**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 109-92-2 |Vinyl ethyl ether | 99 | 203-718-4 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F+
Risk Phrases: 11 2 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Risk of explosion by shock, friction, fire or
other sources of ignition. Irritating to eyes, respiratory system
and skin.Lachrymator (substance which increases the flow of
tears).Air sensitive.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. Prolonged and/or repeated contact may cause
defatting of the skin and dermatitis.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause central nervous system depression, characterized
by excitement, followed by headache, dizziness, drowsiness, and
nausea. Advanced stages may cause collapse, unconsciousness, coma
and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Causes respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Containers may explode in the heat of a
fire. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wash area with soap and water.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Use a spark-proof
tool. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Take precautionary measures against
static discharges. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Use only in a chemical fume hood. If
peroxide formation is suspected, do not open or move container. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Refrigerator/flammables. Regularly check
inhibitor levels to maintain peroxide levels below 1%.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 109-92-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: none reported
pH: Not available.
Vapor Pressure: 428 mm Hg @ 20 deg C
Viscosity: Not available.
Boiling Point: 36 deg C @ 760.00mm Hg
Freezing/Melting Point: -116 deg C
Autoignition Temperature: 180 deg C ( 356.00 deg F)
Flash Point: -50 deg C ( -58.00 deg F)
Explosion Limits, lower: 1.40 vol %
Explosion Limits, upper: 28.00 vol %
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.7540g/cm3
Molecular Formula: C4H8O
Molecular Weight: 72.11
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not stable during routine use and handling conditions. On long term
storage, substances with similar functional groups form explosive
peroxides.
Conditions to Avoid:
Incompatible materials, ignition sources, exposure to air.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, oxygen.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: May occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-92-2: KO0710000
LD50/LC50:
CAS# 109-92-2: Inhalation, mouse: LC50 = 324 gm/m3/15M; Oral, rat:
LD50 = 8160 uL/kg; Skin, rabbit: LD50 = >20 mL/kg; Skin, rat: LD50 =
>20 gm/kg.
Carcinogenicity:
Vinyl ethyl ether -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish toxicity: LC50/Leuciscus idus/: >2200 <4600 mg/l/96h
Daphnia
toxicity: EC/LC50 (48 h):>100 mg/l
Algae toxicity: EC/LC50 (72 h):
510 mg/l
Bacteriatoxicity: EC/LC50 (17 h): >5000 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F+
Risk Phrases:
R 11 Highly flammable.
R 2 Risk of explosion by shock, friction, fire or
other sources of ignition.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 33 Take precautionary measures against static
discharges.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 109-92-2: 1
Canada
CAS# 109-92-2 is listed on Canada's DSL List.
CAS# 109-92-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-92-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 3/10/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
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| 1011-15-0 |
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Hexamethyl dewar benzene, 97%
| 7641-77-2 |
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alpha-Angelicalactone, 98%
| 591-12-8 |
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| 779-30-6 |
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| 40497-30-1 |
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| 569-77-7 |
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2,3-Dimethyl-P-Nitroanisole, 98%
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| 10355-53-0 |
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2,3-Dimethylcyclohexylamine, mixture of isomers, 99+%
| 42195-92-6 |
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Epibromohydrin, 98%
| 3132-64-7 |
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Stearic Anhydride
| 638-08-4 |
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Ethyl Vinyl Ether, 99% (gc)
| 109-92-2 |
|
Fluoresceinamine Isomer I, 99% (UV-Vis)
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| 1193-55-1 |
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| 2390-54-7 |
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Methyl dichloroacetate, 99+%
| 116-54-1 |
|
Trimethylsilyl Trifluoromethanesulfonate, 99%
| 27607-77-8 |
|
3,4-Dihydro-2H-Pyran, 99%
| 110-87-2 |
|
2-Nitrophenyl Disulfide, 95%
| 1155-00-6 |
|
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| 101-68-8 |
|
1-Bromo-2,3-Dichlorobenzene, 99%
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|
n-Butyric Anhydride, 99%
| 106-31-0 |
|
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| 4252-78-2 |
|
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| 504-57-4 |
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