**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 137-26-8 |Tetramethylthiuram disulfide | 97 | 205-286-2 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN N
Risk Phrases: 20/22 36/38 43 48/22 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation and if swallowed. Irritating to eyes and skin.
May cause sensitization by skin contact. Harmful : danger of serious
damage to health by prolonged exposure if swallowed. Very toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Use extinguishing media
appropriate to the surrounding fire. Substance is noncombustible.
Containers may explode when heated.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use water
spray, fog or regular foam. Cool containers with flooding quantities
of water until well after fire is out.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
CAS# 137-26-8:
United States OSHA: 5 mg/m3 TWA
Belgium - TWA: 1 mg/m3 VLE
France - VME: 5 mg/m3 VME
Germany: 5 mg/m3 TWA (inhalable fraction)
Malaysia: 1 mg/m3 TWA
Netherlands: 5 mg/m3 MAC
Russia: 0.5 mg/m3 TWA
Spain: 1 mg/m3 VLA-ED
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: white
Odor: characteristic odor
pH: Not available.
Vapor Pressure: Negligible
Viscosity: Not available.
Boiling Point: 129 deg C @ 20 mmHg
Freezing/Melting Point: > 146 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: and carbon disulfide
Specific Gravity/Density: 1.29 @ 20C
Molecular Formula: C6H12N2S4
Molecular Weight: 240.41
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Acids - oxidizing agents - reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 137-26-8: JO1400000
LD50/LC50:
CAS# 137-26-8: Draize test, rabbit, eye: 100 mg/24H Moderate;
Inhalation, rat: LC50 = 500 mg/m3/4H; Oral, mouse: LD50 = 1250
mg/kg; Oral, rabbit: LD50 = 210 mg/kg; Oral, rat: LD50 = 560 mg/kg.
Carcinogenicity:
Tetramethylthiuram disulfide -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 137-26-8: 10 lb final RQ; 4.54 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN N
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitization by skin contact.
R 48/22 Harmful : danger of serious damage to health
by prolonged exposure if swallowed.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37 Wear suitable protective clothing and
gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 137-26-8: No information available.
Canada
CAS# 137-26-8 is listed on Canada's DSL List.
CAS# 137-26-8 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 137-26-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 1/06/1999 Revision #3 Date: 6/18/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Bis-(trimethylsilyl)-trifluoroacetamide, 98+%
| 25561-30-2 |
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2-Chloro-m-xylene, 99%
| 6781-98-2 |
|
1,4-Dioxaspiro[4.5]Decan-8-One, 98%
| 4746-97-8 |
|
Alpha, Alpha, Alpha, 4-Tetrafluoro-M-Toluidine, 99%
| 2357-47-3 |
|
3-Aminophthalic Acid Hydrochloride, 98% (Titr.)
| 6946-22-1 |
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Arsenic atomic absorption standard solution, 1mg/ml as in 2% koh
| 1310-58-3 |
|
5-Bromocytosine, 99%
| 2240-25-7 |
|
2-Methyl-3-nitrobenzyl alcohol, 99%
| 23876-13-3 |
|
1-Chloro-3,4-dinitrobenzene, tech., 90%
| 610-40-2 |
|
(R)-(-)-2-Hydroxy-2-phenylpropionic acid, 99%
| 3966-30-1 |
|
l-(+)-Leucinol, 98%
| 7533-40-6 |
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Barium iodide hydrate
| 13718-50-8 |
|
2-Phenylglycinonitrile hydrochloride, tech., 95
| 53941-45-0 |
|
BOC-L-Methionine, 99+%
| 2488-15-5 |
|
(R)-(-)-Alpha-Methoxyphenylacetic Acid 99%
| 3966-32-3 |
|
1-Phenyl-3-pyrazolidinone, 97%
| 92-43-3 |
|
6-Fluoro-DL-Tryptophan, 97%
| 7730-20-3 |
|
1,3-Dibromo-2-propanol
| 96-21-9 |
|
Cyanoacetic Acid, 99%
| 372-09-8 |
|
Methyl 4-bromocrotonate, tech., 85%
| 1117-71-1 |
|
4-Methyl-2-Pentanol, 99+% (gc)
| 108-11-2 |
|
2-Methylpyrazine, 99+%
| 109-08-0 |
|
Prostaglandin E2, 98%
| 363-24-6 |
|
2,6-Dimethyl-4-heptanone, Tech., 80%, Remainder mainly
| 108-83-8 |
|
4-(Trifluoromethoxy)benzaldehyde, 99%
| 659-28-9 |
|
Diethylenetriaminepentaacetic acid, 97%
| 67-43-6 |
|
3-Cyclohexylpropylchloride, 99+%
| 1124-62-5 |
|
Urea Hydrogen Peroxide (1 gr Tablets), Contains 35 Wt% H2O2,
| 124-43-6 |
|
Mercury(II) sulfide, red, 99.5+%
| 1344-48-5 |
|
Tetramethylthiuram disulfide, 97%
| 137-26-8 |
|
Tris-(Triphenylphosphine)-Ruthenium(II)Chloride, 98%
| 15529-49-4 |
|
p-Hydroxyphenethyl Alcohol, 98%
| 501-94-0 |
|
5-(P-Dimethylaminobenzylidene)Rhodanine, 97%(UV-VIS)
| 536-17-4 |
|
Chloroacetaldehyde Diethyl Acetal, 99%
| 621-62-5 |
|
4-Chlorophenyl isothiocyanate
| 2131-55-7 |
|
D-Cycloserine, 98+%
| 68-41-7 |
|
4-Isopropylbenzyl Alcohol, 97+%
| 536-60-7 |
|
Basic Fuchsin, For Staining Flagella (Cert )
| 58969-01-0 |
|
3-Mercaptopropionic acid, 99+%
| 107-96-0 |
|
N-Phenyl-1-Naphthylamine Hydrobromide
| 0-00-1 |
|
2-Hydroxy-4-Methylpyrimidine Hydro-Chloride, 97%
| 5348-51-6 |
|
4-Chloro-2-fluoroaniline,99%
| 57946-52-2 |
|
Dodecahydrotriphenylene, 99%
| 1610-39-5 |
|
Cyclohexyl phenyl ether, 95+% (GC)
| 2206-38-4 |
|
2-Bromo-2-butene, 98%, mixture of cis and trans
| 13294-71-8 |
|
Pentafluorobenzene, 98%
| 363-52-0 |
|
2,5-Dichlorobenzotrifluoride, 98+%
| 320-50-3 |
|
Coumarin 343, Laser Grade
| 55804-65-4 |
|
9-(Chloromethyl)Anthracene, 98+%
| 24463-19-2 |
|
2,4-Dimethoxybenzonitrile, 99%
| 4107-65-7 |
|
|