**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 107-14-2 |Chloroacetonitrile | 98+ | 203-467-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.
Potential Health Effects
Eye:
Causes moderate eye irritation. Causes redness and pain.
Lachrymator (substance which increases the flow of tears).
Skin:
Causes mild skin irritation. May be fatal if absorbed through the
skin. Causes redness and pain. Substance is readily absorbed through
the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause headache.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. May
cause drowsiness, unconsciousness, and central nervous system
depression. Vapors may cause dizziness or suffocation. Harmful if
inhaled.
Chronic:
Chronic exposure may cause degenerative lesions of the heart, liver,
and kidneys. Chronic inhalation may cause damage to the respiratory
tract and bronchi which may result in dealth.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Wash mouth out with
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Absorption of this product into the body may cause cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Moderate degrees of cyanosis need to be treated only by supportive
measures: bed rest and oxygen inhalation. If cyanosis is severe,
intravenous injection of Methylene Blue, 1mg/kg of body weight may
be of value.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Do not breathe dust, vapor, mist, or gas.
Do not get in eyes, on skin, or on clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not ingest or inhale. Use only in a chemical fume hood. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 107-14-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless to pale yellow
Odor: Pungent
pH: Not available.
Vapor Pressure: 11.5 mbar @ 20 deg
Viscosity: Not available.
Boiling Point: 124 - 126 deg C @ 760.00mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: 56 deg C ( 132.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble in hydrocarbons, alcohols, chlor
Specific Gravity/Density: 1.1930g/cm3
Molecular Formula: C2H2ClN
Molecular Weight: 75.50
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong reducing agents, strong oxidizing agents, strong bases, strong
acids.
Hazardous Decomposition Products:
Hydrogen chloride, hydrogen cyanide, nitrogen oxides, carbon
monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 107-14-2: AL8225000
LD50/LC50:
CAS# 107-14-2: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 139 mg/kg;
Oral, rat: LD50 = 220 mg/kg; Skin, rabbit: LD50 = 71 uL/kg.
Carcinogenicity:
Chloroacetonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLOROACETONITRILE
Hazard Class: 6.1 (3)
UN Number: 2668
Packing Group: II
IMO
Shipping Name: CHLOROACETONITRILE
Hazard Class: 6.1 (3)
UN Number: 2668
Packing Group: II
RID/ADR
Shipping Name: CHLOROACETONITRILE
Hazard Class: 6.1
UN Number: 2668
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 107-14-2: No information available.
Canada
CAS# 107-14-2 is listed on Canada's NDSL List.
CAS# 107-14-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 107-14-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/24/1999 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cholesteryl Crotylcarbonate
| 62637-94-9 |
|
Chloroacetonitrile, 98+%
| 107-14-2 |
|
3-Quinuclidinone hydrochloride, 99% (tlc)
| 1193-65-3 |
|
2'-me-2',3',10,11-tetrahydrospiro(5h-diben
| 35926-76-2 |
|
l-Leucine methyl ester hydrochloride, 98%
| 7517-19-3 |
|
3-Methylbenzylamine, 98%
| 100-81-2 |
|
3-Amino-4-methylbenzoic acid, 99%
| 2458-12-0 |
|
Methyl 4-Nitrobutyrate, Tech. 80%
| 13013-02-0 |
|
2,3,4-Trimethoxybenzonitrile, 97%
| 43020-38-8 |
|
1-Phenyl-3-(2-Thiazolyl)-2-Thiourea, 97+%
| 14901-16-7 |
|
Hydrogen fluoride, 37 wt% solution in triethylamine
| 73602-61-6 |
|
Ammonium Sodium Phosphate Tetrahydrate 99%
| 0-00-1 |
|
5,6-Benzoquinoline, 99+%
| 85-02-9 |
|
4-Methoxy-2-nitrophenol, 99+%
| 1568-70-3 |
|
4-Hydroxybenzyl Alcohol, 97% (TLC)
| 623-05-2 |
|
1-(2-Fluorophenyl)piperazine, 97%(GC)
| 1011-15-0 |
|
Hexamethyl dewar benzene, 97%
| 7641-77-2 |
|
Triaza-12-Crown-4, 99%
| 0-01-1 |
|
alpha-Angelicalactone, 98%
| 591-12-8 |
|
3-Acetamidocoumarin
| 779-30-6 |
|
4,6-Dihydroxy-2-Methylpyrimidine, 99%
| 40497-30-1 |
|
Purpurogallin, tech.
| 569-77-7 |
|
2,3-Dimethyl-P-Nitroanisole, 98%
| 81029-03-0 |
|
4-Nitro-p-terphenyl
| 10355-53-0 |
|
2,3-Dimethylcyclohexylamine, mixture of isomers, 99+%
| 42195-92-6 |
|
Epibromohydrin, 98%
| 3132-64-7 |
|
Stearic Anhydride
| 638-08-4 |
|
Ethyl Vinyl Ether, 99% (gc)
| 109-92-2 |
|
Fluoresceinamine Isomer I, 99% (UV-Vis)
| 3326-34-9 |
|
2-Methyl-1,3-cyclohexanedione, 98+%
| 1193-55-1 |
|
(2S,3S)-2-Amino-3-Ethoxybutanoic Acid Hydrochloride, 99+%, (80% e.e.)
| 0-01-1 |
|
Thioflavin t
| 2390-54-7 |
|
Methyl dichloroacetate, 99+%
| 116-54-1 |
|
Trimethylsilyl Trifluoromethanesulfonate, 99%
| 27607-77-8 |
|
3,4-Dihydro-2H-Pyran, 99%
| 110-87-2 |
|
2-Nitrophenyl Disulfide, 95%
| 1155-00-6 |
|
Methylenedi-p-phenyl diisocyanate
| 101-68-8 |
|
1-Bromo-2,3-Dichlorobenzene, 99%
| 56961-77-4 |
|
n-Butyric Anhydride, 99%
| 106-31-0 |
|
2,2',4'-Trichloroacetophenone, 95%, containing up to 10% water,
| 4252-78-2 |
|
10-Nonadecanone, 99%
| 504-57-4 |
|
Hydrogen hexachloroiridate(IV) hexahydrate, approx. 40% Iridium
| 16941-92-7 |
|
3-(3,4,5-Trimethoxyphenyl)Propionic Acid, 98+%
| 25173-72-2 |
|
Tetrodotoxin, Citrate Free
| 4368-28-9 |
|
Acid Green 25
| 4403-90-1 |
|
Coumalic Acid, 97+%
| 500-05-0 |
|
7,8-Benzoquinoline, 97%
| 230-27-3 |
|
1,10-Diaminodecane, 97+%
| 646-25-3 |
|
Inositol, 98+% (HPLC)
| 87-89-8 |
|
Thallium (III) Nitrate Trihydrate, 99.5%
| 13453-38-8 |
|
|