**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 108-83-8 |Diisobutyl ketone | 80 | 203-620-1 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 10 37
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Irritating to respiratory system.
Potential Health Effects
Eye:
Vapors may cause eye irritation.
Skin:
May cause skin irritation. May cause dermatitis.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
Inhalation of vapors causes irritation of eyes, throat, and skin.
Vapors may cause dizziness or suffocation. Inhalation of high
concentrations may cause narcotic effects.
Chronic:
Prolonged or repeated contact may cause possible eczema.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Containers may explode
in the heat of a fire. Flammable liquid and vapor. Vapors may be
heavier than air. They can spread along the ground and collect in
low or confined areas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use water fog, dry chemical, carbon dioxide, or regular
foam. Use agent most appropriate to extinguish fire. Do NOT use
straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Avoid contact with
eyes, skin, and clothing. Empty containers retain product residue,
(liquid and/or vapor), and can be dangerous. Keep container tightly
closed. Keep away from heat, sparks and flame. Avoid ingestion and
inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 108-83-8:
United Kingdom, WEL - TWA: 25 ppm TWA; 148 mg/m3 TWA
United Kingdom, WEL - STEL: 75 ppm STEL; 444 mg/m3 STEL
United States OSHA: 50 ppm TWA; 290 mg/m3 TWA
Belgium - TWA: 25 ppm VLE; 147 mg/m3 VLE
France - VME: 25 ppm VME; 250 mg/m3 VME
Germany: 50 ppm TWA; 290 mg/m3 TWA
Malaysia: 25 ppm TWA; 145 mg/m3 TWA
Netherlands: 25 ppm MAC; 150 mg/m3 MAC
Spain: 25 ppm VLA-ED; 148 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Color: colorless
Odor: mild odor - peppermint odor
pH: Not available.
Vapor Pressure: 2.4 mbar @ 20 C
Viscosity: 1.05 MPA 20.00 deg
Boiling Point: 169 deg C @ 760.00mm Hg
Freezing/Melting Point: -46 deg C
Autoignition Temperature: 345 deg C ( 653.00 deg F)
Flash Point: 49 deg C ( 120.20 deg F)
Explosion Limits, lower: .80 vol %
Explosion Limits, upper: 7.10 vol %
Decomposition Temperature:
Solubility in water: Immiscible.
Specific Gravity/Density: .8060g/cm3
Molecular Formula: C9H18O
Molecular Weight: 142.24
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, electrical
sparks, exposure to flame, plastics.
Incompatibilities with Other Materials:
Strong acids, alliphatic amines, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 108-83-8: MJ5775000
LD50/LC50:
CAS# 108-83-8: Draize test, rabbit, eye: 500 mg Mild; Oral, mouse:
LD50 = 1416 mg/kg; Oral, rat: LD50 = 5750 mg/kg; Skin, rabbit: LD50 =
16 gm/kg.
Carcinogenicity:
Diisobutyl ketone -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Shrimp: 65 ppm; 24 hr.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: DIISOBUTYL KETONE
Hazard Class: 3
UN Number: 1157
Packing Group: III
IMO
Shipping Name: DIISOBUTYL KETONE
Hazard Class: 3.3
UN Number: 1157
Packing Group: III
RID/ADR
Shipping Name: DIISOBUTYL KETONE
Hazard Class: 3
UN Number: 1157
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 10 Flammable.
R 37 Irritating to respiratory system.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 24 Avoid contact with skin.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 108-83-8: 1
Canada
CAS# 108-83-8 is listed on Canada's DSL List.
