**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 610-40-2 |1-Chloro-3,4-dinitrobenzene | 90 | 210-223-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 23/24/25 33 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed. Danger
of cumulative effects. May cause sensitization by skin contact. Very
toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.Heat sensitive.
Potential Health Effects
Eye:
May cause eye irritation and possible damage.
Skin:
May be fatal if absorbed through the skin. Prolonged and/or repeated
contact may cause irritation and/or dermatitis. May cause skin
sensitization, an allergic reaction, which becomes evident upon
re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause cardiac disturbances. May cause
methemoglobinemia, cyanosis (bluish discoloration of skin due to
deficient oxygenation of the blood), convulsions, and death. May
cause central nervous system effects.
Inhalation:
May cause methemoglobinemia, cyanosis (bluish discoloration of skin
due to deficient oxygenation of the blood), convulsions,
tachycardia, dyspnea (labored breathing), and death. May cause severe
irritation of the respiratory tract with sore throat, coughing,
shortness of breath and delayed lung edema. May cause cardiac
abnormalities. Inhalation at high concentrations may cause CNS
depression and asphixiation.
Chronic:
Prolonged or repeated skin contact may cause sensitization
dermatitis and possible destruction and/or ulceration. Prolonged
exposure may cause anemia and methemoglobinemia, characterized by
dizziness, drowsiness, headache, breath shortness, cyanosis (bluish
skin due to deficient oxygenation of the blood), rapid heart rate
and chocolate-brown colored blood. Repeated exposure may cause
allergic respiratory reaction (asthma).
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
For methemoglobinemia, administer oxygen alone or with Methylene
Blue depending on the methemoglobin concentration in the blood.
Antidote:
Methylene blue, alone or in combination with oxygen is indicated as
a treatment in nitrite induced methemoglobinemia.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Containers
may explode when heated. Runoff from fire control or dilution water
may cause pollution.
Extinguishing Media:
Water or foam may cause frothing. Do NOT get water inside
containers. For small fires, use dry chemical, carbon dioxide, or
water spray. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray. Cool containers with
flooding quantities of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Do not
get in eyes, on skin, or on clothing. Do not ingest or inhale. Use
only with adequate ventilation.
Storage:
Store in a tightly closed container. Keep from contact with
oxidizing materials. Store in a cool, dry, well-ventilated area away
from incompatible substances. Keep away from flammable liquids. Do
not store near alkaline substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 610-40-2:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystals
Color: yellow
Odor: almond-like
pH: Not available.
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: 315 deg C (slight decompose)
Freezing/Melting Point: 36.3 deg C
Autoignition Temperature: Not applicable.
Flash Point: > 112 deg C (> 233.60 deg F)
Explosion Limits, lower: 2.0%
Explosion Limits, upper: 22.0%
Decomposition Temperature: Not available.
Solubility in water: Insoluble.
Specific Gravity/Density: 1.697
Molecular Formula: C6H3ClN2O4
Molecular Weight: 202.55
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. May decompose
violently on heating. Risk of explosion if heated under confinement.
Conditions to Avoid:
Dust generation, excess heat, friction.
Incompatibilities with Other Materials:
Explosive reaction with ammonia. Reacts violently with hydrazine
sulfate and hydrazine hydrate. Incompatible with strong bases and
oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of nitrogen, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 610-40-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Chloro-3,4-dinitrobenzene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: CHLORODINITROBENZENES
Hazard Class: 6.1
UN Number: 1577
Packing Group: II
IMO
Shipping Name: CHLORODINITROBENZENES, LIQUID or SOLID
Hazard Class: 6.1
UN Number: 1577
Packing Group: II
RID/ADR
Shipping Name: CHLORODINITROBENZENES
Hazard Class: 6.1
UN Number: 1577
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 33 Danger of cumulative effects.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 610-40-2: No information available.
Canada
CAS# 610-40-2 is listed on Canada's NDSL List.
