**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-70-3 |1,3,5-Trichlorobenzene | 99% | 203-608-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 22 38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful if swallowed. Irritating to skin.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause liver and kidney damage. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage. Chronic exposure can affect thyroid
function.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 108-70-3:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: Moth-powder odor
pH: Not available.
Vapor Pressure: 10 mm Hg @ 78 deg C
Viscosity: Not available.
Boiling Point: 208 deg C @ 760.00mm Hg
Freezing/Melting Point: 63.0 - 65.0 deg C
Autoignition Temperature: Not available.
Flash Point: 126 deg C ( 258.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble in water (volatile with steam)
Specific Gravity/Density:
Molecular Formula: C6H3Cl3
Molecular Weight: 181.45
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-70-3: DC2100100
LD50/LC50:
CAS# 108-70-3: Draize test, rabbit, eye: 100 mg Mild; Draize test,
rabbit, skin: 500 mg/24H Mild; Oral, mouse: LD50 = 3350 mg/kg; Oral,
rat: LD50 = 800 mg/kg.
Carcinogenicity:
1,3,5-Trichlorobenzene -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
log Pow 4.49 Fish toxicity: LC50 (14day) guppy 3.3 mg/l
(Konemann,W.H. Qualitative Structure-Activity Relationships for
Kinetics and Toxicity of Aquatic Pollutants and their Mixtures to
Fish 1979, Univ.Utrecht). LD50 intraperitoneal rainbow trout 5600
mg/kg (Hodson,P.V. et al Environ.Toxicol.Chem.1988, 7(6), 443-454).
Invertebrate toxicity: EC50 (30min) Photobacterium phosphoreum 14 ppm
Microtox test (Kaiser,K.L.E. et al Water Pollut.Res.J.Can.1991,
26(3), 361-431).
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 22 Harmful if swallowed.
R 38 Irritating to skin.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 108-70-3: 3
Canada
CAS# 108-70-3 is listed on Canada's DSL List.
CAS# 108-70-3 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-70-3 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aluminum isopropoxide
| 555-31-7 |
|
Cholesteryl-2-(ethoxyethoxy)ethyl Carbonate
| 15484-00-1 |
|
3,5-Lutidine, 98+%
| 591-22-0 |
|
Ethyl 4-Methoxyphenylacetate, 97+%
| 14062-18-1 |
|
(-)-Camphanic acid, 99%
| 13429-83-9 |
|
Amberlite irc-718 ion-exchange resin
| 79620-28-3 |
|
3,4,5-Trifluoroaniline, 98%
| |
|
Carbobenzyloxy-D-Phenylalanine, 99+%
| 28709-70-8 |
|
DL-Thioctic Acid, 98% (UV, on the Dried Substance)
| 1077-28-7 |
|
Dowex 1x2-200 ion-exchange resin
| 9085-42-1 |
|
Diphenylacetylchloride, 97.5%
| 1871-76-7 |
|
4-Methyl-1-pentene, 97%
| 691-37-2 |
|
Ethylmethacrylate, 99% (GC)
| 97-63-2 |
|
Anthraquinone-1,5-disulfonic acid, disodium salt, hydrate, tech.
| 853-35-0 |
|
Copper atomic absorption standard solution, 1 mg/ml Cu in 2% HNO3
| 7440-50-8 |
|
Gadolinium (iii) nitrate pentahydrate 99.999%
| 52788-53-1 |
|
1-Iodononane, 99%
| 4282-42-2 |
|
Isopulegol, tech
| 89-79-2 |
|
5-Chloro-8-Hydroxyquinoline, 95%
| 130-16-5 |
|
4-Amino-1-naphthalenesulfonic acid, sodium salt, hydrate, 98%
| 130-13-2 |
|
1,3,5-Trichlorobenzene, 99%
| 108-70-3 |
|
Indoline, 99%
| 496-15-1 |
|
Dimethylamino-1-Naphthylisothiocyanate, 98%
| 29711-79-3 |
|
DL-Alanine Ethyl Ester Hydrochloride, 99% (Titr.)
| 617-27-6 |
|
N-Vinyl-2-pyrrolidinone, stabilized, 98%
| 88-12-0 |
|
Dowex 50x4-400 ion-exchange resin
| 11113-61-4 |
|
Dibutyltin dichloride, 97%
| 683-18-1 |
|
Butyl 4-(4-ethoxyphenoxycarbonyl)phenyl carbonate
| 16494-24-9 |
|
Dihydrocoumarin, 99%
| 119-84-6 |
|
3-Methylbenzyl Cyanide, 98%
| 2947-60-6 |
|
2-Methyl-2-pentene, 99+%
| 625-27-4 |
|
1-Amino-4-methylpiperazine dihydrochloride, monohydrate, 98%
| 40675-60-3 |
|
Bromothymol Blue, Reagent ACS, 97% (uv-vis )
| 76-59-5 |
|
1-(beta-Phenethyl)-4-piperidone, 98%
| 39742-60-4 |
|
2-Ethylfuran, 99%
| 3208-16-0 |
|
Aniline sulfate, 99% (uv-vis)
| 542-16-5 |
|
1-Chloro-2-Propanol, 70%, Remainder 2-Chloro-1-Propanol
| 127-00-4 |
|
Metronidazole, 99%
| 443-48-1 |
|
Tetrabromothiophene, 99+%
| 3958-03-0 |
|
2-(4-Chlorophenoxy)-2-Methylpropionic Acid, 99%
| 882-09-7 |
|
N,N-Dimethylethylamine, 99%
| 598-56-1 |
|
4-Formylphenoxyacetic acid, 99% (titr.)
| 22042-71-3 |
|
1-Amino-2-Naphthol Hydrochloride, Tech., 90%
| 1198-27-2 |
|
N-Acetylmorpholine, 98%
| 1696-20-4 |
|
3-Phenylpropylacetate,98+% (gc)
| 122-72-5 |
|
Europium(iii) chloride hexahydrate, 99.99%
| 13759-92-7 |
|
1,1,3-Trimethoxypropane, 99%
| 14315-97-0 |
|
2-Amino-4-Imino-2-Thiazoline Hydrochloride, 99%
| 36518-76-0 |
|
3-Chlorobenzyl cyanide, 99%
| 1529-41-5 |
|
Tetraphenylethylene, 98%
| 632-51-9 |
|
|