**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 3132-64-7 |Epibromohydrin | 98 | 221-525-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+
Risk Phrases: 10 26/27/28 40
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Very toxic by inhalation, in contact with skin and if
swallowed. Limited evidence of a carcinogenic effect.Lachrymator
(substance which increases the flow of
tears).Corrosive.Water-reactive.
Potential Health Effects
Eye:
May cause severe eye irritation. May cause eye burns. Lachrymator
(substance which increases the flow of tears).
Skin:
May be fatal if absorbed through the skin. May cause severe
irritation and possible burns.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract and possible burns.
Inhalation:
May be fatal if inhaled. May cause respiratory tract irritation.
Vapors may cause dizziness or suffocation.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Induce vomiting only when instructed to do so by a
physician.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and
flash back. Will burn if involved in a fire. Use water spray to keep
fire-exposed containers cool. Containers may explode in the heat of a
fire. Flammable liquid and vapor. Vapors may be heavier than air.
They can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Remove all sources of ignition. Use
a spark-proof tool. Provide ventilation. Do not get water inside
containers. A vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep away from heat, sparks and flame. Do not ingest or
inhale. Do not allow contact with water. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water. Flammables-area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 3132-64-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: Colorless Liquid
Odor: None reported.
pH: Not available.
Vapor Pressure: 2 mm Hg @ 25 C
Viscosity: Not available.
Boiling Point: 134.0 - 136.0 deg C @ 760.00m
Freezing/Melting Point: -40 deg C
Autoignition Temperature: Not available.
Flash Point: 56 deg C ( 132.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: reacts
Specific Gravity/Density: 1.6010g/cm3
Molecular Formula: C3H5BrO
Molecular Weight: 136.98
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong
oxidants, exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, aluminum, magnesium, sodium, strong oxidizing agents, zinc,
water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 3132-64-7: TX4115000
LD50/LC50:
Not available.
Intraperitoneal, mouse: LD50 = 300
Carcinogenicity:
Epibromohydrin -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Estimated Koc value = 22. This value indicates that epibromohydrin
will not adsorb to soil and leaching may occur. Estimated BCF value
= 0.5. This value indicates that epibromohydrin will not
bioconcentrate in aquatic organisms.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: EPIBROMOHYDRIN
Hazard Class: 6.1 (3)
UN Number: 2558
Packing Group:
IMO
Shipping Name: EPIBROMOHYDRIN
Hazard Class: 6.1 (3)
UN Number: 2558
Packing Group: I
RID/ADR
Shipping Name: EPIBROMOHYDRIN
Hazard Class: 6.1
UN Number: 2558
Packing group: I
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+
Risk Phrases:
R 10 Flammable.
R 26/27/28 Very toxic by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
Safety Phrases:
S 7/9 Keep container tightly closed and in a
well-ventilated place.
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 27 Take off immediately all contaminated clothing.
S 33 Take precautionary measures against static
discharges.
S 38 In case of insufficient ventilation, wear
suitable respiratory equipment.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 3132-64-7: No information available.
Canada
CAS# 3132-64-7 is listed on Canada's NDSL List.
CAS# 3132-64-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 3132-64-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/07/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cholesteryl Crotylcarbonate
| 62637-94-9 |
|
Chloroacetonitrile, 98+%
| 107-14-2 |
|
3-Quinuclidinone hydrochloride, 99% (tlc)
| 1193-65-3 |
|
2'-me-2',3',10,11-tetrahydrospiro(5h-diben
| 35926-76-2 |
|
l-Leucine methyl ester hydrochloride, 98%
| 7517-19-3 |
|
3-Methylbenzylamine, 98%
| 100-81-2 |
|
3-Amino-4-methylbenzoic acid, 99%
| 2458-12-0 |
|
Methyl 4-Nitrobutyrate, Tech. 80%
| 13013-02-0 |
|
2,3,4-Trimethoxybenzonitrile, 97%
| 43020-38-8 |
|
1-Phenyl-3-(2-Thiazolyl)-2-Thiourea, 97+%
| 14901-16-7 |
|
Hydrogen fluoride, 37 wt% solution in triethylamine
| 73602-61-6 |
|
Ammonium Sodium Phosphate Tetrahydrate 99%
| 0-00-1 |
|
5,6-Benzoquinoline, 99+%
| 85-02-9 |
|
4-Methoxy-2-nitrophenol, 99+%
| 1568-70-3 |
|
4-Hydroxybenzyl Alcohol, 97% (TLC)
| 623-05-2 |
|
1-(2-Fluorophenyl)piperazine, 97%(GC)
| 1011-15-0 |
|
Hexamethyl dewar benzene, 97%
| 7641-77-2 |
|
Triaza-12-Crown-4, 99%
| 0-01-1 |
|
alpha-Angelicalactone, 98%
| 591-12-8 |
|
3-Acetamidocoumarin
| 779-30-6 |
|
4,6-Dihydroxy-2-Methylpyrimidine, 99%
| 40497-30-1 |
|
Purpurogallin, tech.
| 569-77-7 |
|
2,3-Dimethyl-P-Nitroanisole, 98%
| 81029-03-0 |
|
4-Nitro-p-terphenyl
| 10355-53-0 |
|
2,3-Dimethylcyclohexylamine, mixture of isomers, 99+%
| 42195-92-6 |
|
Epibromohydrin, 98%
| 3132-64-7 |
|
Stearic Anhydride
| 638-08-4 |
|
Ethyl Vinyl Ether, 99% (gc)
| 109-92-2 |
|
Fluoresceinamine Isomer I, 99% (UV-Vis)
| 3326-34-9 |
|
2-Methyl-1,3-cyclohexanedione, 98+%
| 1193-55-1 |
|
(2S,3S)-2-Amino-3-Ethoxybutanoic Acid Hydrochloride, 99+%, (80% e.e.)
| 0-01-1 |
|
Thioflavin t
| 2390-54-7 |
|
Methyl dichloroacetate, 99+%
| 116-54-1 |
|
Trimethylsilyl Trifluoromethanesulfonate, 99%
| 27607-77-8 |
|
3,4-Dihydro-2H-Pyran, 99%
| 110-87-2 |
|
2-Nitrophenyl Disulfide, 95%
| 1155-00-6 |
|
Methylenedi-p-phenyl diisocyanate
| 101-68-8 |
|
1-Bromo-2,3-Dichlorobenzene, 99%
| 56961-77-4 |
|
n-Butyric Anhydride, 99%
| 106-31-0 |
|
2,2',4'-Trichloroacetophenone, 95%, containing up to 10% water,
| 4252-78-2 |
|
10-Nonadecanone, 99%
| 504-57-4 |
|
Hydrogen hexachloroiridate(IV) hexahydrate, approx. 40% Iridium
| 16941-92-7 |
|
3-(3,4,5-Trimethoxyphenyl)Propionic Acid, 98+%
| 25173-72-2 |
|
Tetrodotoxin, Citrate Free
| 4368-28-9 |
|
Acid Green 25
| 4403-90-1 |
|
Coumalic Acid, 97+%
| 500-05-0 |
|
7,8-Benzoquinoline, 97%
| 230-27-3 |
|
1,10-Diaminodecane, 97+%
| 646-25-3 |
|
Inositol, 98+% (HPLC)
| 87-89-8 |
|
Thallium (III) Nitrate Trihydrate, 99.5%
| 13453-38-8 |
|
|