N'-bis(2-Ethanesulfonic Acid) Sesquisodium Salt -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: Daphnia: >1000 mg/L; 24 Hrs; EC50Fish: Zebrafish: >1000
mg/L; 96 Hrs; LC100
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 100037-69-2: No information available.
Canada
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 100037-69-2 is listed on Canada's DSL List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 100037-69-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 100037-69-2 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 2/02/1999 Revision #4 Date: 6/06/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Acetyl acetone
| 123-54-6 |
|
25,27-Dimethoxy-26-(N-tosyl)carbamoyloxy-p-tert-butylcalix[4]arene,
| 325776-14-5 |
|
25,27-Dimethoxy-26-(N-benzoyl)carbamoyloxy-p-tert-butylcalix[4]arene,
| 325776-15-6 |
|
Poly-D-leucine
| 0-01-1 |
|
AMPSO, BioGRADE
| 68399-79-1 |
|
BIS TRIS, BioGRADE
| 6976-37-0 |
|
CAPSO, BioGRADE
| 73463-39-5 |
|
DIPSO, Biograde
| 68399-80-4 |
|
Barium chloride dihydrate, reagent ACS, crystals
| 10326-27-9 |
|
MOPSO, Biograde
| 68399-77-9 |
|
Barium Diphenylaminesulfonate, Indicator Grade
| 6211-24-1 |
|
PIPES 1.5 Na Salt, Biograde
| 7732-18-5 |
|
4-(Methylthio)benzaldehyde, 98%
| 3446-89-7 |
|
Digitonin
| 11024-24-1 |
|
POPSO, BioGRADE
| 68189-43-5 |
|
TAPSO, iograde
| 68399-81-5 |
|
(R)-(-)-Glycidyl nosylate, 98%
| 115314-17-5 |
|
TES, biograde
| 7365-44-8 |
|
1,1,2,2-Tetrabromoethane
| 79-27-6 |
|
Barium hydroxide octahydrate, reagent ACS, 98+%
| 12230-71-6 |
|
Vinylbenzyl Alcohol, Mixture of Isomers
| 7732-18-5 |
|
Triethyl orthopropionate,98+%
| 115-80-0 |
|
1-Chloro-1-Phenylethane, 97%
| 672-65-1 |
|
Fluorescein isothiocyanate I hydrochloride, 99%, certified
| 0-01-1 |
|
Barium sulfate, extra pure
| 7727-43-7 |
|
Ammonium Persulfate, DNase, RNase and Protease Free
| 7727-54-0 |
|
Benzaldehyde
| 100-52-7 |
|
Phenol, Stabilized, DNase, RNase and Protease free
| 108-95-2 |
|
Acetylsalicylic Acid 99%
| 50-78-2 |
|
Boric Acid
| 10043-35-3 |
|
N,N-Dimethylformamide, DNase, RNase, Protease free
| 68-12-2 |
|
Methyl sulfoxide, DNase, RNase, Protease free
| 67-68-5 |
|
DL-Dithiothreitol, DNase, RNase, Protease Free
| 27565-41-9 |
|
Benzoic acid, p.a.
| 65-85-0 |
|
Benzophenone, 99+%
| 119-61-9 |
|
Benzotriazol-1-yloxytris(dimethylamino) phosphonium
| 56602-33-6 |
|
Benzoyl peroxide, 75%, remainder water
| 94-36-0 |
|
Methylcyclohexane, 99%
| 108-87-2 |
|
(1S)-1-(2-Chlorophenyl)Ethane-1,2-Diol, 95%
| 0-01-1 |
|
m-Toluoyl chloride, 99%
| 1711-06-4 |
|
(-)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97%
| 0-01-1 |
|
Bismuth(III) oxide
| 1304-76-3 |
|
(S)-(-)-2-(tert-Butoxycarbonylamino)3-phenyl-1-propanol, 98%
| 66605-57-0 |
|
Formamide, DNase, RNase and Protease free
| 75-12-7 |
|
Beeswax, White
| 8012-89-3 |
|
Tin(IV) chloride pentahydrate, 98+%
| 7646-78-8 |
|
5-Bromo-4-Chloro-3-Indolyl-??-D-Galactoside, DNase, RNase and Protease
| 7240-90-6 |
|
Bromocresol Purple, Indicator Grade
| 115-40-2 |
|
Glycerol, DNase RNase and Protease free
| 56-81-5 |
|
Acridine Orange Hemizinc Salt
| 10127-02-3 |
|
|