**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 56-81-5 |Glycerol | ca. 100 | 200-289-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Low hazard for usual industrial handling.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Low hazard for usual industrial handling. May cause headache.
Inhalation:
Low hazard for usual industrial handling. Inhalation of a mist of
this material may cause respiratory tract irritation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls
of milk or water. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Vapors may be heavier
than air. They can spread along the ground and collect in low or
confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Use water spray, dry chemical,
carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation. Wash
clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. No special
precautions indicated. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 56-81-5:
United Kingdom, WEL - TWA: 10 mg/m3 TWA (mist)
United Kingdom, WEL - STEL: 30 mg/m3 STEL (mist)
United States OSHA: 15 mg/m3 TWA (total dust); 5 mg/m3 TWA
(respirable fraction)
Belgium - TWA: 10 mg/m3 VLE (mist)
France - VME: 10 mg/m3 VME
Malaysia: 10 mg/m3 TWA (mist)
Netherlands: 10 mg/m3 MAC (mist)
Spain: 10 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless - APHA: 5 max
Odor: odorless
pH: Not available.
Vapor Pressure: .003 mbar @ 50 deg
Viscosity: 1069 mPas 20 deg C
Boiling Point: 290 deg C @ 760.00m
Freezing/Melting Point: 18 deg C
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: .90 vol %
Explosion Limits, upper: .00 vol %
Decomposition Temperature: >290 deg C
Solubility in water: >500 G/L WATER (20C)
Specific Gravity/Density: 1.2610g/cm3
Molecular Formula: HOCH2CH(OH)CH2OH
Molecular Weight: 92.09
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. Able to polymerize above 149C/300.2F.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Moisture. Strong oxidizing agents, lead oxide, nitric acid, sulfuric
acid, hydrogen peroxides, potassium permanganate, calcium
hypochlorite, perchloric acid.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 56-81-5: MA8050000
LD50/LC50:
CAS# 56-81-5: Draize test, rabbit, eye: 126 mg Mild; Draize test,
rabbit, eye: 500 mg/24H Mild; Draize test, rabbit, skin: 500 mg/24H
Mild; Inhalation, rat: LC50 = >570 mg/m3/1H; Oral, mouse: LD50 =
4090 mg/kg; Oral, rabbit: LD50 = 27 gm/kg; Oral, rat: LD50 = 12600
mg/kg; Skin, rabbit: LD50 = >10 gm/kg.
Carcinogenicity:
Glycerol -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Cas# 56-81-5:
LC50 (96 Hr.) rainbow trout = 50-67 mg/L; 12 degrees
C
LC50 (96 Hr.) goldfish = >5000 mg/L
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 56-81-5: 0
Canada
CAS# 56-81-5 is listed on Canada's DSL List.
CAS# 56-81-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 56-81-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/11/1999 Revision #5 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Acetyl acetone
| 123-54-6 |
|
25,27-Dimethoxy-26-(N-tosyl)carbamoyloxy-p-tert-butylcalix[4]arene,
| 325776-14-5 |
|
25,27-Dimethoxy-26-(N-benzoyl)carbamoyloxy-p-tert-butylcalix[4]arene,
| 325776-15-6 |
|
Poly-D-leucine
| 0-01-1 |
|
AMPSO, BioGRADE
| 68399-79-1 |
|
BIS TRIS, BioGRADE
| 6976-37-0 |
|
CAPSO, BioGRADE
| 73463-39-5 |
|
DIPSO, Biograde
| 68399-80-4 |
|
Barium chloride dihydrate, reagent ACS, crystals
| 10326-27-9 |
|
MOPSO, Biograde
| 68399-77-9 |
|
Barium Diphenylaminesulfonate, Indicator Grade
| 6211-24-1 |
|
PIPES 1.5 Na Salt, Biograde
| 7732-18-5 |
|
4-(Methylthio)benzaldehyde, 98%
| 3446-89-7 |
|
Digitonin
| 11024-24-1 |
|
POPSO, BioGRADE
| 68189-43-5 |
|
TAPSO, iograde
| 68399-81-5 |
|
(R)-(-)-Glycidyl nosylate, 98%
| 115314-17-5 |
|
TES, biograde
| 7365-44-8 |
|
1,1,2,2-Tetrabromoethane
| 79-27-6 |
|
Barium hydroxide octahydrate, reagent ACS, 98+%
| 12230-71-6 |
|
Vinylbenzyl Alcohol, Mixture of Isomers
| 7732-18-5 |
|
Triethyl orthopropionate,98+%
| 115-80-0 |
|
1-Chloro-1-Phenylethane, 97%
| 672-65-1 |
|
Fluorescein isothiocyanate I hydrochloride, 99%, certified
| 0-01-1 |
|
Barium sulfate, extra pure
| 7727-43-7 |
|
Ammonium Persulfate, DNase, RNase and Protease Free
| 7727-54-0 |
|
Benzaldehyde
| 100-52-7 |
|
Phenol, Stabilized, DNase, RNase and Protease free
| 108-95-2 |
|
Acetylsalicylic Acid 99%
| 50-78-2 |
|
Boric Acid
| 10043-35-3 |
|
N,N-Dimethylformamide, DNase, RNase, Protease free
| 68-12-2 |
|
Methyl sulfoxide, DNase, RNase, Protease free
| 67-68-5 |
|
DL-Dithiothreitol, DNase, RNase, Protease Free
| 27565-41-9 |
|
Benzoic acid, p.a.
| 65-85-0 |
|
Benzophenone, 99+%
| 119-61-9 |
|
Benzotriazol-1-yloxytris(dimethylamino) phosphonium
| 56602-33-6 |
|
Benzoyl peroxide, 75%, remainder water
| 94-36-0 |
|
Methylcyclohexane, 99%
| 108-87-2 |
|
(1S)-1-(2-Chlorophenyl)Ethane-1,2-Diol, 95%
| 0-01-1 |
|
m-Toluoyl chloride, 99%
| 1711-06-4 |
|
(-)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97%
| 0-01-1 |
|
Bismuth(III) oxide
| 1304-76-3 |
|
(S)-(-)-2-(tert-Butoxycarbonylamino)3-phenyl-1-propanol, 98%
| 66605-57-0 |
|
Formamide, DNase, RNase and Protease free
| 75-12-7 |
|
Beeswax, White
| 8012-89-3 |
|
Tin(IV) chloride pentahydrate, 98+%
| 7646-78-8 |
|
5-Bromo-4-Chloro-3-Indolyl-??-D-Galactoside, DNase, RNase and Protease
| 7240-90-6 |
|
Bromocresol Purple, Indicator Grade
| 115-40-2 |
|
Glycerol, DNase RNase and Protease free
| 56-81-5 |
|
Acridine Orange Hemizinc Salt
| 10127-02-3 |
|
|