**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 591-12-8 |alpha-Angelicalactone | 98 | 209-701-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and
corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the
extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation. Aspiration may lead to
pulmonary edema. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Vapors may be heavier than air. They can spread along the ground and
collect in low or confined areas. Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use agent most
appropriate to extinguish fire. Do NOT get water inside containers.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not allow contact with water. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Keep from contact with moist air and
steam.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Store
protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 591-12-8:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light yellow to green
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 55.0 - 56.0 deg C @ 12.00mmHg
Freezing/Melting Point: 18 deg C
Autoignition Temperature: Not available.
Flash Point: 68 deg C ( 154.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 5g/100ml (25 c)
Specific Gravity/Density: 1.0920g/cm3
Molecular Formula: C5H6O2
Molecular Weight: 98.10
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, moisture, excess heat,
strong oxidants.
Incompatibilities with Other Materials:
Moisture, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 591-12-8: LU5075000
LD50/LC50:
CAS# 591-12-8: Oral, mouse: LD50 = 2800 mg/kg; Oral, rat: LD50 =
3900 mg/kg.
Carcinogenicity:
alpha-Angelicalactone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 591-12-8: No information available.
Canada
CAS# 591-12-8 is listed on Canada's DSL List.
CAS# 591-12-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 591-12-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #7 Date: 2/02/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cholesteryl Crotylcarbonate
| 62637-94-9 |
|
Chloroacetonitrile, 98+%
| 107-14-2 |
|
3-Quinuclidinone hydrochloride, 99% (tlc)
| 1193-65-3 |
|
2'-me-2',3',10,11-tetrahydrospiro(5h-diben
| 35926-76-2 |
|
l-Leucine methyl ester hydrochloride, 98%
| 7517-19-3 |
|
3-Methylbenzylamine, 98%
| 100-81-2 |
|
3-Amino-4-methylbenzoic acid, 99%
| 2458-12-0 |
|
Methyl 4-Nitrobutyrate, Tech. 80%
| 13013-02-0 |
|
2,3,4-Trimethoxybenzonitrile, 97%
| 43020-38-8 |
|
1-Phenyl-3-(2-Thiazolyl)-2-Thiourea, 97+%
| 14901-16-7 |
|
Hydrogen fluoride, 37 wt% solution in triethylamine
| 73602-61-6 |
|
Ammonium Sodium Phosphate Tetrahydrate 99%
| 0-00-1 |
|
5,6-Benzoquinoline, 99+%
| 85-02-9 |
|
4-Methoxy-2-nitrophenol, 99+%
| 1568-70-3 |
|
4-Hydroxybenzyl Alcohol, 97% (TLC)
| 623-05-2 |
|
1-(2-Fluorophenyl)piperazine, 97%(GC)
| 1011-15-0 |
|
Hexamethyl dewar benzene, 97%
| 7641-77-2 |
|
Triaza-12-Crown-4, 99%
| 0-01-1 |
|
alpha-Angelicalactone, 98%
| 591-12-8 |
|
3-Acetamidocoumarin
| 779-30-6 |
|
4,6-Dihydroxy-2-Methylpyrimidine, 99%
| 40497-30-1 |
|
Purpurogallin, tech.
| 569-77-7 |
|
2,3-Dimethyl-P-Nitroanisole, 98%
| 81029-03-0 |
|
4-Nitro-p-terphenyl
| 10355-53-0 |
|
2,3-Dimethylcyclohexylamine, mixture of isomers, 99+%
| 42195-92-6 |
|
Epibromohydrin, 98%
| 3132-64-7 |
|
Stearic Anhydride
| 638-08-4 |
|
Ethyl Vinyl Ether, 99% (gc)
| 109-92-2 |
|
Fluoresceinamine Isomer I, 99% (UV-Vis)
| 3326-34-9 |
|
2-Methyl-1,3-cyclohexanedione, 98+%
| 1193-55-1 |
|
(2S,3S)-2-Amino-3-Ethoxybutanoic Acid Hydrochloride, 99+%, (80% e.e.)
| 0-01-1 |
|
Thioflavin t
| 2390-54-7 |
|
Methyl dichloroacetate, 99+%
| 116-54-1 |
|
Trimethylsilyl Trifluoromethanesulfonate, 99%
| 27607-77-8 |
|
3,4-Dihydro-2H-Pyran, 99%
| 110-87-2 |
|
2-Nitrophenyl Disulfide, 95%
| 1155-00-6 |
|
Methylenedi-p-phenyl diisocyanate
| 101-68-8 |
|
1-Bromo-2,3-Dichlorobenzene, 99%
| 56961-77-4 |
|
n-Butyric Anhydride, 99%
| 106-31-0 |
|
2,2',4'-Trichloroacetophenone, 95%, containing up to 10% water,
| 4252-78-2 |
|
10-Nonadecanone, 99%
| 504-57-4 |
|
Hydrogen hexachloroiridate(IV) hexahydrate, approx. 40% Iridium
| 16941-92-7 |
|
3-(3,4,5-Trimethoxyphenyl)Propionic Acid, 98+%
| 25173-72-2 |
|
Tetrodotoxin, Citrate Free
| 4368-28-9 |
|
Acid Green 25
| 4403-90-1 |
|
Coumalic Acid, 97+%
| 500-05-0 |
|
7,8-Benzoquinoline, 97%
| 230-27-3 |
|
1,10-Diaminodecane, 97+%
| 646-25-3 |
|
Inositol, 98+% (HPLC)
| 87-89-8 |
|
Thallium (III) Nitrate Trihydrate, 99.5%
| 13453-38-8 |
|
|