**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 555-31-7 |Aluminum isopropoxide | >98 | 209-090-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.Moisture sensitive.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this
material have not been fully investigated.
Skin:
May cause skin irritation. Isopropanol has a low potential to cause
allergic skin reactions; however, rare cases of allergic contact
dermatitis have been reported.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Hydrolyzes in the presence of water and body fluids to
isopropanol, which can cause headache, nausea, narcosis, and mental
depresssion.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Inhalation of
dusts cause severe irritation of the upper respiratory tract,
gastrointestinal disturbances, albuminuria, gradual loss of weight,
and increasing weakness.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse. If
water-reactive products are embedded in the skin, no water should be
applied. The embedded products should be covered with a light oil.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Dusts at sufficient concentrations can form
explosive mixtures with air. During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Will burn if involved in a fire. Water Reactive. Material will react
with water and may release a flammable and/or toxic gas. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire. Flammable solid. May ignite or explode on
contact with steam or moist air. May re-ignite after fire is
extinguished.
Extinguishing Media:
Use carbon dioxide or dry chemical. DO NOT USE WATER! Do NOT get
water inside containers. Contact professional fire-fighters
immediately. Cool containers with flooding quantities of water until
well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Remove all sources of ignition. Use a
spark-proof tool. Provide ventilation. Do not expose spill to water.
Do not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not allow contact with water. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Store protected from moisture.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 555-31-7:
United Kingdom, WEL - TWA: (listed as aluminum, soluble salts): 2
mg/m3 TWA
United Kingdom, WEL - STEL: (listed as aluminum, soluble salts):
mg/m3 STEL
Belgium - TWA: (listed as aluminum, soluble salts): 2 mg/m3 VLE (
Al)
France - VME: (listed as aluminum, soluble salts): 2 mg/m3 VME
Germany: (listed as aluminum, soluble salts): 2 mg/m3 VME
Malaysia: (listed as aluminum, soluble salts): 2 mg/m3 TWA (as Al
Spain: (listed as aluminum, soluble salts): 2 mg/m3 VLA-ED (as Al
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white
Odor: alcohol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 135 deg C @ 10 mm Hg
Freezing/Melting Point: 119-142 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Decomposes in water.
Specific Gravity/Density: 1.035
Molecular Formula: AlC9H21O3
Molecular Weight: 204.25
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Isopropanol is
susceptible to autoxidation and therefore should be classified as
peroxidizable. Reacts with water.
Conditions to Avoid:
Ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Water.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, aluminum oxide, isopropanol.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 555-31-7: BD0975000
LD50/LC50:
CAS# 555-31-7: Oral, rat: LD50 = 11300 mg/kg.
Carcinogenicity:
Aluminum isopropoxide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S
.*
Hazard Class: 4.1
UN Number: 3181
Packing Group: II
IMO
Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S
.
Hazard Class: 4.1
UN Number: 3181
Packing Group: II
RID/ADR
Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S
.
Hazard Class: 4.1
UN Number: 3181
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 8 Keep container dry.
S 16 Keep away from sources of ignition - No
smoking.
WGK (Water Danger/Protection)
CAS# 555-31-7: 1
Canada
CAS# 555-31-7 is listed on Canada's DSL List.
CAS# 555-31-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 555-31-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/04/1998 Revision #6 Date: 8/17/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Aluminum isopropoxide
| 555-31-7 |
|
Cholesteryl-2-(ethoxyethoxy)ethyl Carbonate
| 15484-00-1 |
|
3,5-Lutidine, 98+%
| 591-22-0 |
|
Ethyl 4-Methoxyphenylacetate, 97+%
| 14062-18-1 |
|
(-)-Camphanic acid, 99%
| 13429-83-9 |
|
Amberlite irc-718 ion-exchange resin
| 79620-28-3 |
|
3,4,5-Trifluoroaniline, 98%
| |
|
Carbobenzyloxy-D-Phenylalanine, 99+%
| 28709-70-8 |
|
DL-Thioctic Acid, 98% (UV, on the Dried Substance)
| 1077-28-7 |
|
Dowex 1x2-200 ion-exchange resin
| 9085-42-1 |
|
Diphenylacetylchloride, 97.5%
| 1871-76-7 |
|
4-Methyl-1-pentene, 97%
| 691-37-2 |
|
Ethylmethacrylate, 99% (GC)
| 97-63-2 |
|
Anthraquinone-1,5-disulfonic acid, disodium salt, hydrate, tech.
| 853-35-0 |
|
Copper atomic absorption standard solution, 1 mg/ml Cu in 2% HNO3
| 7440-50-8 |
|
Gadolinium (iii) nitrate pentahydrate 99.999%
| 52788-53-1 |
|
1-Iodononane, 99%
| 4282-42-2 |
|
Isopulegol, tech
| 89-79-2 |
|
5-Chloro-8-Hydroxyquinoline, 95%
| 130-16-5 |
|
4-Amino-1-naphthalenesulfonic acid, sodium salt, hydrate, 98%
| 130-13-2 |
|
1,3,5-Trichlorobenzene, 99%
| 108-70-3 |
|
Indoline, 99%
| 496-15-1 |
|
Dimethylamino-1-Naphthylisothiocyanate, 98%
| 29711-79-3 |
|
DL-Alanine Ethyl Ester Hydrochloride, 99% (Titr.)
| 617-27-6 |
|
N-Vinyl-2-pyrrolidinone, stabilized, 98%
| 88-12-0 |
|
Dowex 50x4-400 ion-exchange resin
| 11113-61-4 |
|
Dibutyltin dichloride, 97%
| 683-18-1 |
|
Butyl 4-(4-ethoxyphenoxycarbonyl)phenyl carbonate
| 16494-24-9 |
|
Dihydrocoumarin, 99%
| 119-84-6 |
|
3-Methylbenzyl Cyanide, 98%
| 2947-60-6 |
|
2-Methyl-2-pentene, 99+%
| 625-27-4 |
|
1-Amino-4-methylpiperazine dihydrochloride, monohydrate, 98%
| 40675-60-3 |
|
Bromothymol Blue, Reagent ACS, 97% (uv-vis )
| 76-59-5 |
|
1-(beta-Phenethyl)-4-piperidone, 98%
| 39742-60-4 |
|
2-Ethylfuran, 99%
| 3208-16-0 |
|
Aniline sulfate, 99% (uv-vis)
| 542-16-5 |
|
1-Chloro-2-Propanol, 70%, Remainder 2-Chloro-1-Propanol
| 127-00-4 |
|
Metronidazole, 99%
| 443-48-1 |
|
Tetrabromothiophene, 99+%
| 3958-03-0 |
|
2-(4-Chlorophenoxy)-2-Methylpropionic Acid, 99%
| 882-09-7 |
|
N,N-Dimethylethylamine, 99%
| 598-56-1 |
|
4-Formylphenoxyacetic acid, 99% (titr.)
| 22042-71-3 |
|
1-Amino-2-Naphthol Hydrochloride, Tech., 90%
| 1198-27-2 |
|
N-Acetylmorpholine, 98%
| 1696-20-4 |
|
3-Phenylpropylacetate,98+% (gc)
| 122-72-5 |
|
Europium(iii) chloride hexahydrate, 99.99%
| 13759-92-7 |
|
1,1,3-Trimethoxypropane, 99%
| 14315-97-0 |
|
2-Amino-4-Imino-2-Thiazoline Hydrochloride, 99%
| 36518-76-0 |
|
3-Chlorobenzyl cyanide, 99%
| 1529-41-5 |
|
Tetraphenylethylene, 98%
| 632-51-9 |
|
|