CAS# 108-83-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-83-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 4/03/1998 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Bis-(trimethylsilyl)-trifluoroacetamide, 98+%
| 25561-30-2 |
|
2-Chloro-m-xylene, 99%
| 6781-98-2 |
|
1,4-Dioxaspiro[4.5]Decan-8-One, 98%
| 4746-97-8 |
|
Alpha, Alpha, Alpha, 4-Tetrafluoro-M-Toluidine, 99%
| 2357-47-3 |
|
3-Aminophthalic Acid Hydrochloride, 98% (Titr.)
| 6946-22-1 |
|
Arsenic atomic absorption standard solution, 1mg/ml as in 2% koh
| 1310-58-3 |
|
5-Bromocytosine, 99%
| 2240-25-7 |
|
2-Methyl-3-nitrobenzyl alcohol, 99%
| 23876-13-3 |
|
1-Chloro-3,4-dinitrobenzene, tech., 90%
| 610-40-2 |
|
(R)-(-)-2-Hydroxy-2-phenylpropionic acid, 99%
| 3966-30-1 |
|
l-(+)-Leucinol, 98%
| 7533-40-6 |
|
Barium iodide hydrate
| 13718-50-8 |
|
2-Phenylglycinonitrile hydrochloride, tech., 95
| 53941-45-0 |
|
BOC-L-Methionine, 99+%
| 2488-15-5 |
|
(R)-(-)-Alpha-Methoxyphenylacetic Acid 99%
| 3966-32-3 |
|
1-Phenyl-3-pyrazolidinone, 97%
| 92-43-3 |
|
6-Fluoro-DL-Tryptophan, 97%
| 7730-20-3 |
|
1,3-Dibromo-2-propanol
| 96-21-9 |
|
Cyanoacetic Acid, 99%
| 372-09-8 |
|
Methyl 4-bromocrotonate, tech., 85%
| 1117-71-1 |
|
4-Methyl-2-Pentanol, 99+% (gc)
| 108-11-2 |
|
2-Methylpyrazine, 99+%
| 109-08-0 |
|
Prostaglandin E2, 98%
| 363-24-6 |
|
2,6-Dimethyl-4-heptanone, Tech., 80%, Remainder mainly
| 108-83-8 |
|
4-(Trifluoromethoxy)benzaldehyde, 99%
| 659-28-9 |
|
Diethylenetriaminepentaacetic acid, 97%
| 67-43-6 |
|
3-Cyclohexylpropylchloride, 99+%
| 1124-62-5 |
|
Urea Hydrogen Peroxide (1 gr Tablets), Contains 35 Wt% H2O2,
| 124-43-6 |
|
Mercury(II) sulfide, red, 99.5+%
| 1344-48-5 |
|
Tetramethylthiuram disulfide, 97%
| 137-26-8 |
|
Tris-(Triphenylphosphine)-Ruthenium(II)Chloride, 98%
| 15529-49-4 |
|
p-Hydroxyphenethyl Alcohol, 98%
| 501-94-0 |
|
5-(P-Dimethylaminobenzylidene)Rhodanine, 97%(UV-VIS)
| 536-17-4 |
|
Chloroacetaldehyde Diethyl Acetal, 99%
| 621-62-5 |
|
4-Chlorophenyl isothiocyanate
| 2131-55-7 |
|
D-Cycloserine, 98+%
| 68-41-7 |
|
4-Isopropylbenzyl Alcohol, 97+%
| 536-60-7 |
|
Basic Fuchsin, For Staining Flagella (Cert )
| 58969-01-0 |
|
3-Mercaptopropionic acid, 99+%
| 107-96-0 |
|
N-Phenyl-1-Naphthylamine Hydrobromide
| 0-00-1 |
|
2-Hydroxy-4-Methylpyrimidine Hydro-Chloride, 97%
| 5348-51-6 |
|
4-Chloro-2-fluoroaniline,99%
| 57946-52-2 |
|
Dodecahydrotriphenylene, 99%
| 1610-39-5 |
|
Cyclohexyl phenyl ether, 95+% (GC)
| 2206-38-4 |
|
2-Bromo-2-butene, 98%, mixture of cis and trans
| 13294-71-8 |
|
Pentafluorobenzene, 98%
| 363-52-0 |
|
2,5-Dichlorobenzotrifluoride, 98+%
| 320-50-3 |
|
Coumarin 343, Laser Grade
| 55804-65-4 |
|
9-(Chloromethyl)Anthracene, 98+%
| 24463-19-2 |
|
2,4-Dimethoxybenzonitrile, 99%
| 4107-65-7 |
|
|