CAS# 610-40-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 610-40-2 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/11/1998 Revision #5 Date: 3/19/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Bis-(trimethylsilyl)-trifluoroacetamide, 98+%
| 25561-30-2 |
|
2-Chloro-m-xylene, 99%
| 6781-98-2 |
|
1,4-Dioxaspiro[4.5]Decan-8-One, 98%
| 4746-97-8 |
|
Alpha, Alpha, Alpha, 4-Tetrafluoro-M-Toluidine, 99%
| 2357-47-3 |
|
3-Aminophthalic Acid Hydrochloride, 98% (Titr.)
| 6946-22-1 |
|
Arsenic atomic absorption standard solution, 1mg/ml as in 2% koh
| 1310-58-3 |
|
5-Bromocytosine, 99%
| 2240-25-7 |
|
2-Methyl-3-nitrobenzyl alcohol, 99%
| 23876-13-3 |
|
1-Chloro-3,4-dinitrobenzene, tech., 90%
| 610-40-2 |
|
(R)-(-)-2-Hydroxy-2-phenylpropionic acid, 99%
| 3966-30-1 |
|
l-(+)-Leucinol, 98%
| 7533-40-6 |
|
Barium iodide hydrate
| 13718-50-8 |
|
2-Phenylglycinonitrile hydrochloride, tech., 95
| 53941-45-0 |
|
BOC-L-Methionine, 99+%
| 2488-15-5 |
|
(R)-(-)-Alpha-Methoxyphenylacetic Acid 99%
| 3966-32-3 |
|
1-Phenyl-3-pyrazolidinone, 97%
| 92-43-3 |
|
6-Fluoro-DL-Tryptophan, 97%
| 7730-20-3 |
|
1,3-Dibromo-2-propanol
| 96-21-9 |
|
Cyanoacetic Acid, 99%
| 372-09-8 |
|
Methyl 4-bromocrotonate, tech., 85%
| 1117-71-1 |
|
4-Methyl-2-Pentanol, 99+% (gc)
| 108-11-2 |
|
2-Methylpyrazine, 99+%
| 109-08-0 |
|
Prostaglandin E2, 98%
| 363-24-6 |
|
2,6-Dimethyl-4-heptanone, Tech., 80%, Remainder mainly
| 108-83-8 |
|
4-(Trifluoromethoxy)benzaldehyde, 99%
| 659-28-9 |
|
Diethylenetriaminepentaacetic acid, 97%
| 67-43-6 |
|
3-Cyclohexylpropylchloride, 99+%
| 1124-62-5 |
|
Urea Hydrogen Peroxide (1 gr Tablets), Contains 35 Wt% H2O2,
| 124-43-6 |
|
Mercury(II) sulfide, red, 99.5+%
| 1344-48-5 |
|
Tetramethylthiuram disulfide, 97%
| 137-26-8 |
|
Tris-(Triphenylphosphine)-Ruthenium(II)Chloride, 98%
| 15529-49-4 |
|
p-Hydroxyphenethyl Alcohol, 98%
| 501-94-0 |
|
5-(P-Dimethylaminobenzylidene)Rhodanine, 97%(UV-VIS)
| 536-17-4 |
|
Chloroacetaldehyde Diethyl Acetal, 99%
| 621-62-5 |
|
4-Chlorophenyl isothiocyanate
| 2131-55-7 |
|
D-Cycloserine, 98+%
| 68-41-7 |
|
4-Isopropylbenzyl Alcohol, 97+%
| 536-60-7 |
|
Basic Fuchsin, For Staining Flagella (Cert )
| 58969-01-0 |
|
3-Mercaptopropionic acid, 99+%
| 107-96-0 |
|
N-Phenyl-1-Naphthylamine Hydrobromide
| 0-00-1 |
|
2-Hydroxy-4-Methylpyrimidine Hydro-Chloride, 97%
| 5348-51-6 |
|
4-Chloro-2-fluoroaniline,99%
| 57946-52-2 |
|
Dodecahydrotriphenylene, 99%
| 1610-39-5 |
|
Cyclohexyl phenyl ether, 95+% (GC)
| 2206-38-4 |
|
2-Bromo-2-butene, 98%, mixture of cis and trans
| 13294-71-8 |
|
Pentafluorobenzene, 98%
| 363-52-0 |
|
2,5-Dichlorobenzotrifluoride, 98+%
| 320-50-3 |
|
Coumarin 343, Laser Grade
| 55804-65-4 |
|
9-(Chloromethyl)Anthracene, 98+%
| 24463-19-2 |
|
2,4-Dimethoxybenzonitrile, 99%
| 4107-65-7 |
|
|