**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 542-16-5 |Aniline sulfate | 99% | 208-805-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 20/21/22 40 50 48/23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Very toxic to aquatic
organisms. Toxic : danger of serious damage to health by prolonged
exposure through inhalation, contact with skin and if swallowed.The
toxicological properties of this material have not been fully
investigated.Hygroscopic (absorbs moisture from the air).Light
sensitive.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Harmful if absorbed through the skin. If
absorbed, may cause symptoms similar to those for ingestion.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. The toxicological properties of this substance have not
been fully investigated. Methemoglobinemia is characterized by
dizziness, drowsiness, headache, shortness of breath, cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood), rapid heart rate and chocolate-brown colored blood.
Overexposure may cause methemoglobinemia.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. May cause pulmonary edema and severe
respiratory disturbances. The toxicological properties of this
substance have not been fully investigated.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Absorption of this product into the body may cause cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Moderate degrees of cyanosis need to be treated only by supportive
measures: bed rest and oxygen inhalation. For methemoglobinemia,
administer oxygen alone or with Methylene Blue depending on the
methemoglobin concentration in the blood. Cleansing of the entire
contaminated area of the body is of utmost importance.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wash area with soap and water. Clean up spills
immediately, observing precautions in the Protective Equipment
section. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation. Use only in a chemical fume
hood.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store
in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 542-16-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.3800g/cm3
Molecular Formula: C12H14N2.H2SO4
Molecular Weight: 284.33
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 542-16-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Aniline sulfate -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 542-16-5: No information available.
Canada
CAS# 542-16-5 is listed on Canada's DSL List.
CAS# 542-16-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 542-16-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 8/24/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aluminum isopropoxide
| 555-31-7 |
|
Cholesteryl-2-(ethoxyethoxy)ethyl Carbonate
| 15484-00-1 |
|
3,5-Lutidine, 98+%
| 591-22-0 |
|
Ethyl 4-Methoxyphenylacetate, 97+%
| 14062-18-1 |
|
(-)-Camphanic acid, 99%
| 13429-83-9 |
|
Amberlite irc-718 ion-exchange resin
| 79620-28-3 |
|
3,4,5-Trifluoroaniline, 98%
| |
|
Carbobenzyloxy-D-Phenylalanine, 99+%
| 28709-70-8 |
|
DL-Thioctic Acid, 98% (UV, on the Dried Substance)
| 1077-28-7 |
|
Dowex 1x2-200 ion-exchange resin
| 9085-42-1 |
|
Diphenylacetylchloride, 97.5%
| 1871-76-7 |
|
4-Methyl-1-pentene, 97%
| 691-37-2 |
|
Ethylmethacrylate, 99% (GC)
| 97-63-2 |
|
Anthraquinone-1,5-disulfonic acid, disodium salt, hydrate, tech.
| 853-35-0 |
|
Copper atomic absorption standard solution, 1 mg/ml Cu in 2% HNO3
| 7440-50-8 |
|
Gadolinium (iii) nitrate pentahydrate 99.999%
| 52788-53-1 |
|
1-Iodononane, 99%
| 4282-42-2 |
|
Isopulegol, tech
| 89-79-2 |
|
5-Chloro-8-Hydroxyquinoline, 95%
| 130-16-5 |
|
4-Amino-1-naphthalenesulfonic acid, sodium salt, hydrate, 98%
| 130-13-2 |
|
1,3,5-Trichlorobenzene, 99%
| 108-70-3 |
|
Indoline, 99%
| 496-15-1 |
|
Dimethylamino-1-Naphthylisothiocyanate, 98%
| 29711-79-3 |
|
DL-Alanine Ethyl Ester Hydrochloride, 99% (Titr.)
| 617-27-6 |
|
N-Vinyl-2-pyrrolidinone, stabilized, 98%
| 88-12-0 |
|
Dowex 50x4-400 ion-exchange resin
| 11113-61-4 |
|
Dibutyltin dichloride, 97%
| 683-18-1 |
|
Butyl 4-(4-ethoxyphenoxycarbonyl)phenyl carbonate
| 16494-24-9 |
|
Dihydrocoumarin, 99%
| 119-84-6 |
|
3-Methylbenzyl Cyanide, 98%
| 2947-60-6 |
|
2-Methyl-2-pentene, 99+%
| 625-27-4 |
|
1-Amino-4-methylpiperazine dihydrochloride, monohydrate, 98%
| 40675-60-3 |
|
Bromothymol Blue, Reagent ACS, 97% (uv-vis )
| 76-59-5 |
|
1-(beta-Phenethyl)-4-piperidone, 98%
| 39742-60-4 |
|
2-Ethylfuran, 99%
| 3208-16-0 |
|
Aniline sulfate, 99% (uv-vis)
| 542-16-5 |
|
1-Chloro-2-Propanol, 70%, Remainder 2-Chloro-1-Propanol
| 127-00-4 |
|
Metronidazole, 99%
| 443-48-1 |
|
Tetrabromothiophene, 99+%
| 3958-03-0 |
|
2-(4-Chlorophenoxy)-2-Methylpropionic Acid, 99%
| 882-09-7 |
|
N,N-Dimethylethylamine, 99%
| 598-56-1 |
|
4-Formylphenoxyacetic acid, 99% (titr.)
| 22042-71-3 |
|
1-Amino-2-Naphthol Hydrochloride, Tech., 90%
| 1198-27-2 |
|
N-Acetylmorpholine, 98%
| 1696-20-4 |
|
3-Phenylpropylacetate,98+% (gc)
| 122-72-5 |
|
Europium(iii) chloride hexahydrate, 99.99%
| 13759-92-7 |
|
1,1,3-Trimethoxypropane, 99%
| 14315-97-0 |
|
2-Amino-4-Imino-2-Thiazoline Hydrochloride, 99%
| 36518-76-0 |
|
3-Chlorobenzyl cyanide, 99%
| 1529-41-5 |
|
Tetraphenylethylene, 98%
| 632-51-9 |
|
|