**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 116-54-1 |Methyl dichloroacetate | 99+ | 204-146-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 34
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes burns.Corrosive.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes second and third degree burns on short contact, especially if
skin is moist or wet.
Ingestion:
May cause severe and permanent damage to the digestive tract. Causes
gastrointestinal irritation with nausea, vomiting and diarrhea.
Causes gastrointestinal tract burns.
Inhalation:
Causes respiratory tract irritation. Causes chemical burns to the
respiratory tract. Vapors may cause dizziness or suffocation.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Combustible liquid.
Containers may explode when heated.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. DO NOT USE WATER!
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Provide ventilation. Do not get water inside
containers.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Do not get in eyes, on skin, or on clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame. Do
not ingest or inhale. Use with adequate ventilation. Discard
contaminated shoes. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Keep container closed when not in use. Store in a tightly
closed container. Store in a cool, dry, well-ventilated area away
from incompatible substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 116-54-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: ethereal odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 143.0 - 143.0 deg C @ 760.00m
Freezing/Melting Point: -52 deg C
Autoignition Temperature: Not available.
Flash Point: 80 deg C ( 176.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts.
Specific Gravity/Density: 1.3810g/cm3
Molecular Formula: C3H4Cl2O2
Molecular Weight: 142.97
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, contact with water, excess
heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents, acids, bases.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 116-54-1: AG6625000
LD50/LC50:
Not available.
Carcinogenicity:
Methyl dichloroacetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: METHYL DICHLOROACETATE
Hazard Class: 6.1
UN Number: 2299
Packing Group: III
IMO
Shipping Name: METHYL DICHLOROACETATE
Hazard Class: 6.1
UN Number: 2299
Packing Group: III
RID/ADR
Shipping Name: METHYL DICHLOROACETATE
Hazard Class: 6.1
UN Number: 2299
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 116-54-1: 1
Canada
CAS# 116-54-1 is listed on Canada's NDSL List.
CAS# 116-54-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 116-54-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/05/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cholesteryl Crotylcarbonate
| 62637-94-9 |
|
Chloroacetonitrile, 98+%
| 107-14-2 |
|
3-Quinuclidinone hydrochloride, 99% (tlc)
| 1193-65-3 |
|
2'-me-2',3',10,11-tetrahydrospiro(5h-diben
| 35926-76-2 |
|
l-Leucine methyl ester hydrochloride, 98%
| 7517-19-3 |
|
3-Methylbenzylamine, 98%
| 100-81-2 |
|
3-Amino-4-methylbenzoic acid, 99%
| 2458-12-0 |
|
Methyl 4-Nitrobutyrate, Tech. 80%
| 13013-02-0 |
|
2,3,4-Trimethoxybenzonitrile, 97%
| 43020-38-8 |
|
1-Phenyl-3-(2-Thiazolyl)-2-Thiourea, 97+%
| 14901-16-7 |
|
Hydrogen fluoride, 37 wt% solution in triethylamine
| 73602-61-6 |
|
Ammonium Sodium Phosphate Tetrahydrate 99%
| 0-00-1 |
|
5,6-Benzoquinoline, 99+%
| 85-02-9 |
|
4-Methoxy-2-nitrophenol, 99+%
| 1568-70-3 |
|
4-Hydroxybenzyl Alcohol, 97% (TLC)
| 623-05-2 |
|
1-(2-Fluorophenyl)piperazine, 97%(GC)
| 1011-15-0 |
|
Hexamethyl dewar benzene, 97%
| 7641-77-2 |
|
Triaza-12-Crown-4, 99%
| 0-01-1 |
|
alpha-Angelicalactone, 98%
| 591-12-8 |
|
3-Acetamidocoumarin
| 779-30-6 |
|
4,6-Dihydroxy-2-Methylpyrimidine, 99%
| 40497-30-1 |
|
Purpurogallin, tech.
| 569-77-7 |
|
2,3-Dimethyl-P-Nitroanisole, 98%
| 81029-03-0 |
|
4-Nitro-p-terphenyl
| 10355-53-0 |
|
2,3-Dimethylcyclohexylamine, mixture of isomers, 99+%
| 42195-92-6 |
|
Epibromohydrin, 98%
| 3132-64-7 |
|
Stearic Anhydride
| 638-08-4 |
|
Ethyl Vinyl Ether, 99% (gc)
| 109-92-2 |
|
Fluoresceinamine Isomer I, 99% (UV-Vis)
| 3326-34-9 |
|
2-Methyl-1,3-cyclohexanedione, 98+%
| 1193-55-1 |
|
(2S,3S)-2-Amino-3-Ethoxybutanoic Acid Hydrochloride, 99+%, (80% e.e.)
| 0-01-1 |
|
Thioflavin t
| 2390-54-7 |
|
Methyl dichloroacetate, 99+%
| 116-54-1 |
|
Trimethylsilyl Trifluoromethanesulfonate, 99%
| 27607-77-8 |
|
3,4-Dihydro-2H-Pyran, 99%
| 110-87-2 |
|
2-Nitrophenyl Disulfide, 95%
| 1155-00-6 |
|
Methylenedi-p-phenyl diisocyanate
| 101-68-8 |
|
1-Bromo-2,3-Dichlorobenzene, 99%
| 56961-77-4 |
|
n-Butyric Anhydride, 99%
| 106-31-0 |
|
2,2',4'-Trichloroacetophenone, 95%, containing up to 10% water,
| 4252-78-2 |
|
10-Nonadecanone, 99%
| 504-57-4 |
|
Hydrogen hexachloroiridate(IV) hexahydrate, approx. 40% Iridium
| 16941-92-7 |
|
3-(3,4,5-Trimethoxyphenyl)Propionic Acid, 98+%
| 25173-72-2 |
|
Tetrodotoxin, Citrate Free
| 4368-28-9 |
|
Acid Green 25
| 4403-90-1 |
|
Coumalic Acid, 97+%
| 500-05-0 |
|
7,8-Benzoquinoline, 97%
| 230-27-3 |
|
1,10-Diaminodecane, 97+%
| 646-25-3 |
|
Inositol, 98+% (HPLC)
| 87-89-8 |
|
Thallium (III) Nitrate Trihydrate, 99.5%
| 13453-38-8 |
|
|