**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 12230-71-6 |Barium hydroxide octahydrate | >98 | unlisted |
|----------------|--------------------------------------|----------|-----------|
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN C
Risk Phrases: 20/22 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns. Contact produces irritation, tearing, and
burning pain.
Skin:
Causes skin burns.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal tract burns. May cause respiratory failure. May
cause kidney failure. May cause convulsions, increased blood
pressure, muscle spasms, and possible paralysis.
Inhalation:
May cause severe irritation of the upper respiratory tract with
pain, burns, and inflammation. Causes chemical burns to the
respiratory tract.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give
anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of d-Penicillamine as a chelating agent should be determined
by qualified medical personnel.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Decomposes at high temperatures, resulting in toxic
and corrosive products.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Minimize dust generation
and accumulation. Do not get in eyes, on skin, or on clothing. Do not
breathe dust. Use only with adequate ventilation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from strong acids. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 12230-71-6:
United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE
Malaysia: (listed as barium): 0.5 mg/m3 TWA
Netherlands: (listed as barium): 0.5 mg/m3 MAC
Spain: (listed as barium): 0.5 mg/m3 VLA-ED
CAS# 17194-00-2:
United States OSHA: 0.5 mg/m3 TWA (listed under Barium).
Belgium - TWA: (listed as barium): 0.5 mg/m3 VLE
Malaysia: (listed as barium): 0.5 mg/m3 TWA
Netherlands: (listed as barium): 0.5 mg/m3 MAC
Russia: 0.1 mg/m3 TWA
Spain: (listed as barium): 0.5 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: transparent
Odor: odorless
pH: Alkaline.
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: 780 deg C
Freezing/Melting Point: 78 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Moderately in water (5.6 g/100 ml)
Specific Gravity/Density: 2.18
Molecular Formula: Ba(OH)2.8H2O
Molecular Weight: 315.45
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Metals, strong oxidizing agents, acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, barium oxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 12230-71-6 unlisted.
CAS# 17194-00-2: CQ9200000
LD50/LC50:
Not available.
CAS# 17194-00-2: Oral, rat: LD50 = 308 mg/kg.
Carcinogenicity:
Barium hydroxide octahydrate -
Not listed by ACGIH, IARC, or NTP.
Barium hydroxide anhydrous -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CORROSIVE SOLID, TOXIC, N.O.S.
Hazard Class: 8
UN Number: 2923
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, TOXIC, N.O.S.
Hazard Class: 8
UN Number: 2923
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 2923
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN C
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 12230-71-6: 1
CAS# 17194-00-2: 1
Canada
CAS# 17194-00-2 is listed on Canada's DSL List.
CAS# 12230-71-6 is not listed on Canada's Ingredient Disclosure List.
CAS# 17194-00-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12230-71-6 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 17194-00-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 9/14/1998 Revision #4 Date: 11/22/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Acetyl acetone
| 123-54-6 |
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25,27-Dimethoxy-26-(N-tosyl)carbamoyloxy-p-tert-butylcalix[4]arene,
| 325776-14-5 |
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25,27-Dimethoxy-26-(N-benzoyl)carbamoyloxy-p-tert-butylcalix[4]arene,
| 325776-15-6 |
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Poly-D-leucine
| 0-01-1 |
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AMPSO, BioGRADE
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BIS TRIS, BioGRADE
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DIPSO, Biograde
| 68399-80-4 |
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Barium chloride dihydrate, reagent ACS, crystals
| 10326-27-9 |
|
MOPSO, Biograde
| 68399-77-9 |
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Barium Diphenylaminesulfonate, Indicator Grade
| 6211-24-1 |
|
PIPES 1.5 Na Salt, Biograde
| 7732-18-5 |
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4-(Methylthio)benzaldehyde, 98%
| 3446-89-7 |
|
Digitonin
| 11024-24-1 |
|
POPSO, BioGRADE
| 68189-43-5 |
|
TAPSO, iograde
| 68399-81-5 |
|
(R)-(-)-Glycidyl nosylate, 98%
| 115314-17-5 |
|
TES, biograde
| 7365-44-8 |
|
1,1,2,2-Tetrabromoethane
| 79-27-6 |
|
Barium hydroxide octahydrate, reagent ACS, 98+%
| 12230-71-6 |
|
Vinylbenzyl Alcohol, Mixture of Isomers
| 7732-18-5 |
|
Triethyl orthopropionate,98+%
| 115-80-0 |
|
1-Chloro-1-Phenylethane, 97%
| 672-65-1 |
|
Fluorescein isothiocyanate I hydrochloride, 99%, certified
| 0-01-1 |
|
Barium sulfate, extra pure
| 7727-43-7 |
|
Ammonium Persulfate, DNase, RNase and Protease Free
| 7727-54-0 |
|
Benzaldehyde
| 100-52-7 |
|
Phenol, Stabilized, DNase, RNase and Protease free
| 108-95-2 |
|
Acetylsalicylic Acid 99%
| 50-78-2 |
|
Boric Acid
| 10043-35-3 |
|
N,N-Dimethylformamide, DNase, RNase, Protease free
| 68-12-2 |
|
Methyl sulfoxide, DNase, RNase, Protease free
| 67-68-5 |
|
DL-Dithiothreitol, DNase, RNase, Protease Free
| 27565-41-9 |
|
Benzoic acid, p.a.
| 65-85-0 |
|
Benzophenone, 99+%
| 119-61-9 |
|
Benzotriazol-1-yloxytris(dimethylamino) phosphonium
| 56602-33-6 |
|
Benzoyl peroxide, 75%, remainder water
| 94-36-0 |
|
Methylcyclohexane, 99%
| 108-87-2 |
|
(1S)-1-(2-Chlorophenyl)Ethane-1,2-Diol, 95%
| 0-01-1 |
|
m-Toluoyl chloride, 99%
| 1711-06-4 |
|
(-)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97%
| 0-01-1 |
|
Bismuth(III) oxide
| 1304-76-3 |
|
(S)-(-)-2-(tert-Butoxycarbonylamino)3-phenyl-1-propanol, 98%
| 66605-57-0 |
|
Formamide, DNase, RNase and Protease free
| 75-12-7 |
|
Beeswax, White
| 8012-89-3 |
|
Tin(IV) chloride pentahydrate, 98+%
| 7646-78-8 |
|
5-Bromo-4-Chloro-3-Indolyl-??-D-Galactoside, DNase, RNase and Protease
| 7240-90-6 |
|
Bromocresol Purple, Indicator Grade
| 115-40-2 |
|
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| 56-81-5 |
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| 10127-02-3 |
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|