**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 97-63-2 |Ethyl Methacrylate | 99 | 202-597-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI F
Risk Phrases: 11 36/37/38 43
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact.Highly flammable.Lachrymator
(substance which increases the flow of tears).
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears).
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
Causes respiratory tract irritation. Vapors may cause dizziness or
suffocation. Central nervous system effects, which appear to
predominate in acute cases are characterized by abnormal fatigue,
memory difficulties and dizziness.
Chronic:
Repeated exposure may cause sensitization dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid. Do
NOT allow victim to rub eyes or keep eyes closed.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Use water spray to keep fire-exposed
containers cool. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Flammable liquid
and vapor. Vapors may be heavier than air. They can spread along
the ground and collect in low or confined areas. May polymerize
explosively when involved in a fire. Will be easily ignited by heat,
sparks or flame. Containers may explode if exposed to fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Water may be ineffective. Water may spread
fire. If water is the only media available, use in flooding amounts.
For large fires, use water spray, fog or alcohol-resistant foam. Do
NOT use straight streams of water. Cool containers with flooding
quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Keep container
tightly closed. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Use with adequate ventilation. Wash
clothing before reuse. Do not pressurize, cut, weld, braze, solder,
drill, grind, or expose empty containers to heat, sparks or open
flames.
Storage:
Keep away from heat, sparks, and flame. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Flammables-area. Keep refrigerated. (Store
below 4C/39F.) Do not store in metal containers. Keep away from
polymerization catalysts.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 97-63-2:
Germany: 250 mg/m3 TWA
Netherlands: 10 ppm MAC; 48 mg/m3 MAC
Russia: 50 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: acrid odor
pH: Not available.
Vapor Pressure: 21.3 mbar @ 20
Viscosity: 0.63 mPas @ 20C
Boiling Point: 118 deg C
Freezing/Melting Point: -75 deg C
Autoignition Temperature: Not available.
Flash Point: 21 deg C ( 69.80 deg F)
Explosion Limits, lower: 1.8
Explosion Limits, upper: Saturation
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density: .9180g/cm3
Molecular Formula: C6H10O2
Molecular Weight: 114.14
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Stable. However, it may undergo explosive
polymerization if uninhibited.
Conditions to Avoid:
Incompatible materials, ignition sources, metals, excess heat, strong
oxidants, temperatures above 40C.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Will occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 97-63-2: OZ4550000
LD50/LC50:
CAS# 97-63-2: Inhalation, rat: LC50 = 8300 ppm/4H; Oral, mouse: LD50
= 7836 mg/kg; Oral, rat: LD50 = 14800 mg/kg.
Carcinogenicity:
Ethyl Methacrylate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 97-63-2: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI F
Risk Phrases:
R 11 Highly flammable.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 97-63-2: 1
Canada
CAS# 97-63-2 is listed on Canada's DSL List.
CAS# 97-63-2 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 97-63-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 10/20/1998 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Aluminum isopropoxide
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Cholesteryl-2-(ethoxyethoxy)ethyl Carbonate
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3,5-Lutidine, 98+%
| 591-22-0 |
|
Ethyl 4-Methoxyphenylacetate, 97+%
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(-)-Camphanic acid, 99%
| 13429-83-9 |
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Amberlite irc-718 ion-exchange resin
| 79620-28-3 |
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3,4,5-Trifluoroaniline, 98%
| |
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Carbobenzyloxy-D-Phenylalanine, 99+%
| 28709-70-8 |
|
DL-Thioctic Acid, 98% (UV, on the Dried Substance)
| 1077-28-7 |
|
Dowex 1x2-200 ion-exchange resin
| 9085-42-1 |
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Diphenylacetylchloride, 97.5%
| 1871-76-7 |
|
4-Methyl-1-pentene, 97%
| 691-37-2 |
|
Ethylmethacrylate, 99% (GC)
| 97-63-2 |
|
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| 853-35-0 |
|
Copper atomic absorption standard solution, 1 mg/ml Cu in 2% HNO3
| 7440-50-8 |
|
Gadolinium (iii) nitrate pentahydrate 99.999%
| 52788-53-1 |
|
1-Iodononane, 99%
| 4282-42-2 |
|
Isopulegol, tech
| 89-79-2 |
|
5-Chloro-8-Hydroxyquinoline, 95%
| 130-16-5 |
|
4-Amino-1-naphthalenesulfonic acid, sodium salt, hydrate, 98%
| 130-13-2 |
|
1,3,5-Trichlorobenzene, 99%
| 108-70-3 |
|
Indoline, 99%
| 496-15-1 |
|
Dimethylamino-1-Naphthylisothiocyanate, 98%
| 29711-79-3 |
|
DL-Alanine Ethyl Ester Hydrochloride, 99% (Titr.)
| 617-27-6 |
|
N-Vinyl-2-pyrrolidinone, stabilized, 98%
| 88-12-0 |
|
Dowex 50x4-400 ion-exchange resin
| 11113-61-4 |
|
Dibutyltin dichloride, 97%
| 683-18-1 |
|
Butyl 4-(4-ethoxyphenoxycarbonyl)phenyl carbonate
| 16494-24-9 |
|
Dihydrocoumarin, 99%
| 119-84-6 |
|
3-Methylbenzyl Cyanide, 98%
| 2947-60-6 |
|
2-Methyl-2-pentene, 99+%
| 625-27-4 |
|
1-Amino-4-methylpiperazine dihydrochloride, monohydrate, 98%
| 40675-60-3 |
|
Bromothymol Blue, Reagent ACS, 97% (uv-vis )
| 76-59-5 |
|
1-(beta-Phenethyl)-4-piperidone, 98%
| 39742-60-4 |
|
2-Ethylfuran, 99%
| 3208-16-0 |
|
Aniline sulfate, 99% (uv-vis)
| 542-16-5 |
|
1-Chloro-2-Propanol, 70%, Remainder 2-Chloro-1-Propanol
| 127-00-4 |
|
Metronidazole, 99%
| 443-48-1 |
|
Tetrabromothiophene, 99+%
| 3958-03-0 |
|
2-(4-Chlorophenoxy)-2-Methylpropionic Acid, 99%
| 882-09-7 |
|
N,N-Dimethylethylamine, 99%
| 598-56-1 |
|
4-Formylphenoxyacetic acid, 99% (titr.)
| 22042-71-3 |
|
1-Amino-2-Naphthol Hydrochloride, Tech., 90%
| 1198-27-2 |
|
N-Acetylmorpholine, 98%
| 1696-20-4 |
|
3-Phenylpropylacetate,98+% (gc)
| 122-72-5 |
|
Europium(iii) chloride hexahydrate, 99.99%
| 13759-92-7 |
|
1,1,3-Trimethoxypropane, 99%
| 14315-97-0 |
|
2-Amino-4-Imino-2-Thiazoline Hydrochloride, 99%
| 36518-76-0 |
|
3-Chlorobenzyl cyanide, 99%
| 1529-41-5 |
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Tetraphenylethylene, 98%
| 632-51-9 |
|
|