**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 75-12-7 |Formamide | 100 | 200-842-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 61
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
May cause harm to the unborn child.Hygroscopic (absorbs moisture
from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. Not
expected to cause an allergic skin reaction.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause central nervous system effects.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause respiratory tract irritation.
Chronic:
Prolonged or repeated exposure may cause adverse reproductive
effects. May cause fetal effects. Chronic exposure may cause liver
damage. There is a danger of cumulative effects.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool.
Extinguishing Media:
Use dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Wear a
self contained breathing apparatus and appropriate personal
protection. (See Exposure Controls, Personal Protection section).
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Use only with adequate ventilation. Avoid
breathing vapor or mist. Pregnant workers should keep exposure to a
minimum.
Storage:
Do not store in direct sunlight. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Store protected from moisture. Refrigeration
has been recommended.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 75-12-7:
United Kingdom, WEL - TWA: 20 ppm TWA; 37 mg/m3 TWA
United Kingdom, WEL - STEL: 30 ppm STEL; 56 mg/m3 STEL
Belgium - TWA: 10 ppm VLE; 18 mg/m3 VLE
France - VME: 20 ppm VME; 30 mg/m3 VME
Germany: 18 mg/m3 TWA
Germany: Skin absorber
Malaysia: 10 ppm TWA; 18 mg/m3 TWA
Netherlands: 9 ppm MAC; 16 mg/m3 MAC
Russia: 3 mg/m3 TWA
Spain: 10 ppm VLA-ED; 19 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: ammonia-like - weak odor
pH: 7.1 (0.5M aq soln)
Vapor Pressure: .06 mm Hg @ 25 deg C
Viscosity: Not available.
Boiling Point: 210 deg C
Freezing/Melting Point: 2-3 deg C
Autoignition Temperature: Not available.
Flash Point: 154 deg C ( 309.20 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 180 deg C
Solubility in water: Soluble.
Specific Gravity/Density: 1.13 (water=1)
Molecular Formula: CH3NO
Molecular Weight: 45.04
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Light, moisture, temperatures >180C as formamide will begin to
partially decompose into carbon monoxide and ammonia.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, ammonia, isocyanates, phenols
and cresols, iodine, sulfur trioxide, pyridine.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide,
ammonia.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 75-12-7: LQ0525000
LD50/LC50:
CAS# 75-12-7: Draize test, rabbit, eye: 100 mg Severe; Inhalation,
rat: LC50 = >3900 ppm/6H; Oral, mouse: LD50 = 3150 mg/kg; Oral, rat:
LD50 = 5577 mg/kg; Skin, rabbit: LD50 = 17 gm/kg.
Carcinogenicity:
Formamide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Minnow LC50=>500mg/L/48H
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not Regulated
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: NOT REGULATED
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not Regulated
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 61 May cause harm to the unborn child.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 75-12-7: 1
Canada
CAS# 75-12-7 is listed on Canada's DSL List.
CAS# 75-12-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 75-12-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/26/1999 Revision #9 Date: 7/18/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
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| ALL MSDS PAGES IN THIS GROUP
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25,27-Dimethoxy-26-(N-tosyl)carbamoyloxy-p-tert-butylcalix[4]arene,
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Poly-D-leucine
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MOPSO, Biograde
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PIPES 1.5 Na Salt, Biograde
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4-(Methylthio)benzaldehyde, 98%
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| 115314-17-5 |
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TES, biograde
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1,1,2,2-Tetrabromoethane
| 79-27-6 |
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Barium hydroxide octahydrate, reagent ACS, 98+%
| 12230-71-6 |
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Vinylbenzyl Alcohol, Mixture of Isomers
| 7732-18-5 |
|
Triethyl orthopropionate,98+%
| 115-80-0 |
|
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| 672-65-1 |
|
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| 0-01-1 |
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Barium sulfate, extra pure
| 7727-43-7 |
|
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| 7727-54-0 |
|
Benzaldehyde
| 100-52-7 |
|
Phenol, Stabilized, DNase, RNase and Protease free
| 108-95-2 |
|
Acetylsalicylic Acid 99%
| 50-78-2 |
|
Boric Acid
| 10043-35-3 |
|
N,N-Dimethylformamide, DNase, RNase, Protease free
| 68-12-2 |
|
Methyl sulfoxide, DNase, RNase, Protease free
| 67-68-5 |
|
DL-Dithiothreitol, DNase, RNase, Protease Free
| 27565-41-9 |
|
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| 65-85-0 |
|
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| 119-61-9 |
|
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| 56602-33-6 |
|
Benzoyl peroxide, 75%, remainder water
| 94-36-0 |
|
Methylcyclohexane, 99%
| 108-87-2 |
|
(1S)-1-(2-Chlorophenyl)Ethane-1,2-Diol, 95%
| 0-01-1 |
|
m-Toluoyl chloride, 99%
| 1711-06-4 |
|
(-)-Cis-2-Oxabicyclo(3.3.0)Oct-6-En-3-One, 97%
| 0-01-1 |
|
Bismuth(III) oxide
| 1304-76-3 |
|
(S)-(-)-2-(tert-Butoxycarbonylamino)3-phenyl-1-propanol, 98%
| 66605-57-0 |
|
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| 75-12-7 |
|
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| 8012-89-3 |
|
Tin(IV) chloride pentahydrate, 98+%
| 7646-78-8 |
|
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| 7240-90-6 |
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| 115-40-2 |
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| 56-81-5 |
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| 10127-02-3 |
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